Method for manufacturing artificial leather

A manufacturing method and synthetic leather technology, which is applied in chemical instruments and methods, synthetic resin layered products, textiles and papermaking, etc., can solve the problems of difficult synthetic leather and time required, and achieve the effect of shortening the manufacturing time and realizing labor saving

Active Publication Date: 2020-05-05
DIC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since a crosslinking agent and an organic solvent are required, time is required for the crosslinking step of the crosslinking agent and the drying step of the organic solvent, and it is difficult to obtain practically usable synthetic leather in a short period of time.

Method used

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  • Method for manufacturing artificial leather
  • Method for manufacturing artificial leather

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0038] Hereinafter, the present invention will be described in more detail using examples.

Synthetic example 1

[0039] [Synthesis Example 1] Synthesis of Urethane Prepolymer (A-1)

[0040] In the reaction vessel equipped with thermometer, stirrer, inert gas inlet and reflux cooler, add the polyoxytetramethylene glycol (number average molecular weight; 1000) of 250 mass parts, the polyester polyol of 250 mass parts ( The reaction product of 1,6-hexanediol and adipic acid, number average molecular weight; 2000) was dehydrated under reduced pressure until the moisture content became 0.05% by mass or less.

[0041] Next, 133 parts by mass of 4,4'-diphenylmethane diisocyanate was added, the temperature was raised to 110° C., and the reaction was carried out for about 2 hours until the content rate of isocyanate groups became constant to obtain a urethane prepolymer ( A-1).

Embodiment 1

[0043] After the urethane prepolymer (A-1) was melted at 110°C, it was placed on the release paper of the roll coater at 0.2kg / m 2 After the amount of coating is applied, it is bonded with a non-woven fabric impregnated with urethane resin (hereinafter referred to as "impregnated non-woven fabric") in a viscous state. Stand for 2 days to obtain synthetic leather.

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Abstract

The present invention addresses the problem of providing a method for manufacturing an artificial leather at a practically usable level without using any organic solvent and without requiring any crosslinking step with the use of a crosslinking agent. Provided is a method for manufacturing an artificial leather, said artificial leather comprising a layer of a cured product of a moisture-curable urethane hot melt resin composition, characterized in that: the moisture-curable urethane hot melt resin composition comprises an isocyanate group-containing urethane prepolymer but is free from any crosslinking agent having a hydroxyl group and / or an amino group; and the cured product layer is formed by applying the moisture-curable urethane hot melt resin composition at a rate of 0.03-0.5 kg / m2 relative to a base material.

Description

technical field [0001] The present invention relates to a method for producing synthetic leather. Background technique [0002] Synthetic leather made of urethane resin is widely used in the manufacture of vehicle interior materials, furniture, and moisture-permeable waterproof clothing. As the above-mentioned urethane resin, N,N-dimethylformamide (hereinafter, abbreviated as "DMF") solution of polyurethane is generally used. However, the regulation of the use of DMF in Europe or mainland China has been formalized, and the reduction of its use or the shift to solvent-free has become urgent. [0003] In addition, synthetic leather is usually formed as a laminate consisting of a base fabric, a middle layer, and a skin layer as essential layers. The manufacturing method generally involves making a skin layer on a release paper, forming a middle layer on it, and passing an adhesive In the process of laminating the intermediate layer to the base fabric, it should be noted that ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06N3/14C08G18/10
CPCD06N3/14C08G18/12C08G18/4238C08G18/4854C08G18/4018C08G18/7671C09D175/06C09D175/08C08G18/10B32B27/40B32B37/025C08G18/7664C08J5/18C08J2375/08
Inventor 小松崎邦彦竹田伸吾金川善典藤原丰邦
Owner DIC CORP
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