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Conductive polymer composite gel and preparation method thereof

A technology of conductive polymer and composite gel, applied in gel preparation, carbon preparation/purification, chemical instruments and methods, etc., can solve the problem of easy aggregation of conductive materials, and achieve the effect of excellent conductivity

Active Publication Date: 2021-01-05
JINAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to overcome the technical problem that the conductive material is easy to aggregate in the process of preparing the gel material in the prior art, the present invention provides a method for preparing a conductive polymer composite gel

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1 Preparation of Conductive Polymer Composite Gel

[0026] (1) Cut the melamine foam into 2cm*2cm*2cm squares, rinse with ethanol and deionized water and dry at 60°C;

[0027] (2) Put the melamine foam into the tube furnace, feed nitrogen into the tube furnace until the pressure is 15MPa, raise the temperature to 500°C at 2°C / min, keep it warm for 1h; then heat at a rate of 2°C / min to 900°C, heat preservation for 2 hours; then naturally cool to room temperature to obtain three-dimensional continuous porous carbon;

[0028] (3) Immerse the three-dimensional continuous porous carbon in the gel solution for 2 hours, then transfer the gel solution soaked in the three-dimensional continuous porous carbon to a mold, and shape it at room temperature to obtain the conductive polymer composite gel.

Embodiment 2

[0029] Embodiment 2 Preparation of Conductive Polymer Composite Gel

[0030] (1) Cut the melamine foam into 2cm*2cm*2cm squares, rinse with ethanol and deionized water and dry at 60°C;

[0031] (2) Put the melamine foam into the tube furnace, feed in nitrogen until the pressure in the tube furnace is 10MPa, raise the temperature to 500°C at 2°C / min, and keep it warm for 1h; 2 The pressure in the tube furnace is 15MPa, then heated to 900°C at a heating rate of 2°C / min, and kept for 2h; then naturally cooled to room temperature to obtain a three-dimensional continuous porous carbon;

[0032] (3) Immerse the three-dimensional continuous porous carbon in the gel solution for 2 hours, then transfer the gel solution soaked in the three-dimensional continuous porous carbon to a mold, and shape it at room temperature to obtain the conductive polymer composite gel.

Embodiment 3

[0033] Example 3 Preparation of Conductive Polymer Composite Gel

[0034] (1) Cut the melamine foam into 2cm*2cm*2cm squares, rinse with ethanol and deionized water and dry at 60°C;

[0035] (2) Put the melamine foam into the tube furnace, feed nitrogen into the tube furnace until the pressure is 8MPa, raise the temperature to 500°C at 3°C / min, and keep it warm for 1h; 2 The pressure in the tube furnace is 12MPa, then heated to 800°C at a heating rate of 3°C / min, and kept for 2h; then naturally cooled to room temperature to obtain a three-dimensional continuous porous carbon;

[0036] (3) Immerse the three-dimensional continuous porous carbon in the gel solution for 2 hours, then transfer the gel solution soaked in the three-dimensional continuous porous carbon to a mold, and shape it at room temperature to obtain the conductive polymer composite gel.

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Abstract

The invention relates to the technical field of gel material preparation, and particularly discloses conductive polymer composite gel and a preparation method thereof. The preparation method of the conductive polymer composite gel comprises the following steps: (1) taking melamine foam, cleaning and drying; (2) heating melamine foam in a nitrogen or nitrogen and CO2 atmosphere for reaction to obtain three-dimensional continuous porous carbon; and (3) immersing the three-dimensional continuous porous carbon into a gel solution, and molding to obtain the conductive polymer composite gel. The conductive polymer composite gel prepared by the method successfully overcomes the technical problems that the conductive material is difficult to disperse in the gel and the conductive material is easyto gather in the traditional method. Besides, the three-dimensional continuous porous carbon is structurally connected with one another to form a continuous conductive path, so that the conductive composite gel material can be endowed with excellent conductivity.

Description

technical field [0001] The invention relates to the technical field of gel material preparation, in particular to a conductive polymer composite gel and a preparation method thereof. Background technique [0002] High-efficiency flexible conductive polymers have a wide range of application backgrounds and potentials in electronic displays, mobile energy storage devices, and bio-integration requirements. Specifically, flexible conductive polymers can be cross-linked by physical or chemical bonds of soluble polymers to prepare hydrogel materials, and then conductive fillers are incorporated into the hydrogel matrix. The prepared conductive gel material has both the flexibility of the hydrogel matrix and the high electron transfer rate brought by the filler, and is considered to be a potential candidate for the construction of a flexible electronic platform. In previous technical research, most of the carbon-based materials (such as activated carbon, graphene, carbon nanotubes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J13/00C01B32/05
CPCB01J13/0052C01B32/05
Inventor 林志丹曹琳覃彩云
Owner JINAN UNIVERSITY