Aqueous binder composition
A technology of water-based adhesives and compositions, applied in the directions of lignin adhesives, adhesive types, adhesives, etc., can solve problems such as expensive and expensive adhesives
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[0234] In the following examples, several adhesives falling within the limits of the invention were prepared and compared with adhesives according to the prior art.
[0235] For the adhesive according to the invention and the adhesive according to the prior art, the following properties were respectively determined:
[0236] Solids Content of Adhesive Components
[0237] Prior to curing, the amounts of individual components in a given binder solution are based on the anhydrous mass of the components.
[0238] Reaction Loss – Definition
[0239] Reaction loss is defined as the difference between the solids content of the binder components and the binder solids
[0240] Therefore, the reaction loss is calculated by:
[0241] Reaction Loss = (Binder Component Solids - Binder Solids) / (Binder Component Solids)
[0242] Kraft Lignin by UPM to LignoBoost TMSupplied, UPM BioPiva 100 as a powder, oxidized kraft lignin based on UPM BioPiva 100 (AOL) was supplied by Aarhus Universit...
Embodiment B
[0333] Example B - Scale-up of lignin oxidation in ammonia with hydrogen peroxide to pilot scale
[0334] Oxidation of lignin with hydrogen peroxide is an exothermic process, and even at the laboratory scale, the addition of peroxide increases the temperature significantly. This is a natural problem when scaling up chemical processes, since the heat generated scales with the third power of size (volume), whereas cooling typically only increases with the square of the size (area). Additionally, due to the high viscosity of the adhesive intermediate, process equipment must be carefully selected or designed. Therefore, the amplification is carefully designed and performed in several steps.
[0335] The first scale-up step is from 1 liter (laboratory scale) to 9 liters using a professional stainless steel mixer with very efficient mechanical agitation. Scale-up resulted in only slightly higher final temperatures than those obtained at laboratory scale, which was attributed to ef...
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