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Metal glaze as well as preparation method and application method thereof

An application method, the technology of metal glaze, applied in the field of ceramic glaze, can solve the problems of difficult appearance of metal luster, poor stability of metal effect, poor metal effect, etc., and achieve the effect of improving the excellent rate, showing stability, and reducing crystallization conditions

Active Publication Date: 2021-11-02
FOSHAN SANSHUI CREATE TIDE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] One of the purposes of the present invention is to overcome the deficiencies of the prior art and provide a metallic glaze to solve the problems of the existing metallic glazes that the metallic luster is not easy to appear and the stability of the metallic effect is poor
[0006] The third object of the present invention is to provide a method for applying a metal glaze, that is, to apply the above-mentioned metal glaze or the metal glaze obtained by the above-mentioned method for preparing a metal glaze to prepare ceramic rock slabs, so as to solve the existing problems. The metal effect of the ceramic rock plate is not good, and the glaze has many defects, and it can present a three-dimensional effect on the ceramic rock plate

Method used

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  • Metal glaze as well as preparation method and application method thereof
  • Metal glaze as well as preparation method and application method thereof
  • Metal glaze as well as preparation method and application method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A kind of metallic glaze of the present embodiment, the weight percent of its each raw material is:

[0048] Albite 37%, quartz 15%, wollastonite 2%, calcined kaolin 9%, calcined zinc oxide 4%, calcined iron phosphate 19%, self-made high phosphorus frit powder 14%.

[0049] Among them, the weight percentage of each raw material in the self-made high phosphorus frit powder is: aluminum dihydrogen phosphate 40%, phosphate rock powder 15%, sodium carbonate 12%, calcined kaolin 9%, potassium carbonate 13%, alumina 11%.

[0050] The preparation method of this metallic glaze comprises the following steps:

[0051] Step S11, preparing self-made high-phosphorus frit powder: weighing according to the above formula of self-made high-phosphorus frit powder, mixing the weighed raw materials evenly in a mixer, and then melting in a high-temperature frit furnace, the melting process The heating rate in the medium is 10°C / min, the maximum temperature is 1000°C, and the holding time i...

Embodiment 2

[0057] A kind of metallic glaze of the present embodiment, the weight percent of its each raw material is:

[0058] Albite 35%, quartz 8%, wollastonite 4%, calcined kaolin 11%, calcined zinc oxide 4%, calcined iron phosphate 23%, self-made high phosphorus frit powder 15%.

[0059] Among them, the weight percentage of each raw material in the self-made high phosphorus frit powder is: aluminum dihydrogen phosphate 48%, phosphate rock powder 10%, sodium carbonate 11%, calcined kaolin 5%, potassium carbonate 12%, alumina 14%.

[0060] The preparation method of this metallic glaze comprises the following steps:

[0061] Step S11, preparing self-made high-phosphorus frit powder: weighing according to the above formula of self-made high-phosphorus frit powder, mixing the weighed raw materials evenly in a mixer, and then melting in a high-temperature frit furnace, the melting process The heating rate in the medium is 10°C / min, the maximum temperature is 1050°C, and the holding time i...

Embodiment 3

[0067] A kind of metallic glaze of the present embodiment, the weight percent of its each raw material is:

[0068] Albite 34%, quartz 10%, calcined kaolin 16%, calcined zinc oxide 4%, calcined iron phosphate 23%, homemade high phosphorus frit powder 13%.

[0069] Among them, the weight percentage of each raw material in the self-made high phosphorus frit powder is: aluminum dihydrogen phosphate 30%, phosphate rock powder 25%, sodium carbonate 15%, calcined kaolin 5%, potassium carbonate 15%, alumina 10%.

[0070] The preparation method of this metallic glaze comprises the following steps:

[0071] Step S11, preparing self-made high-phosphorus frit powder: weighing according to the above formula of self-made high-phosphorus frit powder, mixing the weighed raw materials evenly in a mixer, and then melting in a high-temperature frit furnace, the melting process The heating rate in the medium is 10°C / min, the highest temperature is 1060°C, and the holding time is 5h. After stopp...

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Abstract

The invention belongs to the technical field of ceramic glaze, and relates to metal glaze as well as a preparation method and an application method thereof. The metal glaze comprises the following raw materials in percentage by weight: 30-37% of albite, 8-15% of quartz, 0-4% of wollastonite, 9-16% of calcined kaolin, 4-6% of calcined zinc oxide, 19-23% of calcined iron phosphate and 13-20% of self-made high-phosphorus frit powder. On the basis of calcined iron phosphate, self-made high-phosphorus frit powder is added as a crystallization accelerant into the metal glaze, so that the metal luster is more easily presented. The element P is introduced into the self-made high-phosphorus frit powder in a frit form, and compared with a high-phosphorus raw material system, the self-made high-phosphorus frit powder has a wider firing temperature range, and the metal effect is more stably presented. By finely adjusting the ratio of the self-made high-phosphorus frit powder to the silicon-aluminum of the metal glaze, the adjustment of metal to different colors can be realized. In addition, the metal glaze is combined with a roller printing process, so that the glaze surface can present a good three-dimensional effect.

Description

technical field [0001] The invention relates to the technical field of ceramic glazes, in particular to a metal glaze, a preparation method and an application method thereof. Background technique [0002] Decorative metal materials are highly sought after by consumers because of their gorgeous and precious decorative styles, but their high price and poor acid and alkali resistance limit their application scenarios. With the innovation of preparation technology of decorative materials, architectural ceramics with metallic effects are widely used because of their realistic metallic luster and excellent corrosion resistance. [0003] Among them, the metal glaze is a special crystal glaze. There are four methods of preparing metallic glazes in the ceramic industry: coating pyrolysis and imitation gold technology, thermal spraying, evaporation and sintering. The sintering method is the most common method for preparing metallic glazes. Usually, transition metal oxides (such as C...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/14C03C8/08C04B41/89
CPCC03C8/14C03C8/08C04B41/89C04B41/52C04B41/5022C04B41/4539C04B41/4543
Inventor 肖元成王衔雯周军张天杰戴建斌黄文辉张丹肖永平
Owner FOSHAN SANSHUI CREATE TIDE
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