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A kind of two-component silicone structural adhesive for solar thermal power generation and preparation method thereof

A photothermal power generation, two-component technology, applied in the direction of adhesives, polymer adhesive additives, non-polymer adhesive additives, etc., can solve the problems of reduced bonding strength, reduced cross-linking density of sealing materials, etc., to achieve Effects of improving tensile bond strength, increasing crosslink density, and improving moisture and heat aging resistance

Active Publication Date: 2021-04-02
CHENGDU GUIBAO NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the fact that the room temperature vulcanized silicone rubber has a phenomenon of reducing the crosslinking density of the sealing material in a high-temperature and high-humidity environment, in terms of adhesive performance, it shows that the adhesive strength to the substrate after double 85 aging is greatly reduced

Method used

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  • A kind of two-component silicone structural adhesive for solar thermal power generation and preparation method thereof
  • A kind of two-component silicone structural adhesive for solar thermal power generation and preparation method thereof
  • A kind of two-component silicone structural adhesive for solar thermal power generation and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A component preparation

[0054] 20 parts of α, ω-dihydroxypolydimethylsiloxane with a viscosity of 700mPa·s, 80 parts of α,ω-dihydroxypolydimethylsiloxane with a viscosity of 20000mPa·s, 20 parts of a viscosity of 500mPa ·S polydimethylsiloxane, 30 parts of nano-active calcium carbonate, 50 parts of heavy calcium carbonate, and 5 parts of fumed white carbon black are uniformly dispersed and mixed under vacuum to prepare component A.

[0055] B component preparation

[0056] 30 parts of pigment carbon black, 40 parts of polydimethylsiloxane with a viscosity of 500mPa·s, 20 parts of the first type of crosslinking agent, 40 parts of tetraethyl orthosilicate, 10 parts of coupling agent, 2 parts of dibutyl The base tin laurate is uniformly dispersed and mixed under vacuum to prepare the B component.

[0057] Among them, the first type of cross-linking agent adopts a cross-linking agent whose X is an ethyl group and R1 and R2 are a methyl structure, and its molecular struc...

Embodiment 2

[0063] A component preparation

[0064] Mix 10 parts of α,ω-dihydroxypolydimethylsiloxane with a viscosity of 700mPa·s, 100 parts of α,ω-dihydroxypolydimethylsiloxane with a viscosity of 20000mPa·s, 20 parts of a viscosity of 500mPa ·S polydimethylsiloxane, 100 parts of nano-active calcium carbonate, 50 parts of heavy calcium carbonate, and 2 parts of fumed white carbon black are uniformly dispersed and mixed under vacuum to prepare component A.

[0065] B component preparation

[0066] 30 parts of pigment carbon black, 40 parts of polydimethylsiloxane with a viscosity of 500mPa·s, 15 parts of first-class crosslinking agent, 40 parts of tetraethyl orthosilicate, 10 parts of coupling agent, 2 parts of dibutyl The base tin laurate is uniformly dispersed and mixed under vacuum to prepare the B component.

[0067] Among them, the first type of cross-linking agent adopts a cross-linking agent in which X is octyl, R1 and R2 are methyl structures, and its molecular structure is

...

Embodiment 3

[0073] A component preparation

[0074] 40 parts of α, ω-dihydroxypolydimethylsiloxane with a viscosity of 700mPa·s, 60 parts of α,ω-dihydroxypolydimethylsiloxane with a viscosity of 20000mPa·s, 10 parts of a viscosity of 500mPa ·S polydimethylsiloxane, 60 parts of nano-active calcium carbonate, 60 parts of heavy calcium carbonate, and 5 parts of fumed white carbon black are uniformly dispersed and mixed under vacuum to prepare component A.

[0075] B component preparation

[0076] 30 parts of pigment carbon black, 40 parts of polydimethylsiloxane with a viscosity of 500mPa·s, 20 parts of the first type of crosslinking agent, 40 parts of tetraethyl orthosilicate, 10 parts of coupling agent, 2 parts of dibutyl The base tin laurate is uniformly dispersed and mixed under vacuum to prepare the B component.

[0077] Among them, the first type of cross-linking agent adopts the cross-linking agent whose X is ethyl, R1 and R2 are ethyl structure, and its molecular structure is

[0...

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Abstract

The invention discloses a bicomponent silicone structural adhesive for solar thermal power generation. The bicomponent silicone structural adhesive comprises a component A and a component B. The component A includes: 10-40 parts of type 1 alpha, omega-dihydroxy polydimethylsiloxane; 60-100 parts of type 2 alpha, omega-dihydroxy polydimethylsiloxane; 5-35 parts of a plasticizer; 80-150 parts of type 1 filler; and 0.5-10 parts of type 2 filler. The component B includes: 20-35 parts of carbon black; 25-40 parts of a plasticizer; 10-80 parts of a type 1 cross-linking agent; 25-80 parts of a type 2cross-linking agent; 2.5-20 parts of a coupling agent; and 0.1-2 parts of a catalyst. The invention also discloses a preparation method of the bicomponent silicone structural adhesive for solar thermal power generation. The silicone sealant can be used for structural bonding outdoors, and is especially suitable for structural bonding fixation between a solar thermal power generation reflecting mirror and support.

Description

technical field [0001] The invention relates to a silicone adhesive and a preparation method thereof, in particular to a two-component silicone structural adhesive for solar thermal power generation and a preparation method thereof, belonging to the technical field of organic silicon structural adhesives. Background technique [0002] According to the different ways of solar power generation, it can be divided into solar photovoltaic power generation and solar thermal power generation. Solar thermal power generation is a solar energy utilization technology that uses concentrated solar collectors to gather solar radiation energy, and then uses the energy to heat a certain working fluid to hundreds of degrees Celsius, and use this working fluid to drive a generator to generate electricity. Since the birth of solar thermal power generation technology in the 1950s, the current global solar thermal power generation market is mainly concentrated in Spain, the United States and oth...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J183/04C09J11/04C09J11/06C09J11/08
CPCC08K2003/265C08K2201/011C08K2201/014C08L2205/025C08L2205/03C08L2312/00C09J11/04C09J11/06C09J11/08C09J183/04C08L83/04C08K13/02C08K3/26C08K3/36C08K5/544C08K5/5435
Inventor 张明赵为周静罗诗寓王有治
Owner CHENGDU GUIBAO NEW MATERIAL
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