Method for improving solid solution quantity of P of phosphorus containing high-strength IF steel through rare earth treatment

A technology of solid solution and high strength, which is applied in the field of rare earth treatment to increase the solid solution of phosphorus-containing high-strength IF steel, can solve the problems of reducing strip strength, unfavorable r value, increasing interstitial C and N atoms, etc., and achieves good stamping performance , Improve the effect of solid solution strengthening and increase the effect of solid solution

Inactive Publication Date: 2020-08-21
BAOTOU IRON & STEEL GRP
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Problems solved by technology

[0003] Phosphorus-containing IF steel mainly uses the solid-solution strengthening effect of phosphorus to improve the strength of the steel, but phosphorus is easily precipitated as FeTiP precipitated phase and segregated at the grain boundary, causing the grain boundary brittleness of the steel. The pinning effect hinders the growth of favorable {111} oriented grains and weakens the strength of the γ texture, which is unfavorable for the r value
In addition, the precipitation of Fe(Ti+Nb)P will also consume the solid-solution P element, which reduces the strength of the strip, and also consumes the Ti element, increasing the interstitial C and N atoms, and impairing the formability of the material.

Method used

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  • Method for improving solid solution quantity of P of phosphorus containing high-strength IF steel through rare earth treatment
  • Method for improving solid solution quantity of P of phosphorus containing high-strength IF steel through rare earth treatment
  • Method for improving solid solution quantity of P of phosphorus containing high-strength IF steel through rare earth treatment

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Embodiment Construction

[0018] In the hot continuous rolling production line, the production test of phosphorus-containing strengthened IF steel was carried out in adjacent batches of co-casting. The production process flow and the timing of adding rare earths are as follows: figure 1 shown. During RH vacuum treatment, the ultimate vacuum degree is ≤0.12Kpa, and the vacuum treatment time is 30 minutes in total. Because rare earths have strong oxidizing properties, in order to avoid the oxidation of oxygen brought in by other alloys during the alloying process, and to ensure the effective boron content in the steel, after aluminum deoxidation, the alloy addition sequence in the RH vacuum treatment process is Mn Iron, Ti iron, Nb iron, boron iron. 110 kg of rare earth cerium-iron alloy (with a Ce content of 10%) was added at 5 min of circulation after the alloying was completed. After the RH treatment, the sedation time is longer than 15 minutes to ensure that the inclusions fully float up. The yiel...

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Abstract

The invention discloses a method for improving the solid solution quantity of P of phosphorus containing high-strength IF steel through rare earth treatment. The method is characterized by comprises the steps that at the treatment last stage of the RH refining procedure, an alloy is added in the RH vacuum treatment process, when circulating is carried out for 5 min after alloying is finished, a rare earth cerium-iron alloy is added, and the Ce content of molten steel reaches 18 ppm. By means of the method, rear earth Ce is added into steel, Ce and active O in steel are combined to have lower gibbs free energy, and CeAlO3, Ce2O2S, Ce2O3 and other rare earth oxide, rare earth aluminate and rare earth oxysulfide can be generated extremely easily; and the rear earth Ce suppresses precipitationof the P element and the Fe(Nb+Ti)P phase, the solid solution quantity of the P element in steel can be effectively increased, the solid solution enhancement effect of the P element in the high-strength IF steel can be improved easily, and therefore the r90 value of the forming performance index can be improved easily, and the phosphorus containing high-strength IF steel has better punching performance.

Description

technical field [0001] The invention relates to the fields of steel rolling and product development, in particular to a method for increasing the P solid solution content of phosphorus-containing high-strength IF steel by rare earth treatment. Background technique [0002] With the development of automobiles in the direction of weight reduction and lightweight, automobile sheets with both high strength and ultra-deep drawing properties have been developed rapidly, and solid solution strengthened IF steel is one of the main directions for the development of high-strength IF steel at home and abroad. Because the strengthening effect of P element is good and the price is low, an appropriate amount of P element is added to IF steel and the ratio of Si and Mn elements is adjusted to improve the strength of the steel plate through solid solution strengthening. The higher the proportion of favorable texture, the higher the value of plastic strain ratio r, the better the stamping pe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/10C21C7/06C21C7/00
CPCC21C7/0006C21C7/06C21C7/10
Inventor 王皓段承轶刘妍路璐张齐敬鑫朱师伟魏慧慧陈冰晶姚熠莹张建
Owner BAOTOU IRON & STEEL GRP
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