Aluminum alloy material capable of being used for online hydrogen supply

A technology of aluminum alloy materials and alloys, which is applied in the field of aluminum alloy materials, can solve the problems of difficult and stable application, unstable hydrogen production rate of alloys, etc., and achieve the effect of promoting hydrolysis reaction, stable hydrogen production rate, and satisfying online hydrogen supply

Active Publication Date: 2019-02-01
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] However, in the existing research on hydrogen production of aluminum gallium alloys, the hydrogen production rate of the alloy is not stable, and the hydrogen production rate curve is similar to a parabola, which is difficult to apply smoothly

Method used

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  • Aluminum alloy material capable of being used for online hydrogen supply
  • Aluminum alloy material capable of being used for online hydrogen supply
  • Aluminum alloy material capable of being used for online hydrogen supply

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] With 90wt% Al bulk, 3.2wt% Ga, 5wt% In and Sn, where the atomic ratio of In:Sn is 3:1, 1.8wt% Al with a size of 200 mesh 2 o 3 Granules are used as raw materials, melted at 800°C for 1.5h in a stirred furnace filled with nitrogen protection gas, then stirred at 60r / min for 15 minutes, poured into steel molds, and obtained Al-Ga-In-Sn-Al after natural cooling 2 o 3 alloy. Its SEM characterization picture is as follows figure 1 shown.

[0025] Take 1 g of the prepared aluminum alloy and carry out hydrolysis reaction with distilled water at 40 degrees at room temperature of 20 degrees. The hydrogen production performance of hydrolysis is shown in Table 1, and the instantaneous hydrogen production rate is as figure 2 shown.

Embodiment 2

[0029] With 85wt% Al bulk, 3.5wt% Ga, 9wt% In and Sn, where the atomic ratio of In:Sn is 3:1, 2.5wt% Al with a size of 100 mesh 2 o 3 Granules are used as raw materials, melted at 900°C for 1 hour in a stirred furnace filled with nitrogen protection gas, stirred at 80r / min for 12 minutes, poured into steel molds, and obtained Al-Ga-In-Sn-Al after natural cooling 2 o 3 alloy.

[0030] Take 1 g of the prepared aluminum alloy and carry out hydrolysis reaction with distilled water at 40°C, and the measured hydrogen production performance by hydrolysis is shown in Table 1.

Embodiment 3

[0034] With 85wt% Al bulk, 5wt% Ga, 8wt% In and Sn, where the atomic ratio of In:Sn is 3:1, 2wt% Al with a size of 100 mesh 2 o 3Granules are used as raw materials, melted at 800°C for 1 hour in a stirred furnace filled with nitrogen protection gas, stirred at 70r / min for 20 minutes, poured into steel molds, and obtained Al-Ga-In-Sn-Al after natural cooling 2 o 3 Alloy materials.

[0035] Take 1 g of the prepared aluminum alloy and carry out hydrolysis reaction with distilled water at 40°C, and the measured hydrogen production performance by hydrolysis is shown in Table 1.

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Abstract

The invention discloses an aluminum alloy material capable of being used for online hydrogen supply. According to the aluminum alloy material, Al2O3 powder is introduced into an Al-Ga-In-Sn alloy capable of achieving hydrogen generation through hydrolysis to obtain an Al-Ga-In-Sn-Al2O3 alloy, wherein the content of the Al2O3 is not more than 8% by weight; and a fusion casting method is adopted forpreparation. Researches show that an Al2O3 doped aluminum alloy has the good hydrogen production performance, hydrogen can be generated immediately after the alloy is in contact with water, and a reaction does not have delaying time. The Al-Ga-In-Sn-Al2O3 alloy has the stable hydrogen production rate and can be used for online hydrogen supply through hydrolysis, and a stable hydrogen source is provided for proton exchange membrane fuel cells.

Description

technical field [0001] The invention belongs to the field of hydrogen production by hydrolysis of aluminum alloys, and in particular relates to an aluminum alloy material with a stable hydrogen production rate that can be used for online hydrogen supply. Background technique [0002] Hydrogen energy is regarded as the clean energy with the most development potential in the 21st century, especially when combined with the use of fuel cells, the utilization rate of hydrogen energy can be improved. However, the storage of hydrogen is an important technical bottleneck restricting the widespread use of fuel cells. In addition, safety issues and high costs during hydrogen transportation also limit the large-scale use of hydrogen energy. [0003] In order to meet the application requirements of proton exchange membrane fuel cells, the corresponding on-site hydrogen production technology requires raw materials with high hydrogen production capacity and relatively stable hydrogen pro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/00C22C1/02C22C1/10C01B3/08
CPCC01B3/08C22C1/1036C22C21/00C22C21/003Y02E60/36
Inventor 魏存弟刘州高钱许书郡刘丹安琦
Owner JILIN UNIV
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