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Method for removing aniline, chromium and antimony in wastewater

A wastewater and aniline technology, applied in chemical instruments and methods, water pollutants, water/sewage treatment, etc., can solve the problems of difficult to meet discharge standards, complex wastewater components, etc., and achieve the effect of less dosage and economical removal rate

Active Publication Date: 2022-07-05
GUANGZHOU UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the composition of actual wastewater is complex, and the treated effluent often contains low concentrations of anilines, chromium (VI) and antimony, making it difficult to meet the discharge standards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A printing and dyeing wastewater, wherein the content of aniline is 2.3 mg / L, the content of chromium (VI) is 1.5 mg / L, and the content of antimony is 0.5 mg / L.

[0045] A method for removing aniline, chromium and antimony in wastewater, comprising the following steps:

[0046] S1: Take 500mL of the above waste water, filter out the insoluble matter, use H 2 SO 4 solution and NaOH solution to adjust the pH value to 4, add sodium persulfate (Na 2 S 2 O 8 ) to sodium persulfate (Na 2 S 2 O 8 ) concentration is 5mmol / L, mix well;

[0047]S2: Add 1 g of MIEX magnetic resin (commercially available MIEX resin provided by Orica Company, 150-180 μm) to the above-mentioned waste water, stir for 1 h, adjust the pH value to 9 with NaOH, stir evenly and let stand for 40 min;

[0048] S3: The supernatant is separated, and the precipitate is recovered.

[0049] According to the method provided by GB11889-1989 "N-(1-naphthyl) ethylenediamine azo spectrophotometric method for ...

Embodiment 2

[0053] A printing and dyeing wastewater, wherein the content of aniline is 3.5 mg / L, the content of chromium (VI) is 2.7 mg / L, and the content of antimony is 0.9 mg / L.

[0054] A method for removing aniline, chromium and antimony in wastewater, comprising the following steps:

[0055] S1: Take 500mL of the above waste water, filter out the insoluble matter, use H 2 SO 4 solution and NaOH solution to adjust the pH value to 3, add sodium persulfate (Na 2 S 2 O 8 ) to sodium persulfate (Na 2 S 2 O 8 ) concentration is 5mmol / L, mix well;

[0056] S2: add 1.2 g of MIEX magnetic resin (commercially available MIEX resin provided by Orica company, 150-180 μm) to the above-mentioned waste water, stir for 1.5 h, adjust the pH value to 10 with NaOH, stir evenly and let stand for 45 min;

[0057] S3: The supernatant is separated, and the precipitate is recovered.

[0058] In the supernatant liquid, according to the method provided by GB11889-1989 "Determination of anilines in wat...

Embodiment 3

[0062] A printing and dyeing wastewater, wherein the content of aniline is 4.3 mg / L, the content of chromium (VI) is 3.8 mg / L, and the content of antimony is 1.1 mg / L.

[0063] A method for removing aniline, chromium and antimony in wastewater, comprising the following steps:

[0064] S1: Take 500mL of the above waste water, filter out the insoluble matter, use H 2 SO 4 solution and NaOH solution to adjust the pH value to 3, add sodium persulfate (Na 2 S 2 O 8 ) to sodium persulfate (Na 2 S 2 O 8 ) concentration is 10mmol / L, mix well;

[0065] S2: add 1.8g of MIEX magnetic resin (commercially available Orica company provides MIEX resin, 150-180μm) to the above waste water, stir for 1.5h, adjust the pH value to 9 with NaOH, stir evenly and let stand for 50min;

[0066] S3: The supernatant is separated, and the precipitate is recovered.

[0067] According to the method provided by GB11889-1989 "Determination of Anilines in Water Quality N-(1-naphthyl)ethylenediamineazo ...

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Abstract

The invention provides a method for removing aniline, chromium and antimony in wastewater. The waste water treated by this method adopts GB 11889-1989 "Determination of water quality anilines N-(1-naphthyl) ethylenediamine azo spectrophotometry" to measure aniline content<1.0mg / L; adopt GB 7467-1987 The content of hexavalent chromium <0.5mg / L was measured in "Determination of Hexavalent Chromium in Water Quality by Diphenylcarbazide Spectrophotometry"; antimony was measured by HJ 1047‑2019 "Determination of Antimony in Water Quality by Graphite Furnace Atomic Absorption Spectrophotometry" The content is less than 0.05mg / L, which meets the emission standard.

Description

technical field [0001] The invention belongs to the technical field of wastewater treatment, in particular to a method for removing aniline, chromium and antimony in wastewater. Background technique [0002] The development of textile dyeing and finishing industry has brought about the problem of printing and dyeing wastewater. With the wide application of new dyes and auxiliaries, the composition of printing and dyeing wastewater is more complex. It will contain aniline substances, as well as heavy metals such as chromium and antimony. [0003] Aniline substances are usually produced by biochemical treatment of benzidine azo dyes in dye wastewater, and these substances have strong carcinogenic, teratogenic and mutagenic effects. Heavy metal chromium comes from potassium dichromate, which is a key oxidant in printing process and dye fixation in wool dyeing, and also has strong carcinogenic, teratogenic and mutagenic effects. Antimony and its compounds in the printing and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/12C02F101/38C02F101/20C02F101/22
CPCC02F9/00C02F1/72C02F1/42C02F1/488C02F1/66C02F1/52C02F2101/38C02F2101/20C02F2101/22C02F2209/06C02F2305/023
Inventor 张平石正琴费颖恒刘煜李伙生李笛姚焱
Owner GUANGZHOU UNIVERSITY