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Method for separating PVC (Polyvinyl Chloride) and PS (Poly Styrene) from mixed waste plastic

A technology of mixing plastics and waste plastics, which is applied in the field of polystyrene and polyvinyl chloride, and can solve the problems of low dissolution rate, low efficiency and slow dissolution speed of PVC plastics, and achieve less pollutants, high efficiency and good effect Effect

Pending Publication Date: 2021-12-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to solve the problem of low dissolution rate of PVC plastics or slow dissolution rate and low efficiency when solvents are used to separate waste plastics in the prior art, and to provide a simple and efficient method for separating PVC and PS

Method used

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  • Method for separating PVC (Polyvinyl Chloride) and PS (Poly Styrene) from mixed waste plastic
  • Method for separating PVC (Polyvinyl Chloride) and PS (Poly Styrene) from mixed waste plastic
  • Method for separating PVC (Polyvinyl Chloride) and PS (Poly Styrene) from mixed waste plastic

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Add mixed plastic A with a particle size of 4 mm into the methyl ethyl ketone solvent, and the ratio of plastic to solvent is 0.1 g / ml. At a temperature of 70°C, stir mechanically for 60 minutes. Filter the solution with a 150-mesh screen, and dry the filtered residue to obtain PVC-free plastic; evaporate the filtrate at a temperature of 80°C, dry the precipitated solute to obtain PVC plastic, and recycle the evaporated methyl ethyl ketone solvent. The test conditions and results are listed in Table 1. As can be seen from Table 1, the removal rate of PVC is 96.2%.

Embodiment 2

[0042] Add mixed plastic A with a particle size of 10 mm into dimethylformamide solvent, and the ratio of plastic to solvent is 0.1 g / ml. At a temperature of 90°C, stir mechanically for 50 minutes. Use a 150-mesh screen to filter the solution, and dry the filtered residue to obtain PVC-free plastic; evaporate the filtrate at a temperature of 150°C, dry the precipitated solute to obtain PVC plastic, and circulate the evaporated dimethylformamide solvent use. The test conditions and results are listed in Table 1. As can be seen from Table 1, the removal rate of PVC is 96.1%.

Embodiment 3

[0044]Add mixed plastic A with a particle size of 30 mm into the cyclohexanone solvent, and the ratio of plastic to solvent is 0.1 g / ml. At a temperature of 90°C, stir mechanically for 50 minutes. Filter the solution with a 150-mesh screen, and dry the filtered residue to obtain PVC-free plastic; evaporate the filtrate at a temperature of 150°C, dry the precipitated solute to obtain PVC plastic, and recycle the evaporated cyclohexanone solvent. The test conditions and results are listed in Table 1. As can be seen from Table 1, the removal rate of PVC is 95.6%.

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Abstract

The invention relates to a method for separating PVC (Polyvinyl Chloride) and PS (Poly Styrene) from mixed waste plastic, which comprises the steps of: fully mixing crushed mixed waste plastic with a selective organic solvent for dissolving, carrying out solid-liquid separation on the dissolved mixture to obtain filtrate and solid particles which are mixed waste plastic with PVC and / or PS removed, and recycling the filtrate to obtain a recycled organic solvent and PVC and / or PS solid particles. The method provided by the invention is used for separating mixed waste plastic. The effect of selectively separating PVC is good, the efficiency is high, and PVC and PS particles obtained through separation can be further utilized. In addition, the recycled organic solvent can be recycled, and the method is high in economical efficiency and few in pollutants.

Description

technical field [0001] The invention belongs to the technical field of recycling waste plastics, in particular to a method for separating polyvinyl chloride (PVC) and polystyrene (PS) from mixed waste plastics. Background technique [0002] Due to the mass production, consumption and short use cycle of plastics, the amount of plastic waste has increased dramatically. A large amount of plastic waste not only causes a huge waste of resources, but also brings great harm to the environment: polluting the soil and oceans, and producing a large amount of toxic substances through incineration. Under the new situation of increasingly prominent energy problems and increasingly severe environmental problems, the research on strengthening the recycling of waste plastics has attracted great attention from governments of various countries. Among them, the use of waste plastics to make oil has great utilization value, but PVC in mixed plastics has a serious impact on equipment corrosion ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J11/08C08L27/06C08L25/06
CPCC08J11/08C08J2327/06C08J2325/06Y02W30/62
Inventor 李红伟邹亮王志强夏国富徐润王树青侯吉礼
Owner CHINA PETROLEUM & CHEM CORP