Hydrogel with wet-state adhesion property as well as preparation method and application thereof

A hydrogel and performance technology, applied in the direction of adhesives, adhesive types, grafted polymer adhesives, etc., can solve problems such as insufficient adhesion strength, loss of adhesion performance, weak adhesion of hydrogels, etc. , to achieve the effects of simple preparation method, excellent mechanical properties and excellent adhesion properties

Inactive Publication Date: 2021-12-07
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, hydrogel is easy to absorb water, and a water film will be formed between the hydrogel and the substrate, which will greatly reduce the adhesion of the hydrogel to the substrate, especially in wet conditions and water environments. However, traditional hydrogels tend to lose their adhesive properties completely, which limits the application of hydrogels to a large extent.
[0003] In recent years, researchers have done a lot of research on the wet adhesion of hydrogels, and developed some hydrogels that can be used in wet environments, but these hydrogels still have obvious defects or deficiencies. It is mainly manifested in the following aspects: 1) The adhesion of hydrogel is still weak in a wet environment, and the adhesion strength is not enough; 2) It has certain toxicity, which is not safe and environmentally friendly; 3) Hydrogel is easy to appear Significant swelling, eventually deformed

Method used

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  • Hydrogel with wet-state adhesion property as well as preparation method and application thereof
  • Hydrogel with wet-state adhesion property as well as preparation method and application thereof
  • Hydrogel with wet-state adhesion property as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A kind of hydrogel with wet state adhesion performance, its preparation method comprises the following steps:

[0043] Disperse 100g of acrylic acid in 400mL of deionized water, then add 10g of quaternized xylan, 4.5g of tannic acid and 0.2g of N,N'-methylenebisacrylamide, stir well, and then add 0.5 g of ammonium persulfate was stirred evenly, and then the obtained mixture was poured into a mold, and cross-linked at 55° C. for 4 hours to obtain a hydrogel with wet adhesion properties.

Embodiment 2

[0045] A kind of hydrogel with wet state adhesion performance, its preparation method comprises the following steps:

[0046] Disperse 100g of acrylic acid in 230mL of deionized water, then add 20g of quaternized xylan, 5g of tannic acid and 0.3g of N,N'-methylenebisacrylamide, stir well, and then add 0.6 gram of ammonium persulfate, stirred evenly, then poured the obtained mixture into a mold, and cross-linked at 60°C for 6 hours to obtain a hydrogel with wet adhesion properties.

Embodiment 3

[0048] A kind of hydrogel with wet state adhesion performance, its preparation method comprises the following steps:

[0049] Disperse 100g of acrylic acid in 150mL of deionized water, then add 30g of quaternized xylan, 5.5g of tannic acid and 0.4g of N,N'-methylenebisacrylamide, stir well, and then add Stir 0.8g of ammonium persulfate evenly, then pour the obtained mixture into a mold, and cross-link at 70°C for 7 hours to obtain a hydrogel with wet adhesion properties.

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Abstract

The invention discloses hydrogel with wet-state adhesion property as well as a preparation method and application thereof. The hydrogel with the wet-state adhesion property is prepared from the following raw materials in parts by mass: 100 parts of acrylic acid, 10 parts to 30 parts of quaternized xylan, 3 parts to 6 parts of tannic acid, 0.1 part to 1 part of a cross-linking agent, 0.1 part to 1 part of an initiator, and 150 parts to 400 parts of water. The hydrogel disclosed by the invention has excellent mechanical property and underwater adhesion property, and is environment-friendly, the preparation method is simple, and industrial large-scale production is easy to realize.

Description

technical field [0001] The invention relates to the technical field of hydrogel materials, in particular to a hydrogel with wet-state adhesion performance and a preparation method and application thereof. Background technique [0002] Hydrogel is a material with a three-dimensional network structure produced by hydrophilic polymers through physical or chemical reactions. It also has certain fluidity while maintaining mechanical properties, and has a structure similar to that of natural extracellular matrix. structure, so it has excellent application prospects in the fields of wearable biosensors, bioadhesives, medical dressings, etc. However, hydrogel is easy to absorb water, and a water film will be formed between the hydrogel and the substrate, which will greatly reduce the adhesion of the hydrogel to the substrate, especially in wet conditions and water environments. Among them, conventional hydrogels tend to lose their adhesive properties completely, which limits the ap...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00C08F220/06C08F222/38C08F2/44C09J151/02C09J11/06
CPCC08F251/00C08F2/44C09J151/02C09J11/06C08F220/06C08F222/385C08K5/1545
Inventor 刘昕昕常敏敏任俊莉
Owner SOUTH CHINA UNIV OF TECH
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