Preparation of high-protection composite material based on TPV base material and application of high-protection composite material in high-flexibility flexible cable products

A composite material, protective technology, applied in rubber insulators, organic insulators, etc., can solve the problems of short service life, poor cable flexibility, inconvenient use, etc.

Inactive Publication Date: 2019-02-15
YANGZHOU YAGUANG CABLE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides a preparation of a composite material with high protective properties based on TPV base material and its application in highly flexible soft cable products, which has the advantages of high strength and solves the problem of heat resistance and solvent resistance. On the one hand, it cannot meet the requirements of some industries. PP+EPDM blended dynamic vulcanized elastomer (TPV) has excellent heat resistance and solvent resistance, which makes up for the shortcomings of TPES materials, while traditional cables have poor flexibility. , so the service life is short and inconvenient to use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment one: a kind of composite material preparation based on TPV base material protective property, comprises the following steps:

[0026] 1) First take several parts of maleic anhydride;

[0027] 2) Add several parts of maleic anhydride to EPDM for grafting reaction to obtain EPDM-g-MA with a grafting rate of 1-3%. The grafting reaction includes pre-mixing EPDM, free radical initiators and additives and adding them to In the internal mixer, when EPDM is completely plasticized, add 6wt% MAH based on EPDM in two times, banbury at 160°C for 10min, wash and filter to obtain EPDM-g-MAH;

[0028] 3) Add PA6 and 0.3wt% triethylamine based on PA6 to phenol, and heat to 140°C to completely dissolve the solid;

[0029] 4) Then add the xylene solution dissolved in EPDM-g-MAH into the container containing the phenol mixture, and keep it warm for 9 hours; after cooling to room temperature, pour the obtained reaction material into dimethylformamide and let it settle for 1 -2...

Embodiment 2

[0038] Embodiment two: a kind of composite material preparation based on TPV base material protective property, comprises the following steps:

[0039] 1) First take several parts of maleic anhydride;

[0040] 2) Add several parts of maleic anhydride to EPDM for grafting reaction to obtain EPDM-g-MA with a grafting rate of 1-3%. The grafting reaction includes pre-mixing EPDM, free radical initiators and additives and adding them to In the internal mixer, when EPDM is completely plasticized, add 7wt% MAH based on EPDM twice, banbury at 170°C for 12min, wash and filter to obtain EPDM-g-MAH;

[0041] 3) Add PA6 and 0.4wt% triethylamine based on PA6 to phenol, and heat to 150°C to completely dissolve the solid;

[0042] 4) Then add the xylene solution dissolved in EPDM-g-MAH into the container containing the phenol mixture, and keep it warm for 10 hours; after cooling to room temperature, pour the obtained reaction material into dimethylformamide and let it settle for 1.5 h, filte...

Embodiment 3

[0051] Embodiment three: a kind of composite material preparation based on TPV base material protective property, comprises the following steps:

[0052] 1) First take several parts of maleic anhydride;

[0053] 2) Add several parts of maleic anhydride to EPDM for grafting reaction to obtain EPDM-g-MA with a grafting rate of 3%. The grafting reaction includes pre-mixing EPDM, free radical initiators and additives and then adding them to the banburying In the machine, when EPDM is completely plasticized, add 8wt% MAH based on EPDM twice, banbury at 180°C for 15min, wash and filter to obtain EPDM-g-MAH;

[0054] 3) Add PA6 and 0.5wt% triethylamine based on PA6 to phenol, and heat to 160°C to completely dissolve the solid;

[0055] 4) Then add the xylene solution dissolved in EPDM-g-MAH into the container containing the phenol mixture, and keep it warm for 12 hours; after cooling to room temperature, pour the obtained reaction material into dimethylformamide and let it settle fo...

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PUM

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Abstract

The invention relates to the technical field of cables, and discloses preparation of a high-protection composite material based on a TPV base material. The preparation comprises the following steps: taking a plurality of maleic anhydride at the first; and adding the maleic anhydride into EPDM for grafting reaction to obtain EPDM-g-MA with a grafting rate of 1-3%, wherein the grafting reaction comprise steps of premixing EPDM, a free radical initiator and additives and then adding the mixture to an internal mixer. The preparation of the high-protection composite material based on the TPV base material and the application of the high-protection composite material in high-flexibility flexible cable products overcome a shortcoming of poor blending compatibility between the EPDM as a non-polarmaterial and strong polar nylon by grafting non-polar EPDM with maleic anhydride and then reacting with nylon to obtain modified EPDM, and improve blending processability and high strength of the TPVmaterial; and antioxidants, light stabilizers and internal lubricants are added to make the prepared TPV material have relatively long service life and processing stability.

Description

technical field [0001] The invention relates to the technical field of cables, in particular to the preparation of a composite material with high protective properties based on TPV base material and its application in highly flexible soft cable products. Background technique [0002] TPV is mainly composed of two parts, one is plastic as the continuous phase, and the other is rubber as the dispersed phase. Usually rubber needs to be combined with softening oil or plasticizer. Vulcanizing agent and some auxiliary agents are also essential. In addition, for To reduce costs or improve certain aspects of performance, some inorganic fillers will be added. [0003] The application of thermoplastic elastomer TPE has gradually deepened and expanded. Although styrene-based TPE (TPEs) is widely used, this type of material cannot meet the requirements of some industries in terms of heat resistance and solvent resistance. PP+EPDM blended dynamic vulcanized elastomer (TPV) has excellent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L77/02C08L51/04C08L23/12C08L83/04C08L23/08C08L61/06C08K13/02C08K3/22C08K3/24C08K3/38C08K3/34H01B3/28C08F255/06C08F222/06
CPCC08F255/06C08K2003/2227C08K2003/387C08K2201/011C08L23/16C08L2201/08C08L2203/202C08L2205/025C08L2205/035C08L2312/00H01B3/28C08L77/02C08L51/04C08L23/12C08L83/04C08L23/0853C08L61/06C08K13/02C08K3/22C08K3/24C08K3/38C08K3/34C08F222/06
Inventor 王金合鲁永林邵玉和曾天祥张跃芳杨业兵胡沛霖张美玲
Owner YANGZHOU YAGUANG CABLE
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