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Comprehensive recovering and environmentally-friendly recycling method of wasted three-way catalyst

A three-way catalyst and environmental protection technology, applied in the direction of improving process efficiency, etc., can solve problems such as backward recycling and refining technology, chaotic market order, low product purity, etc., achieve obvious advancement and cleanliness, improve environmental quality, and product purity high effect

Inactive Publication Date: 2019-02-15
WUYI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In view of the scarcity and importance of platinum group metal resources, due to the high physical and chemical stability of platinum group metals, during the use of its products, even if some of their functions are lost, the value of the metal itself is still there.
At present, the recovery and refining market of precious metal industrial catalysts and automobile exhaust catalysts in my country is still in its infancy, the market is chaotic, and the recycling and refining technology is backward. The recovery and refining process causes a lot of secondary pollution, low product purity, and serious waste of resources.

Method used

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  • Comprehensive recovering and environmentally-friendly recycling method of wasted three-way catalyst

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Embodiment 1

[0017] Such as figure 1 As shown, the waste three-way catalyst described in this embodiment 1 comprehensively recycles the method for environmental protection and recycling, comprising the following steps:

[0018] (1) Collect the exhaust pipes of waste automobiles with waste three-way catalysts, then crush them, and separate the waste three-way catalysts and waste iron shells;

[0019] (2) waste three-way catalyst is burned and made into powder;

[0020] (3) Carry out dry extraction and smelting of waste three-way catalyst powder, dry extraction and smelting adopts electric arc furnace smelting, adds Fe-based metal iron nuggets as a capture agent, and extracts and separates to form iron nuggets enriched with platinum group metals and harmless Chemicalized waste three-way catalyst carrier;

[0021] (4) Separating the iron block enriched with platinum group metals from the iron block and platinum group metals, and adopting the wet separation process of fractional extraction a...

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Abstract

The invention discloses a comprehensive recovering and environmentally-friendly recycling method of a wasted three-way catalyst. The method comprises the following steps: (1) collecting wasted automobile exhaust pipes containing the wasted three-way catalysts; crushing; and separating the wasted three-way catalysts and wasted iron housings; (2) incinerating the wasted three-way catalyst; and powdering; (3) extracting and melting the wasted three-way catalyst powder through an electric arc furnace in a dry manner; adding Fe serial iron block as a trapping agent; and extracting and separating platinum group metal enriched iron blocks and harmless wasted three-way catalyst carriers; (4) separating the iron blocks and platinum group metal from the platinum group metal enriched iron blocks; andseparating the platinum group metal by grades through a graded extracting and resin adsorbing type wet separation technology; and (5) refining and purifying the separated platinum group metal until the purity is more than 99.9%, thus obtaining the high-purity platinum group metal. According to the method, the precious metal recycling capacity is improved; the environmental pollution is reduced; and the environment is improved.

Description

technical field [0001] The invention relates to the technical field of recovering precious metals in waste three-way catalysts, in particular to a method for comprehensive recovery, environmental protection and recycling of waste three-way catalysts. Background technique [0002] At present, the role of platinum group metals in industry is just like our human body cannot do without vitamins, and it is also known as "industrial vitamins". Although the quantity is small, it is indispensable. Due to the unique properties of platinum group metals and the scarcity of resources, they are regarded as "strategic reserve metals" in the world, and are known as "the first high-tech metals" in the development of high-tech industries. [0003] With the advancement of science and technology, the application fields of platinum group metals are becoming wider and wider, and the consumption is increasing, so the recycling of secondary resources becomes more important. Therefore, all countri...

Claims

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Application Information

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IPC IPC(8): C22B7/00C22B11/02C22B11/00
CPCC22B7/001C22B7/006C22B7/009C22B11/026C22B11/048C22B3/26Y02P10/20
Inventor 尹荔松涂驰周马思琪蓝键
Owner WUYI UNIV
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