Methods of making capsules
A technology for capsules and precursors, applied in the field of preparing capsules, can solve problems such as low permeability
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Embodiment 1
[0325] Example 1: Non-hydrolyzable precursor synthesis
[0326] Precursors for samples A-S, AV-AAD were prepared by:
[0327] Under a nitrogen atmosphere, a certain amount of TAOS reagent (purchased from Sigma Aldrich) was added to a clean dry round bottom flask equipped with a stirring bar and distillation equipment. A volume of acetic anhydride (available from Sigma Aldrich) and catalyst (available from Gelest, Sigma Aldrich) was added, and the contents of the flask were stirred and heated, as indicated in Table 1 . The reaction is heated to the indicated temperature for the indicated time, during which time the organic ester formed by the reaction of the alkoxysilane group with acetic anhydride and the condensation of the silyl acetate group with other alkoxysilane groups are distilled off Further organic esters are formed, this condensation occurs when polyalkoxysilanes (PAOS) are formed. The reaction flask was cooled to room temperature and placed on a rotary evapor...
Embodiment 2
[0329] Example 2: Synthesis of Hydrolyzed Precursors
[0330] Precursors for samples U-Z, AA-AI, and AK-AAB were prepared by:
[0331] Under a nitrogen atmosphere, an amount of TAOS reagent (available from Sigma Aldrich) was added to a clean dry round bottom flask equipped with a stirring bar and distillation equipment, and an amount of alcohol (available from Sigma Aldrich) was added thereto. As shown in Table 2, a certain amount of catalyst dissolved in water was added. 1N and 0.1N HCl dissolved in water were purchased from SigmaAldrich. 0.002N HCl was prepared by diluting 0.1N HCl in distilled water (purchased from Sigma Aldrich). The reaction was stirred and heated to the indicated temperature for the indicated time, during which time the alcohol formed by the hydrolysis of the alkoxysilane groups and the alcohol solvent and some water formed by the condensation of the silanol groups distilled off to form the polyalkane Occurs when oxysilane (PAOS) is used. The rea...
Embodiment 3
[0339] Embodiment 3: oil-in-water capsules
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