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A positive electrode slurry, a positive electrode sheet, and a method for preparing the positive electrode sheet

A technology of positive electrode slurry and positive electrode sheet, which is applied in the field of electrode sheet and electrode sheet preparation using the slurry, can solve the problems of long pre-insertion time, consumption and high environmental requirements, and achieves short and low pre-insertion time. Efficient, easy-to-use effects for the first time

Active Publication Date: 2020-05-08
上海杉容新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Lithium metal supplementation is a lithium supplementation method that has high requirements on the environment, and lithium metal residues may pose a great safety hazard. At the same time, during the production process, the pre-intercalation of lithium takes a long time, which is unfavorable to mass production.
The second is to use a high-concentration electrolyte for lithium supplementation, and apply intermittent current pulses to charge the capacitor. The lithium ions in the electrolyte are inserted into the negative electrode to complete the pre-intercalation of lithium. However, this method will consume lithium ions in the electrolyte and weaken the capacitor. power characteristics

Method used

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  • A positive electrode slurry, a positive electrode sheet, and a method for preparing the positive electrode sheet
  • A positive electrode slurry, a positive electrode sheet, and a method for preparing the positive electrode sheet

Examples

Experimental program
Comparison scheme
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Embodiment 1

[0033] Activated carbon as the first cathode material, Li 2 CuO 2 As the second positive electrode material, conductive carbon black (Super P) is used as the conductive agent, and PVDF is used as the binder. First weigh activated carbon, Li 2 CuO 2 , Conductive carbon black and PVDF. PVDF was dissolved in the solvent NMP to prepare a glue solution with a mass concentration of 10%. The weighed activated carbon, Li 2 CuO 2 , Conductive carbon black (Super P) is mixed evenly in a ball mill to obtain the positive electrode mixture, and then the prepared adhesive glue is added, NMP is slowly added while stirring in a vacuum environment, and the viscosity and solid content of the slurry are slowly adjusted to make it It is suitable for coating and stirred for 2 hours to prepare positive electrode slurry. Then, the positive electrode slurry was coated on a porous aluminum foil with a porosity of 30% by a vertical coating method, and the oven temperature was set at 150 ° C, and...

Embodiment 2

[0035] Activated carbon as the first cathode material, Li 2 NiO 2 As the second positive electrode material, conductive carbon black (Super P) is used as the conductive agent, and PVDF is used as the binder. First weigh activated carbon, Li 2 NiO 2 , Conductive carbon black and PVDF. PVDF was dissolved in the solvent NMP to prepare a glue solution with a mass concentration of 5%. The weighed activated carbon, Li 2 NiO 2 1. Conductive carbon black (Super P) was uniformly mixed in a ball mill to obtain a positive electrode mixture, and then the prepared adhesive glue was added, and NMP was slowly added while stirring in a vacuum environment, and stirred for 2 hours to obtain a positive electrode slurry. Then, the positive electrode slurry was coated on a porous aluminum foil with a porosity of 30% by a vertical coating method, and the oven temperature was set at 120 ° C, and the vacuum degree was 50 Pa, baked and dried for 12 hours, and then rolled and molded to obtain a p...

Embodiment 3

[0037] Activated carbon as the first cathode material, Li 5 FeO 4 As the second positive electrode material, conductive carbon black (Super P) is used as the conductive agent, and PVDF is used as the binder. First weigh activated carbon, Li 5 FeO 4 , Conductive carbon black and PVDF. PVDF was dissolved in the solvent NMP to prepare a glue solution with a mass concentration of 6%. The weighed activated carbon, Li 5 FeO 4 1. Conductive carbon black (Super P) was uniformly mixed in a ball mill to obtain a positive electrode mixture, and then the prepared adhesive glue was added, and NMP was slowly added while stirring in a vacuum environment, and stirred for 2 hours to obtain a positive electrode slurry. Then, the positive electrode slurry was coated on a porous aluminum foil with a porosity of 30% by a vertical coating method, the oven temperature was set at 170°C, and the vacuum degree was 50 Pa, baked and dried for 12 hours, and then rolled and molded to obtain the posit...

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Abstract

The invention discloses positive electrode slurry; the positive electrode slurry is prepared from a first positive electrode material, a second positive electrode material, a conductive agent and a binder according to the following mass percentages: 50-80% of the first positive electrode material, 10-40% of the second positive electrode material, 2-5% of the conductive agent and 5-8% of the binder, wherein the first positive electrode material is one kind of carbon nano tubes, graphene, activated carbon, and nano-gate carbon; the second positive electrode material is one kind of Li<2>NiO<2>, Li<2>MoO<3>, Li<6>CoO<4>, Li<2>CuO<2>, Li<6>ZnO<4>, Li<5>AlO<4>, Li<8>ZrO<4>, Li<5>ReO<6> and Li<5>FeO<4>; and the binder is dissolved into a solvent to form a glue solution with the mass concentrationof 1-10%. The positive electrode slurry is coated on a porous current collector to be dried to obtain a positive electrode plate. A negative electrode is subjected to pre-lithium-intercalation by theobtained second positive electrode material on the positive electrode plate, and meanwhile, the structure is simple, and the operation is convenient.

Description

technical field [0001] The invention relates to a slurry coated on an electrode sheet, because there is a slurry used for a positive electrode of a lithium ion capacitor, an electrode sheet using the slurry, and a preparation method of the electrode sheet. Background technique [0002] Lithium-ion capacitors are energy storage devices that combine lithium-ion batteries and supercapacitors. Compared with supercapacitors, lithium-ion capacitors have higher energy density. Compared with lithium-ion batteries, lithium-ion capacitors have better low-temperature performance and better rate performance. A very important technology in the production process of lithium-ion capacitors is the pre-intercalation lithium technology of negative electrode materials. There are two main types of existing pre-intercalation lithium technologies: one is to use inert lithium powder (FMC, SLMP) or lithium metal Lithium supplementation, how to add inert lithium powder, the choice of solvent, and h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G11/30H01G11/36H01G11/32H01G11/46H01G11/50H01G11/86
CPCH01G11/30H01G11/32H01G11/36H01G11/46H01G11/50H01G11/86Y02E60/13
Inventor 林佳颐廖运平
Owner 上海杉容新能源科技有限公司