Method of extraction and separation of chlorogenic acid from sweet potato leaves through ultrasonic-microwave-double water phase cooperation
A two-phase, ultrasonic technology, applied in chemical instruments and methods, separation/purification of carboxylic acid esters, preparation of carboxylic acid esters, etc., can solve the problems of long time and many steps, and achieve mild conditions, simple operation, and environmental protection. friendly effect
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Embodiment 1
[0039] (1) Preparation of two-phase aqueous system
[0040] Take 5g K 2 HPO 4 ·3H 2 O, add 50mL of 50% ethanol to prepare a two-phase aqueous extractant.
[0041] (2) Ultrasonic-microwave-water two-phase synergistic extraction
[0042] Take 25 mL of the two-phase aqueous system obtained in step (1), add 0.5 g of sweet potato leaf powder that has passed through a 60-mesh sieve, accurately weighed, the ratio of solid to liquid is 1:50 (g / mL), and the ultrasonic conditions are set to 200W, 30°C The treatment time was 8 minutes, and then the microwave treatment conditions were 480W and 1.5 minutes, and the ultrasonic-microwave-water two-phase synergistic extraction was carried out. After the extraction, the sweet potato chlorogenic acid extract with obvious phase separation was obtained by suction filtration, and the extraction rate was 4.26%. Separate the upper and lower phases, take the upper liquid, concentrate under reduced pressure (vacuum degree 0.1MPa, temperature 40°C)...
Embodiment 2
[0050] (1) Preparation of two-phase aqueous system
[0051] Take 5g K 2 HPO 4 ·3H 2 O, add 50mL50% ethanol to prepare a two-phase extractant;
[0052] (2) Ultrasonic-microwave-water two-phase synergistic extraction
[0053] Take 40 mL of the two-phase aqueous system obtained in step (1), add 0.5 g of sweet potato leaf powder that has passed through a 60-mesh sieve, and add 0.5 g of it, the ratio of solid to liquid is 1:80 (g / mL), and the ultrasonic conditions are set to 220W, 35°C The treatment time was 5 minutes, and then the microwave treatment conditions were 800W and 1 minute, and ultrasonic-microwave-water two-phase synergistic extraction was carried out. After the extraction, the sweet potato chlorogenic acid extract with obvious phase separation was suction-filtered, and the extraction rate was 4.32%. Separate the upper and lower phases, take the upper liquid, concentrate under reduced pressure (vacuum degree 0.1MPa, temperature 45°C), and vacuum dry (60°C, 3.5h) to...
Embodiment 3
[0055] (1) Preparation of two-phase aqueous system
[0056] Take 5g K 2 HPO 4 ·3H 2 O, add 50mL50% ethanol to prepare a two-phase extractant;
[0057] (2) Ultrasonic-microwave-water two-phase synergistic extraction
[0058] Take 50mL of the two-phase aqueous system obtained in step (1), add 0.5g of sweet potato leaf powder accurately weighed through a 60-mesh sieve, the material-to-liquid ratio is 1:100 (g / mL), and set the ultrasonic conditions to 180W, 25°C The treatment time was 10 minutes, and then the microwave treatment conditions were 560W and 1.5 minutes, and ultrasonic-microwave-water two-phase synergistic extraction was carried out. After the extraction, the sweet potato chlorogenic acid extract with obvious phase separation was suction-filtered, and the extraction rate was 4.42%. Separate the upper and lower phases, take the upper liquid, concentrate under reduced pressure (vacuum degree 0.1MPa, temperature 40°C), and vacuum dry (60°C, 3.5h) to obtain 0.0324g of ...
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