A clean silicone wristband and its production process
A clean wristband technology, applied to watch straps, bracelets, clothing, etc., can solve the problems of single function of silicone wristbands and insufficient development of silicone wristband functions, so as to achieve diversified functions and improve the ability to withstand alcohol , the effect of increasing strength
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preparation example 1
[0057] Preparation of polystyrene-modified nano-silica:
[0058] Mix 1000g of nano-silica with 10kg of ethanol, add 300g of KH550 dropwise at 55°C for 1 hour, continue to stir for 3h, filter and dry in a 55°C oven for 1h to obtain KH550 modified nano-silica ;
[0059] Mix 10g azobisisobutyronitrile and 500g ethanol into a catalyst solution, mix 1000g KH550 modified nano-silica, 1500g styrene, 200g polyvinylpyrrolidone, 100g water and 9.5kg ethanol, then add dropwise at 50°C The catalyst solution was added dropwise for 1 h, and the stirring reaction was continued for 7 h. After the reaction, the solution was filtered and dried in an oven at 55° C. for 1 h to obtain polystyrene modified nano-silica.
preparation example 2
[0061] Preparation of polystyrene-modified nano-silica:
[0062] Mix 1000g of nano-silica with 12kg of ethanol, add 450g of KH550 dropwise at 70°C, after 1h of dropwise addition, continue to stir for 1h, filter and dry in a 55°C oven for 1h to obtain KH550 modified nano-silica ;
[0063] Mix 20g azobisisobutyronitrile and 500g ethanol into a catalyst solution, mix 1000g KH550 modified nano-silica, 2000g styrene, 400g polyvinylpyrrolidone, 300g water and 11.5kg ethanol, then add dropwise at 65°C The catalyst solution was added dropwise for 1 h, and the stirring reaction was continued for 9 h. After the reaction, it was filtered and dried in an oven at 55° C. for 1 h to obtain polystyrene-modified nano-silica.
preparation example 3
[0065] Preparation of polystyrene-modified nano-titanium dioxide:
[0066] Mix 1000g of nano titanium dioxide with 12kg of ethanol, add 450g of KH550 dropwise at 70°C, after 1 hour of dropwise addition, continue to stir and react for 1 hour, filter and dry in a 55°C oven for 1 hour to obtain KH550 modified nano-titanium dioxide;
[0067] Mix 20g azobisisobutyronitrile and 500g ethanol into a catalyst solution, mix 1000g KH550 modified nano-titanium dioxide, 2000g styrene, 400g polyvinylpyrrolidone, 300g water and 11.5kg ethanol, and then add the catalyst solution dropwise at 65°C , 1h was added dropwise, and the stirring reaction was continued for 9h. After the reaction, the reaction was filtered and dried in an oven at 55° C. for 1h to obtain polystyrene-modified nano-titanium dioxide.
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