Multi-stage formation method of lithium ion battery
A lithium-ion battery and a chemical formation method are applied in the field of multi-stage chemical formation of lithium-ion batteries to achieve the effects of improving film-forming effect, good film-forming effect and broad industrial application prospects.
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Embodiment 1
[0028] 1) Inject the first electrolytic solution into the battery, the first electrolytic solution accounts for 60% of the total volume of the electrolytic solution, the additive in the first electrolytic solution is vinylene carbonate, the volume percentage of vinylene carbonate 12%;
[0029] 2) 0.05C constant current charging to the first predetermined voltage, the first predetermined voltage=3.25+1.68*0.12=3.45V;
[0030] 3) Carry out constant voltage charging at the first predetermined voltage until the charging current is lower than 0.01C;
[0031] 4) injecting the second electrolytic solution, the second electrolytic solution accounts for 25% of the total volume of the electrolytic solution, the additive in the second electrolytic solution is methyl chloroformate, and the volume percentage of methyl chloroformate is 5%;
[0032] 5) 0.1C constant current charging to the second predetermined voltage, the second predetermined voltage=3.52+1.25*0.05=3.58V;
[0033] 6) Carr...
Embodiment 2
[0039] 1) Inject the first electrolytic solution into the battery, the first electrolytic solution accounts for 60% of the total volume of the electrolytic solution, the additive in the first electrolytic solution is vinylene carbonate, the volume percentage of vinylene carbonate 16%;
[0040] 2) 0.1C constant current charging to the first predetermined voltage, the first predetermined voltage=3.25+1.68*0.16=3.52V;
[0041] 3) Carry out constant voltage charging at the first predetermined voltage until the charging current is lower than 0.01C;
[0042] 4) Inject the second electrolyte, the second electrolyte accounts for 25% of the total volume of the electrolyte, the additive in the second electrolyte is methyl chloroformate, and the volume percentage of methyl chloroformate is 8%;
[0043] 5) 0.2C constant current charging to the second predetermined voltage, the second predetermined voltage=3.52+1.25*0.08=3.62V;
[0044] 6) Carry out constant voltage charging at the secon...
Embodiment 3
[0050] 1) Inject the first electrolytic solution into the battery, the first electrolytic solution accounts for 60% of the total volume of the electrolytic solution, the additive in the first electrolytic solution is vinylene carbonate, the volume percentage of vinylene carbonate 14%;
[0051] 2) 0.05C constant current charging to the first predetermined voltage, the first predetermined voltage=3.25+1.68*0.14=3.49V;
[0052] 3) Carry out constant voltage charging at the first predetermined voltage until the charging current is lower than 0.01C;
[0053] 4) Inject the second electrolyte, the second electrolyte accounts for 25% of the total volume of the electrolyte, the additive in the second electrolyte is methyl chloroformate, and the volume percentage of methyl chloroformate is 6%;
[0054] 5) 0.1C constant current charging to the second predetermined voltage, the second predetermined voltage=3.52+1.25*0.07=3.61V;
[0055] 6) Carry out constant voltage charging at the seco...
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Abstract
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