Method for preparing large-particle baking soda by secondary carbonization method and obtained baking soda

A secondary carbonization, baking soda technology, applied in the preparation of bicarbonate, the preparation of alkali metal carbonate shape, reagents and other directions, can solve the problems of poor product quality, long reaction time, difficult to control the operation process, etc., to achieve particle size Large, easy to operate, and the effect of improving utilization

Active Publication Date: 2020-09-08
山东海天生物化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present in this patented technology describes methods for making small diameter (3/cm) carbonizable materials called BCDS that have improved efficiency compared to existing techniques such as chemical vapor deposition. By controllably adjusting certain parameters during heat treatments, these smaller sizes result in more uniformly distributed carbon structures than previously possible. These properties allow for better use of CO2. Additionally, it provides technical means for efficiently extracting valuable products from waste streams containing C02 emissions. Overall, the process involves three steps - firstly prone carbonsizing followed by carbonification, then post-treatment at temperatures below 250°C to improve conversion rates.

Problems solved by technology

Technological Problem: Current Method For Preparating Bake Spinning Solutions Using Natural alkalis involves multiple steps including dissolution into water followed by filtering or centrifugal separation processes that increase costs compared to traditional ways like producing grades from other sources. Additionally, current Crystallizable Grinding Stabilizers are expensive due to their high cost per gram of soluble calcium salt produced during manufacturing.

Method used

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  • Method for preparing large-particle baking soda by secondary carbonization method and obtained baking soda
  • Method for preparing large-particle baking soda by secondary carbonization method and obtained baking soda
  • Method for preparing large-particle baking soda by secondary carbonization method and obtained baking soda

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Embodiment 1

[0044] See attached figure 1 , a kind of secondary carbonization method of the present invention prepares the method for large particle sodium bicarbonate, comprises the following steps:

[0045] 1) get sodium carbonate and sodium bicarbonate, mix, add water, the concentration that makes sodium carbonate is 172g / L and the concentration of sodium bicarbonate is the lye of 84g / L, purifies, standby;

[0046] 2) Using a flow pump to 0.25m 3 The flow rate of step 1) is transported to the top of the pre-carbonization tower by the flow rate of step 1), so that the lye enters the pre-carbonization tower from the top of the pre-carbonization tower, and the carbon dioxide gas is 1m from the bottom of the pre-carbonization tower 3 The / h flow rate enters the pre-carbonization tower, and the lye and carbon dioxide gas undergo a pre-carbonization reaction at a reaction temperature of 10°C to obtain pre-carbonized lye;

[0047] 3) Emit the pre-carbonized lye from the bottom of the pre-car...

Embodiment 2

[0052] A kind of secondary carbonization method of the present invention prepares the method for large particle sodium bicarbonate according to attached figure 2 The shown technological process is carried out, at first, the lye after the mixing of sodium carbonate and sodium bicarbonate is stored in the lye storage tank 1, simultaneously, the mother liquor of return liquid tank 7 is also circulated to the lye storage tank 1, three common Form lye, after the lye is purified, enter the pre-carbonization tower 2 from the upper part of the pre-carbonization tower 2, and carry out pre-carbonization reaction with carbon dioxide gas, and the carbon dioxide absorbs and reacts with the raw material sodium carbonate in the pre-carbonization tower 2; the lye after the reaction , flows into the cooling tank 3 with coil cooling from the bottom of the pre-carbonization tower 2, and drops to a suitable temperature; the lye after cooling can be returned to the pre-carbonization tower 2, and t...

Embodiment 3

[0061] A kind of secondary carbonization method of the present invention prepares the method for large particle sodium bicarbonate, comprises the following steps:

[0062] 1) get sodium carbonate, add water, make the concentration of sodium carbonate and be the soda ash solution of 150g / L, add the sodium polystyrene sulfonate of 10ppm, purify, standby;

[0063] 2) Using a flow pump to 0.26m 3 The flow rate of step 1) is transported to the upper part of the pre-carbonization tower by the flow rate of step 1), so that the solution enters the pre-carbonization tower from the upper part of the pre-carbonization tower, and the carbon dioxide gas flows from the bottom of the pre-carbonization tower at 1.5m 3 The / h flow rate enters the pre-carbonization tower, and the solution and carbon dioxide gas undergo a pre-carbonization reaction at a reaction temperature of 60°C to obtain a pre-carbonized solution;

[0064] 3) Release the pre-carbonized solution from the bottom of the pre-ca...

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Abstract

The invention provides a method for preparing large-particle baking soda by a secondary carbonization method and the obtained baking soda. The method comprises the following steps of: 1) taking a sodium carbonate solution, and performing purifying; 2) enabling the solution to enter the upper part of a pre-carbonization tower, and carrying out pre-carbonization reaction with carbon dioxide gas; 3)discharging the pre-carbonized solution from the bottom of the pre-carbonization tower, and performing cooling; 4) feeding the solution obtained in step 3) into the middle part and the upper part of the carbonization tower in a multi-strand manner, feeding carbon dioxide into the middle part and the lower part of the carbonization tower in a multi-strand manner, and carrying out carbonization reaction to generate baking soda crystal mush; 5) compressing the carbon dioxide tail gas exhausted from the top of the carbonization tower, and enabling the compressed carbon dioxide tail gas to enter the lower part of the pre-carbonization tower; and 6) discharging the baking soda crystal mush from the bottom of the carbonization tower, and performing separating and drying to obtain baking soda. Large-particle baking soda is obtained through pre-carbonization, cooling and carbonization in the carbonization tower in a multi-strand feeding and multi-strand air inflow mode, and the yield of the baking soda is increased; the pre-carbonization tower absorbs the tail gas of the carbonization tower, so that the utilization rate of carbon dioxide is increased, and the economic benefit is good.

Description

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Claims

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Application Information

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Owner 山东海天生物化工有限公司
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