High-compaction-density ternary positive electrode material
A positive electrode material and high-pressure compaction technology, applied in the direction of positive electrodes, electrical components, battery electrodes, etc., can solve the problems of inability to meet the needs of cruising range, insufficient cruising range, and high price of new energy vehicles, so as to improve the volumetric energy density , reduce the cracking of balls, and improve the compaction density
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Embodiment 1
[0054] The high compacted density ternary positive electrode material described in Example 1 includes the following raw materials in parts by weight: 3 parts of secondary balls, 1 part of single crystal;
[0055] The general formula of the quadratic sphere is Li n Ni a co b m 1-a-b o 2 , 0.95≤n≤1.10, 0.75≤a≤1, 0≤b≤0.2, M is one of Mn and Al, and the average particle size of the secondary ball is 12.73μm;
[0056] The secondary ball is composed of primary particles of the secondary ball, and the general formula of the primary particle of the secondary ball is Li n Ni a co b m 1-a-b o 2 , 0.95≤n≤1.10, 0.75≤a≤1, 0≤b≤0.2, M is one of Mn and Al, and the particle size range of the primary particle of the secondary ball is 90nm~950nm;
[0057] The general formula of a single crystal is Li m Ni c co d N 1-c-d o 2 , 0.95≤m≤1.15, 0.80≤c≤1, 0≤d≤0.2, N is one of Mn and Al, and the average particle size of the single crystal is 1.63 μm;
[0058] The single crystal is compose...
Embodiment 2
[0077] The high compacted density ternary positive electrode material described in Example 2 includes the following raw materials in parts by weight: 4 parts of secondary balls, 1 part of single crystal;
[0078] The general formula of the quadratic sphere is Li n Ni a co b m 1-a-b o 2 , 0.95≤n≤1.10, 0.75≤a≤1, 0≤b≤0.2, M is one of Mn and Al, and the average particle size of the secondary ball is 6.71 μm;
[0079] The secondary ball is composed of primary particles of the secondary ball, and the general formula of the primary particle of the secondary ball is Li n Ni a co b m 1-a-b o 2 , 0.95≤n≤1.10, 0.75≤a≤1, 0≤b≤0.2, M is one of Mn and Al, and the particle size range of the primary particle of the secondary ball is 90nm-950nm;
[0080] The general formula of a single crystal is Li m Ni c co d N 1-c-d o 2 , 0.95≤m≤1.15, 0.80≤c≤1, 0≤d≤0.2, N is one of Mn and Al, and the average particle size of the single crystal is 1.63 μm;
[0081] The single crystal is compose...
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