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A method for anti-condensation in the process of reusing dry calcium carbide slag

A carbide slag and anti-condensation technology, which is applied in separation methods, chemical instruments and methods, and solid waste removal, etc. The problem of high cost, to achieve the effect of improving moisture absorption and condensation performance, reducing equipment maintenance frequency, good economic and social value

Active Publication Date: 2021-07-27
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the separation process, the residual moisture in the dry calcium carbide slag will be redistributed during the interaction with the gas, enriched, condensed, and even hardened inside the equipment, causing equipment damage, which is not conducive to the resource utilization of dry calcium carbide slag , is a technical problem that needs to be solved urgently
[0003] CN104190243A discloses a method and equipment for desulfurizing calcium carbide slag in a coal-fired boiler. The method includes drying the calcium carbide slag until the moisture content is less than 2wt%; blowing the calcium carbide slag into the furnace of the coal-fired boiler with a Roots blower, The blowing position is the secondary air inlet elbow under the front and rear walls of the furnace, and the number of blowing points is 4 on each of the front and rear walls of the furnace. The dried calcium carbide slag is directly used for desulfurization in the furnace, but the cost of drying treatment is high
[0004] CN107213779A discloses a production system and production process of calcium carbide slag desulfurizer. The production system includes: calcium carbide slag drying and crushing system, tail gas treatment system and collection and storage system, and calcium carbide slag is used as Desulfurization agent in the furnace, but the residual moisture is treated by drying, and the cost of drying is relatively high
[0005] CN108704470A discloses a calcium carbide slag composite calcium-based desulfurizer based on biomass conditioning and its preparation method. The desulfurizer utilizes biomass to mix with wet carbide slag to adjust the moisture in the wet carbide slag, thereby eliminating the need for heating and drying processes. Solve the problem of entering the furnace of wet calcium carbide slag under certain conditions, but it takes a long time for air-drying and tempering

Method used

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  • A method for anti-condensation in the process of reusing dry calcium carbide slag

Examples

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Effect test

Embodiment 1

[0035]This example provides a method for anti-condensation during the reutilization of dry calcium carbide slag. The method includes adding a dehumidifier in the impurity removal process of preparing the desulfurizer, wherein the desulfurizer is prepared by winnowing, and the dehumidifier is 90wt % calcium oxide and 10wt% anhydrous calcium sulfate, mixed dry carbide slag and desiccant in the raw material storage device, wherein the moisture content of the dry carbide slag is 5wt%, and the particle size of the dry carbide slag is less than 100 microns The particle content is 85wt%, and the content of particles with a particle size <50 microns in the dry process carbide slag is 50 wt%, the mass ratio of the desiccant to the dry process carbide slag is 0.05:1, and the particles with a particle size <50 microns in the desiccant The content of particles is 95wt%; and the content of particles with a particle diameter of <20 microns in the desiccant is 55wt%.

Embodiment 2

[0037] This example provides a method for anti-condensation during the reutilization of dry calcium carbide slag. The method includes adding a dehumidifier in the impurity removal process of preparing the desulfurizer, wherein the desulfurizer is prepared by winnowing, and the dehumidifier is 15wt % calcium oxide, 70wt% anhydrous calcium sulfate, 10wt% magnesium sulfate and 5wt% sodium sulfate, mixed dry carbide slag and desiccant at the feed inlet, wherein the moisture content of dry carbide slag is 4.2wt %, the particle content of particle diameter<100 microns in the dry process carbide slag is 90wt%, and the particle content of particle diameter<50 microns in the dry process carbide slag is 45wt%, and the mass ratio of desiccant and dry process carbide slag is 0.02: 1. The content of particles with a particle size <50 microns in the desiccant is 85 wt%, and the content of particles with a particle size <20 microns in the desiccant is 45 wt%.

Embodiment 3

[0039] This example provides a method for anti-condensation during the reutilization of dry calcium carbide slag. The method includes adding a dehumidifier in the impurity removal process of preparing the desulfurizer, wherein the desulfurizer is prepared by winnowing, and the dehumidifier is 85wt % of calcium oxide, 10wt% of anhydrous calcium sulfate and 5wt% of sodium hydroxide, mixed dry carbide slag and desiccant in the delivery pipeline, wherein the moisture content of dry carbide slag is 3wt%, in dry carbide slag The content of particles with a particle size of <100 microns is 75wt%, and the content of particles with a particle size of <50 microns in the dry-process carbide slag is 33wt%, and the mass ratio of the desiccant to the dry-process carbide slag is 0.007:1. In the desiccant The content of particles with a particle diameter of <50 microns is 90 wt%, and the content of particles with a particle diameter of <20 microns in the desiccant is 40 wt%.

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Abstract

The invention provides a method for anti-condensation in the process of reusing dry calcium carbide slag. The method includes adding a dehumidifier in the impurity removal process of the dry process carbide slag reuse process, and mixing the dry calcium carbide slag and the dehumidifier. In the desiccant, the content of particles with a particle diameter of <50 microns is ≥80wt%, and the content of particles with a particle diameter of <20 microns in the desiccant is ≥40wt%. The short-range resource utilization technology of dry calcium carbide slag reduces the risk of bag dust and corrosion on the surface of the bag filter, and reduces the frequency of equipment maintenance. The method is simple and does not affect product performance, effectively solving the problem of dry calcium carbide slag. Difficulties in the process of slag recovery have good economic and social value.

Description

technical field [0001] The invention relates to the technical field of resource recycling, in particular to a method for anti-condensation during the reutilization of dry calcium carbide slag. Background technique [0002] Carbide slag is solid waste produced during the process of preparing acetylene from calcium carbide and water. The polyvinyl chloride (PVC) industry discharges 18 million tons of carbide slag every year. The main component of calcium carbide slag is calcium hydroxide, the content can reach 80~90wt%, which has great potential utilization value, but the residual impurity particles will affect the efficiency of the desulfurization process and the quality of the by-product desulfurization gypsum on the one hand, and on the other hand, the coarse Hard and large-particle impurities will cause wear and tear on equipment, so the recycling of calcium carbide slag first needs to separate and process the impurities through mechanical and gravity methods. In the sepa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09B3/00B01D53/48B01D53/81C01F11/02C01F11/18
CPCB01D53/48B01D53/81B01D2251/304B01D2251/306B01D2251/404B01D2251/602B01D2251/604B01D2251/606B01D2251/608B09B3/00C01F11/02C01F11/18
Inventor 李会泉李少鹏颜坤朱干宇孟子衡
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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