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Intelligent nano oil-displacing agent as well as preparation method and application thereof

A kind of oil displacement agent and nano technology, which is applied in the direction of chemical instruments and methods, earth square drilling, production fluid, etc., can solve the problems that montmorillonite does not have interface activity, reduce work efficiency, etc., achieve obvious emulsification effect and increase oil recovery rate , highly active effect

Active Publication Date: 2020-12-15
NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the compounding process requires secondary reactions, and montmorillonite itself does not have interfacial activity, which reduces work efficiency
Considering the compatibility of various agents and the stability of the system, there may be some disadvantages in the compounding process

Method used

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  • Intelligent nano oil-displacing agent as well as preparation method and application thereof
  • Intelligent nano oil-displacing agent as well as preparation method and application thereof
  • Intelligent nano oil-displacing agent as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] 1) Put the purchased hydrophobic nano-montmorillonite into a beaker, add water, and prepare a solution I with a hydrophobic nano-montmorillonite concentration of 10000 ppm;

[0053] 2) Heating deionized water in a water bath, and after the temperature reaches 30°C, weigh a certain mass of dodecyltrimethylammonium bromide and add it into deionized water, dissolve to obtain solution II;

[0054]3) After the dissolving of dodecyltrimethylammonium bromide, cetyl hydroxysulfobetaine is added to solution II, and it is mixed evenly by stirring to obtain solution III, in which dodecyl The concentration of trimethylammonium bromide is 100ppm, and the concentration of cetyl hydroxysulfobetaine is 100ppm;

[0055] 4) Place 100mL of solution I in an oil bath pre-heated to 80°C, stir for 30 minutes, and then add 15mL of solution III by dropwise addition at a rate of 1d / 5s. After the dropwise addition, continue to maintain the temperature at 80°C °C for 8 hours to obtain an intellig...

Embodiment 2

[0057] 1) Put the purchased hydrophobic nano-montmorillonite into a beaker, add water, and prepare a solution I with a hydrophobic nano-montmorillonite concentration of 5000ppm;

[0058] 2) Heating deionized water in a water bath, and after the temperature reaches 50°C, weigh a certain mass of dodecyltrimethylammonium bromide and add it into deionized water, dissolve to obtain solution II;

[0059] 3) After the dissolving of dodecyltrimethylammonium bromide, cetyl hydroxysulfobetaine is added to solution II, and it is mixed evenly by stirring to obtain solution III, in which dodecyl The concentration of trimethylammonium bromide is 300ppm, and the concentration of cetyl hydroxysulfobetaine is 600ppm;

[0060] 4) Place 100mL of solution I in an oil bath pre-heated to 50°C, stir for 30min, then add 15mL of solution III by dropwise addition at a rate of 1d / 5s. After the dropwise addition, continue to maintain the temperature at 50°C °C for 8 hours to obtain an intelligent nano o...

Embodiment 3

[0062] 1) Put the purchased hydrophobic nano-montmorillonite into a beaker, add water, and prepare a solution I with a hydrophobic nano-montmorillonite concentration of 10000 ppm;

[0063] 2) Heating deionized water in a water bath, and after the temperature reaches 30°C, weigh a certain mass of dodecyltrimethylammonium bromide and add it to deionized water, dissolve to obtain solution II;

[0064] 3) After the dissolving of dodecyltrimethylammonium bromide, cetyl hydroxysulfobetaine is added to solution II, and it is mixed evenly by stirring to obtain solution III, in which dodecyl Trimethylammonium bromide concentration is 1000ppm, cetyl sulfobetaine concentration is 1000ppm;

[0065] 4) Place 100mL of solution I in an oil bath pre-heated to 80°C, stir for 30 minutes, and then add 15mL of solution III by dropwise addition at a rate of 1d / 5s. After the dropwise addition, continue to maintain the temperature at 80°C °C for 8 hours to obtain an intelligent nano oil displacemen...

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Abstract

The invention discloses an intelligent nano oil displacement agent as well as a preparation method and application thereof. The intelligent nano oil-displacing agent comprises a montmorillonite silicate sheet layer and a cation replacement layer, the cation replacement layer is positioned between the montmorillonite silicate sheet layers; the cation replacement layer comprises a hydrophilic end and an oleophylic end; the hydrophilic end is close to the montmorillonite silicate sheet layer; the oleophylic end is far away from the montmorillonite silicate sheet layer; and the cation replacementlayer is from a quaternary ammonium salt surfactant, wherein the quaternary ammonium salt surfactant comprises betaine and long-chain alkyl ammonium halide. The intelligent nano oil-displacing agent has the advantages of high activity, obvious emulsification effect, high interfacial activity and the like.

Description

technical field [0001] The application relates to an intelligent nanometer oil displacement agent and its preparation method and application, belonging to the field of oil exploitation. Background technique [0002] At present, the thermal recovery of heavy oil has become a hot research topic, but with the complexity of reservoir conditions and the increase of production depth, the recovery rate of heavy oil reservoirs gradually decreases. How to enhance oil recovery is a current research hotspot. [0003] Chemical flooding is an important method to enhance oil recovery. Currently, the oil displacing agent used for heavy oil recovery is basically a composite oil displacing agent obtained through compounding. Its disadvantages are that it is not resistant to high temperature and high salt, and the viscosity decreases at a high temperature and high salt. The rate of viscosity decrease is super fast and the synthesis process is complicated And after compounding, the composite...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584C09K8/60C01B33/44E21B43/22
CPCC09K8/584C09K8/602C01B33/44E21B43/16C09K2208/10
Inventor 邓青春史建民王耀国
Owner NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD