Packaging material for batteries, method for producing same, polybutylene terephthalate film for packaging material for batteries, and battery
A technology of polybutylene terephthalate film and polybutylene terephthalate, which is applied in battery pack parts, chemical instruments and methods, circuits, etc., can solve problems such as warping easily. Achieve the effect of not easy to warp and excellent formability
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Embodiment 1-3
[0164]
[0165] The barrier layer is laminated on the substrate layer by dry lamination. As the base material layer, a biaxially stretched polybutylene terephthalate film (PBT film) whose relationship (X / Y) between the puncture strength X and the thickness Y described later was the value shown in Table 1 was used, respectively. In addition, as the barrier layer, an aluminum alloy foil (JIS H4160: 1994A8021HO, thickness 35 μm) having both surfaces subjected to chemical surface treatment was used. Specifically, a two-component polyurethane adhesive (polyol compound and aromatic isocyanate compound) was applied to one surface of the aluminum alloy foil to form an adhesive layer (thickness: 3 μm) on the barrier layer. Next, the adhesive layer and the substrate layer on the barrier layer were laminated, and then aging treatment was performed at 40° C. for 24 hours, thereby producing a laminate of substrate layer / adhesive layer / barrier layer. Among them, the chemical surface trea...
reference example 1
[0177]
[0178]It carried out similarly to Example 1, and produced the laminated body of a base material layer / adhesive layer / barrier layer. Next, on the barrier layer of the laminate, an adhesive layer (thickness 15 μm, arranged on the barrier layer side) made of maleic anhydride-modified polypropylene resin and a heat-bonded adhesive layer made of random polypropylene resin were coextruded. Resin layer (thickness 15 μm, innermost layer), thereby obtaining a laminated film in which a substrate layer, an adhesive layer, a barrier layer, an adhesive layer, and a thermally fusible resin layer are laminated in this order. Next, the laminated film was subjected to an aging step to obtain a battery packaging material of Reference Example 1. In Reference Example 1, the aging step was performed at 40° C. for 48 hours.
[0179] In the manufacturing process of the battery packaging material of Reference Example 1, the polybutylene terephthalate film was exposed to a temperature T (°...
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