Rubber blend, sulfur-crosslinkable rubber mixture and vehicle tire
A technology of rubber blends and rubber mixtures, applied in special tires, vehicle parts, tire parts, etc., can solve the problems of rolling resistance, deterioration of winter characteristics and wear characteristics, and achieve improved rolling resistance indicators and improved wet grip characteristics. , the effect of improving physical properties
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[0108] The present invention will now be described in detail by way of comparative examples and working examples.
[0109] Production of the rubber blend of the present invention:
[0110] Copolymerization of 1,3-butadiene with styrene (diene polymer A)
[0111] Copolymerization was carried out in a jacketed 40 L steel reactor which was purged with nitrogen prior to addition of organic solvent, monomer, polar ligand compound, initiator compound and other components. The following components were added in the order indicated: cyclohexane solvent (18 560 g), butadiene monomer (1777 g), styrene monomer (448 g) and tetramethylethylenediamine (TMEDA, 1.0 g), and The mixture was heated to 40°C and then titrated with n-butyllithium to remove traces of water or other impurities. n-BuLi (14.08 mmol) was added to the polymerization reactor to initiate polymerization. The polymerization was carried out for 20 minutes, during which the polymerization temperature was not allowed to ris...
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