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Preparation and application of silver ferrite/silver vanadate composite photocatalyst

A silver vanadate, composite light technology, applied in catalyst activation/preparation, physical/chemical process catalyst, metal/metal oxide/metal hydroxide catalyst, etc. Catalytic activity limitation and other problems, to achieve the effect of stable photocatalytic performance, high photocatalytic activity and easy control of conditions

Active Publication Date: 2021-10-22
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ag 3 VO 4 Although exhibiting high photocatalytic performance, its photocatalytic activity is limited due to the low separation efficiency of photogenerated electrons and holes

Method used

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  • Preparation and application of silver ferrite/silver vanadate composite photocatalyst
  • Preparation and application of silver ferrite/silver vanadate composite photocatalyst
  • Preparation and application of silver ferrite/silver vanadate composite photocatalyst

Examples

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Embodiment example 1

[0028] The invention discloses a silver ferrite / silver vanadate p-n heterojunction composite photocatalyst. The silver ferrite / silver vanadate p-n heterojunction composite photocatalyst uses silver vanadate as a carrier and uses silver ferrite to modify the silver vanadate.

[0029] In this embodiment, the silver ferrite / silver vanadate composite photocatalyst has a mass percentage of 1 wt% of silver ferrite in silver vanadate.

[0030] In this embodiment, the silver ferrite is a nano particle, which is a p-type semiconductor, and the silver vanadate is a micron particle, which is an n-type semiconductor.

[0031] The preparation method of described silver ferrite / silver vanadate composite photocatalyst comprises the following steps:

[0032] Weigh 0.808 g of ferric nitrate and 0.340 g of silver nitrate in 50 mL of ultrapure water, stir in the dark for 10 min, add 10 mL of 60 g / L NaOH solution to the solution, continue stirring for 30 min, pour the solution into Put it into a...

Embodiment example 2

[0039]A silver ferrite / silver vanadate composite photocatalyst, which is basically the same as the implementation case 1, the only difference is that in the silver ferrite / silver vanadate composite photocatalyst of the implementation case 2, the mass percentage of silver ferrite to silver vanadate is 2 %.

[0040] A preparation method of the silver ferrite / silver vanadate composite photocatalyst of the above-mentioned embodiment is basically the same as the preparation method of Example 1, the only difference being that the mass of silver ferrite used in Example 2 is 0.0038 g.

[0041] The silver ferrite / silver vanadate composite photocatalyst prepared in Example 2 was named 2 wt% AFO / AVO.

Embodiment example 3

[0043] A silver ferrite / silver vanadate composite photocatalyst, which is basically the same as the implementation case 1, the only difference is that in the silver ferrite / silver vanadate composite photocatalyst of the implementation case 3, the mass percentage of silver ferrite to silver vanadate is 3 %.

[0044] A preparation method of the silver ferrite / silver vanadate composite photocatalyst of the above-mentioned embodiment is basically the same as the preparation method of Example 1, the only difference being that the mass of silver ferrite used in Example 3 is 0.0057 g.

[0045] The silver ferrite / silver vanadate composite photocatalyst prepared in Example 3 was named 3 wt% AFO / AVO.

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Abstract

The invention belongs to the field of functional materials, and particularly relates to preparation and application of a silver ferrite / silver vanadate composite photocatalyst. The composite photocatalyst is formed by compounding silver ferrite nanoparticles on micron-sized silver vanadate particles, and the silver ferrite / silver vanadate composite photocatalyst is synthesized by adopting a two-step hydrothermal method in the preparation process. Compared with silver vanadate and silver ferrite, the photocatalytic activity of the silver ferrite / silver vanadate composite photocatalyst is obviously improved. The silver ferrite / silver vanadate composite photocatalyst has the advantages of simple preparation method, easily controlled conditions, good photocatalytic activity and the like, is a novel photocatalyst and is successfully applied to dye degradation.

Description

technical field [0001] The invention belongs to the field of functional materials, specifically the field of photocatalysis, and relates to the preparation and application of a silver ferrite / silver vanadate composite photocatalyst. Background technique [0002] Heterogeneous photocatalysis is one of the greenest and most effective methods to solve energy shortage and environmental problems, and has received extensive attention from researchers. In the past few decades, more and more photocatalysts have been developed, including TiO 2 , ZnO, Ta 2 o 5 and CuO. However, most of them have high charge carrier recombination rate and no response in the visible range, and heterojunction photocatalysts are an effective way to overcome the above defects. [0003] Ag 3 VO 4 is a p-type semiconductor with 2.3 eV, which has attracted much attention due to its good photocatalytic activity under visible light irradiation. Ag 3 VO 4 Although exhibiting high photocatalytic perfor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/89B01J37/10C02F1/30C02F101/30C02F101/34C02F101/38
CPCB01J23/898B01J37/10C02F1/30C02F2101/30C02F2101/34C02F2101/38C02F2305/10C02F2101/308B01J35/39B01J35/23Y02W10/37
Inventor 陈志鑫蔡燕卿刘明华肖光参何运慧
Owner FUZHOU UNIV