Metal-glass macrocomposites and compositions and methods of making
A composite material, glass technology, applied in the field of forming large composite materials, can solve the problem of destroying the transparency or surface integrity of the two-phase structure
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[0138] In the following examples, all reagents, starting materials and solvents used in the following examples were purchased from commercial suppliers (such as Stanlab Sp.J., Lublin, Poland) and used without further purification (unless otherwise stated) .
example 1
[0139] Example 1. Bronze-glass composite material
[0140] Metal preparation
[0141] The bronze was cut into 7 millimeter (mm) thick disks with a diameter of 20 mm using an angle grinder with diamond disks. Grind the bronze surface with a metal file to ensure a reflective surface.
[0142] Glass composition preparation
[0143] The components and ratios of the glass composition are shown in Table 4. A batch of 210 grams (g) was hand-milled in a mortar to ensure uniform melting, and transferred to a 200 milliliter (ml) glass porcelain crucible with a spoon at room temperature, and two larger crucibles made of bisque The protective cover is closed.
[0144] Table 4.
[0145] Compound
Mass percentage (weight percentage)
ZnO
33.10
P 2 O 5
45.84
Al 2 O 3
1.80
TiO 2
0.20
Na 2 O
7.88
K 2 O
9.20
CaO
1.98
[0146] Melting procedure:
[0147] Heat the glass according to the following scheme: room temperature to 200°C in 40 minutes, 200°C to 400°C in 40 minutes, 400°C to 800°C in 40...
example 2
[0153] Example 2. Gold-glass composite material
[0154] Metal preparation
[0155] A 1 gram (g) gold piece was prepared by wiping the surface with a cloth to remove dust.
[0156] Glass composition preparation:
[0157] The components and ratios of the glass composition are shown in Table 5. A batch of 210 g was manually ground in a mortar to ensure uniform melting, and placed in a 200 ml glass-ceramic crucible at room temperature, which was closed with two larger crucible protective covers made of bisque.
[0158] table 5.
[0159] Compound
Mass percentage (weight percentage)
ZnO
35.39
P 2 O 5
46.12
Al 2 O 3
1.48
TiO 2
0.39
Na 2 O
6.60
K 2 O
10.03
[0160] Melting procedure:
[0161] Heat the glass according to the following scheme: room temperature to 200°C in 40 minutes, 200°C to 400°C in 40 minutes, 400°C to 800°C in 40 minutes, 800°C to 1100°C in 60 minutes, and then at 1100°C Keep it for 60 minutes.
[0162] Casting procedure:
[0163] The melt is cooled from 1100°C to ...
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