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Plasmon resonance reversible control of silver nanoparticle film and its preparation method and application

A technology of plasmon resonance and silver nanoparticles, applied in the field of smart membrane materials, can solve the problems of slow reversible plasmon resonance regulation rate, small spectral modulation range, poor cycle life, etc., and achieve excellent SPR reversible regulation characteristics, high sensitivity, The effect of excellent cycle performance

Active Publication Date: 2021-07-16
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are still the following problems in the research on the regulation of the external field response dynamic reversible plasmon resonance characteristics in the solid phase: (1) the research mainly focuses on gold nanoparticles; (2) the modulation range of the plasmon resonance absorption spectrum is small; (3 ) The rate of reversible plasmon resonance regulation is slow, and the cycle life is poor
Due to the active chemical properties of silver nanoparticles, so far, the research on the dynamic and reversible regulation of the plasmon resonance properties of silver nanoparticles (AgNPs) by adjusting the distance between adjacent silver nanoparticles (AgNPs) under solid phase has not been reported yet.

Method used

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  • Plasmon resonance reversible control of silver nanoparticle film and its preparation method and application
  • Plasmon resonance reversible control of silver nanoparticle film and its preparation method and application
  • Plasmon resonance reversible control of silver nanoparticle film and its preparation method and application

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Effect test

Embodiment 1

[0067] A method for preparing a plasma resonance reversible regulatory silver nanoparticle film, including steps as follows:

[0068] (1) First, the spectral absorption peak is 420 nm, and the spectral absorption range is 400-450 nm. The spectral absorption ranges from 400-510 nm, the spectral absorption ranges from 400-550 nm, and the spectral absorption range is 400. The silver nanoparticle assembly of -590 nm is dispersed in a mixed solvent of ethanol and water, and ultrasonic mix is ​​uniform. Among them, the mass fraction of the silver nanoparticle assembly is 20 mg / ml, and the mass fraction of ethanol in the mixed solvent is 65%.

[0069] (2) Then, the aqueous sodium carbonate solution having a concentration of 0.1 m was prepared, and the cleaned glass sheet was subjected to a water solution of the sodium carbonate, and the glass sheet was removed at 50 ° C.

[0070] (3) Place the glass sheet treated with sodium carbonate on the flat plate heating station, and the heating te...

Embodiment 2

[0073] A method for preparing a plasma resonance reversible regulatory silver nanoparticle film, including steps as follows:

[0074] (1) First, the silver nanoparticle assembly of the spectral absorption is 400-510 nm is dispersed in a mixed solvent of ethanol and water, and the ultrasonic mix is ​​uniform. Among them, the mass fraction of the silver nanoparticle assembly is 30 mg / ml, and the mass fraction of ethanol in the mixed solvent is 75%.

[0075] (2) Then, the aqueous solution of a sodium silicate having a concentration of 0.5 m was formulated, and the cleansing glass sheet was subjected to the water solution of the cleaning in the sodium silicate solution, and the glass sheet was removed at 50 ° C to dry the spare.

[0076] (3) Place the glass sheet treated with sodium carbonate on the flat plate heating station, and the heating temperature is 50 ° C, and then the sprayed flow rate is 2 ml / min, and the spray time is 5 s per square centimeter, and silver nanoparticles...

Embodiment 3

[0082] A method for preparing a plasma resonance reversible regulatory silver nanoparticle film, including steps as follows:

[0083] (1) First, the silver nanoparticle assembly of 400 to 510 nm is dispersed in a mixed solvent of ethanol and water, and ultrasonic mix is ​​uniform. Among them, the mass fraction of the silver nanoparticle assembly is 40 mg / ml, and the mass fraction of ethanol in the mixed solvent is 80%.

[0084] (2) Then, the aqueous solution of aqueous sodium borate having a concentration of 0.2 m was prepared, and the cleansing glass sheet was subjected to a water solution of the sodium borate, and the glass sheet was removed at 50 ° C.

[0085] (3) Place the glass sheet treated with sodium carbonate on the flat plate heating station, and the heating temperature is 40 ° C, and then the sprayed flow rate is 2 ml / min, and the spraying time is 5 s per square centimeter, and silver nanoparticles The assembly dispersion was sprayed onto a glass sheet to prepare a ...

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Abstract

The present invention relates to a plasma resonance reversibly regulated silver nanoparticle thin film and its preparation method and application. The plasma resonance reversibly regulated silver nanoparticle thin film includes a substrate, and the surface of the substrate is evenly provided with a strong alkali and weak acid salt covering layer. The surface of the strong alkali and weak salt covering layer is uniformly provided with a thin layer formed by stacking silver nanoparticles. Provide a substrate, immerse the substrate in an aqueous solution of strong alkali and weak acid salt, take it out, and then heat and dry it; provide a silver nanoparticle assembly dispersion, and spray the silver nanoparticle assembly dispersion on the surface of the substrate to obtain . The plasmon resonance reversible control silver nano particle thin film of the present invention has excellent SPR reversible control characteristics. The reversible color transformation of the silver nanoparticle film can be driven by the application of water vapor, breath, or even slow fingertip contact.

Description

Technical field [0001] The present invention relates to plasma resonance reversible regulatory silver nanoparticle film and its preparation method and application thereof, belonging to the technical field of intelligent film materials. Background technique [0002] Precious metal nanoparticles have important applications in surface enhanced Raman scattering signals, biometric, biometric, visual detection, color display, catalysis, and photoelectric, etc. in the field. In recent years, due to dynamic reversible regulation of precailed metal nanoparticle plasmon resonance characteristics have important applications in anti-counterfeiting, environmental testing, biological and chemical testing, it has become the focus of researchers. By functionalized modification of the surface by a single precious metal nanoparticle, the assembly is configured to form a assembly, and the pitch between adjacent nanoplasms between adjacent particles can be achieved by regulating the spacing between ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C41/24C09D1/00
CPCB29C41/24B29L2007/002C09D1/00
Inventor 王文寿刘伦涛李新典杨智民
Owner SHANDONG UNIV