Method and system for capturing CO2 by absorption method

An absorption method, CO2 technology, applied in separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of increasing steam energy consumption, not considering regeneration energy consumption, and not conducting in-depth investigations, etc.

Pending Publication Date: 2021-02-23
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the CO obtained in this study 2 The capture rate is still less than 90% of the general requirement of industrial grade, and to achieve the requirement of industrial grade, the energy consumption will increase significantly, but it is not examined in de

Method used

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  • Method and system for capturing CO2 by absorption method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] 1) Get 100L of 30% by weight ethanolamine solution and pass it into CO 2 capture system, with 12 vol% CO 2 The flue gas phase contact (ethanolamine solution with CO 2 The mass ratio of the flue gas is 3:1), and the CO 2 Absorption and capture of decarbonized flue gas and absorption rich liquid; online monitoring of the conductivity of the absorption rich liquid, and according to the fitting equation between the concentration of the absorbent and the conductivity, the concentration of ethanolamine in the ethanolamine solution is controlled to meet the CO 2 absorption and capture;

[0053] 2) Pass compressed air (flow rate: 2L / min, contact time: 4min) into regeneration tower for desorption regeneration, contact temperature is 115°C, contact pressure is 0.18MPa; absorb lean liquid and desorb gas, desorb gas CO 2 The content is more than 98% by volume;

[0054] 3) Adjust the pressure of the regeneration tower to restore the pressure of the regeneration tower to the pre...

Embodiment 2

[0056] 1) Get 100L of 30% by weight ethanolamine solution and pass it into CO 2 capture system with 12 vol% CO 2 The flue gas phase contact (ethanolamine solution with CO 2 The mass ratio of the flue gas is 3:1), and the CO 2 Absorption and capture; get decarbonized flue gas and absorb rich liquid;

[0057] 2) Pass compressed air (flow rate 2L / min, passage time 4min) into the regeneration tower for desorption regeneration at a temperature of 120°C and a pressure of 0.2MPa; obtain the poor absorption liquid and desorption gas; monitor the conductivity of the poor absorption liquid on-line, And according to the fitting equation between the concentration of the absorbent and the conductivity, the concentration of ethanolamine in the ethanolamine solution is controlled to meet the CO 2 Absorption and capture; desorption of CO in the gas 2 The content is more than 98% by volume;

[0058] 3) Adjust the pressure of the regeneration tower to restore the pressure of the regenerati...

Embodiment 3

[0060] 1) Get 100L of 30% by weight ethanolamine solution and pass it into CO 2 capture system with 12 vol% CO 2 Flue gas contact (ethanolamine solution with CO 2 The mass ratio of the flue gas is 3:1), and the CO 2 Absorption and capture of decarbonized flue gas and absorption rich liquid; online monitoring of the conductivity of the absorption rich liquid, and according to the fitting equation between the concentration of the absorbent and the conductivity, the concentration of ethanolamine in the ethanolamine solution is controlled to meet the CO 2 absorption and capture;

[0061] 2) Pass the flue gas of the power plant (flow rate 2L / min, feed time 4min) into the regeneration tower for desorption and regeneration at a temperature of 120°C and a pressure of 0.2MPa; absorb lean liquid and desorption gas, and desorb CO in the gas 2 The content is more than 98% by volume;

[0062] 3) Adjust the pressure of the regeneration tower to restore the pressure of the regeneration t...

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Abstract

The invention relates to the field of carbon dioxide capture, and discloses a method and a system for capturing CO2 by an absorption method. The method comprises the following steps: (1) enabling an absorption liquid containing an absorbent to be in contact with CO2-containing flue gas to absorb and trap CO2 so as to obtain decarburized flue gas while enabling the absorption liquid to trap CO2 toform an absorption rich solution; (2) contacting the absorption rich solution with a carrying gas phase for desorption regeneration to obtain CO2-containing desorbed gas and a CO2-removed absorption lean solution; (3) recovering the desorbed gas, and returning the absorption lean solution to the step (1) to participate in absorption and capture, wherein the use amount of the absorbent and/or watercontained in the absorption liquid in the step (1) is determined and controlled by measuring the conductivity of the absorption rich solution and the absorption lean solution on line. According to the invention, the measurement efficiency of control parameters in the CO2 capture process through the measurement absorption method can be improved, the CO2 capture process can be better monitored fora long period, and energy consumption is reduced.

Description

technical field [0001] The invention relates to the field of carbon dioxide capture, in particular to the absorption method for capturing CO 2 methods and systems. Background technique [0002] Global warming is becoming more and more serious, especially in 2018, when high temperatures above 30°C are rare in the Arctic, carbon emission reduction is imperative. CO capture by solvent method 2 It is currently the most mature CO that is most likely to be promoted on a large scale 2 Capture technology, the concentration of the absorption liquid in the solution capture technology has an effect on CO 2 The trapping effect is greatly affected, and the concentration of the absorbent is always affected by various factors in actual operation, so it is difficult to keep the concentration of the absorbing liquid constant. [0003] CN102553396A provides a method for capturing carbon dioxide in power station flue gas with high efficiency and low energy consumption, including: 1) mixing...

Claims

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Application Information

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IPC IPC(8): B01D53/14B01D53/18
CPCB01D53/1475B01D53/1493B01D53/1425B01D53/1418B01D53/18B01D2252/20478B01D2252/204B01D2252/30B01D2252/202B01D2258/0283Y02C20/40Y02A50/20
Inventor 王保登赵兴雷崔倩曹子雄李永龙顾佑宗
Owner CHNA ENERGY INVESTMENT CORP LTD
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