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Degradable environmentally-friendly polymer composite material

A composite material and polymer technology, which is applied in the field of degradable and environmentally friendly polymer composite materials, can solve the problems that the anti-aging performance needs to be further improved, and achieve the effects of excellent anti-aging effect, good degradation effect, and enhanced anti-aging performance

Active Publication Date: 2019-04-16
惠州市中海源新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the social emphasis on environmental protection, degradable environmentally friendly polymer composite materials have a wide range of demands in 3D printing; in the prior art, polybutylene succinate (PBS), polylactic acid (PLA) and starch Such raw materials have good degradation performance; therefore, they are often used as raw materials for degradable environmental protection materials; however, the anti-aging performance of existing degradable environmental protection materials needs to be further improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1 Preparation of degradable and environmentally friendly polymer composite materials

[0026] The composition of raw materials in parts by weight: 80 parts of polybutylene succinate; 50 parts of polylactic acid; 25 parts of starch; 15 parts of carrageenan; 3 parts of toughening agent; 1 part of coupling agent; 1 part of anti-aging agent.

[0027] Described polybutylene succinate selects the polybutylene succinate with the trade mark H1805 of BASF, Germany; the polylactic acid selects the polylactic acid with the trade mark of U.S. NatureWorks as 3052d; the starch selects corn Starch; the toughening agent is MBS toughening agent with the trade name EM500 from Korea LG; the coupling agent is selected from silane coupling agent KH-540;

[0028] The anti-aging agent is prepared by the following method: dissolving 2,3,3',4'-biphenyltetracarboxylic dianhydride in toluene, then adding 3-amino-n-heptane and 4-dimethylaminopyridine to carry out the process. The reaction...

Embodiment 2

[0030] Example 2 Preparation of degradable and environmentally friendly polymer composite materials

[0031] The composition of raw materials in parts by weight: 50 parts of polybutylene succinate; 40 parts of polylactic acid; 30 parts of starch; 10 parts of carrageenan; 3 parts of toughening agent; 1 part of coupling agent; 1 part of anti-aging agent.

[0032] Described polybutylene succinate selects the polybutylene succinate with the trade mark H1805 of BASF, Germany; the polylactic acid selects the polylactic acid with the trade mark of U.S. NatureWorks as 3052d; the starch selects corn Starch; the toughening agent is MBS toughening agent with the trade name EM500 from Korea LG; the coupling agent is selected from silane coupling agent KH-540;

[0033] The anti-aging agent is prepared by the following method: dissolving 2,3,3',4'-biphenyltetracarboxylic dianhydride in toluene, then adding 3-amino-n-heptane and 4-dimethylaminopyridine to carry out the process. The reaction...

Embodiment 3

[0035] Example 3 Preparation of degradable environment-friendly polymer composites

[0036] The composition of raw materials in parts by weight: 80 parts of polybutylene succinate; 60 parts of polylactic acid; 20 parts of starch; 20 parts of carrageenan; 5 parts of toughening agent; 2 parts of coupling agent; 2 parts of anti-aging agent.

[0037] Described polybutylene succinate selects the polybutylene succinate with the trade mark H1805 of BASF, Germany; the polylactic acid selects the polylactic acid with the trade mark of U.S. NatureWorks as 3052d; the starch selects corn Starch; the toughening agent is MBS toughening agent with the trade name EM500 from Korea LG; the coupling agent is selected from silane coupling agent KH-540;

[0038] The anti-aging agent is prepared by the following method: dissolving 2,3,3',4'-biphenyltetracarboxylic dianhydride in toluene, then adding 3-amino-n-heptane and 4-dimethylaminopyridine to carry out the process. The reaction is heated unde...

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Abstract

The invention relates to the technical field of polymer materials, particularly to a degradable environmentally-friendly polymer composite material, which is prepared from the following raw materialsby weight: 50-80 parts of polybutylene succinate, 40-60 parts of polylactic acid, 20-30 parts of starch, 10-20 parts of carrageenan, 1-5 parts of a toughening agent, 0.5-2 parts of a coupling agent, and 0.5-2 parts of an anti-aging agent. According to the present invention, the material is prepared from polybutylene succinate, polylactic acid, starch and other degradable raw materials, such that the composite material has good degradation effect; and by adding the toughening agent and the anti-aging agent, the obtained material has advantages of good strength, good toughness and good anti-aging effect.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a degradable environment-friendly polymer composite material. Background technique [0002] 3D printing is a technology that builds objects by layer-by-layer printing using bondable materials such as powdered metals or plastics based on digital model files. With the development of 3D printing technology, it has been widely used in industrial design, engineering, automotive, aerospace, dental and medical fields. [0003] With the society's emphasis on environmental protection, degradable and environmentally friendly polymer composite materials have a wide range of needs in 3D printing; in the existing technology, polybutylene succinate (PBS), polylactic acid (PLA) and starch Such raw materials have good degradation performance; therefore, they are often used as raw materials for degradable environmental protection materials; but the anti-aging properties of existing deg...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L67/04C08L3/02C08L5/00C08L51/04C08K5/3415C07D209/48C07D405/04
CPCC07D209/48C07D405/04C08L67/02C08L2201/06C08L2201/08C08L2205/035C08L67/04C08L3/02C08L5/00C08L51/04C08K5/005C08K5/3415
Inventor 郑皓天
Owner 惠州市中海源新材料科技有限公司