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The application relates to the technical field of oilfield sewage treatment, and particularly discloses a composite water clarifying agent for oilfield sewage treatment and a preparation method thereof. The composite water clarifying agent for oilfield sewage treatment is prepared from the following raw materials: double-modified polyacrylamide, imidazoline quaternary ammonium salt graft copolymer, scale inhibitor, adsorbent, dodecyl dimethyl betaine, coagulant aid and deionized water; the double-modified polyacrylamide is obtained by double modification of 2,3-epoxypropyl trimethyl ammonium chloride and a hydrophobic monomer on polyacrylamide; and the imidazoline quaternary ammonium salt graft copolymer is a graft copolymer of imidazoline quaternary ammonium salt, acrylamide and acrylamide-2-methylpropane sulfonic acid. The composite water clarifying agent can be used for treating high-salt and high-oil sewage generated in the middle and late stages of oilfield exploitation, has the advantages of strong salt resistance, complete demulsification and good flocculation effect, can efficiently remove oil and suspended solids, ensures that the effluent meets the standards, and meets the complex sewage treatment requirements of oilfields.