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Preparation method and application of polyurethane/polypropylene foam composite material

A polypropylene foam and composite material technology, applied in the field of polyurethane composite materials, can solve the problems of excessive VOC, increase the weight of composite materials, incomplete combustion, etc., and achieve the effect of reducing odor and VOC, excellent hydrolysis resistance, and improving production efficiency.

Pending Publication Date: 2022-04-08
ANHUI ANLI MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the current industry, PVC or PU polyurethane skin and polyurethane sponge are mostly prepared by flame compounding process, but when flame compounding, because the surface of the sponge needs to be melted, the combustion will be incomplete, and the initial decomposition will generate isocyanate and polyol, and then further decompose It is water, carbon dioxide and other volatile organic compounds (VOC). Although most of the VOC will volatilize in the subsequent process, it may still be incompletely volatilized, resulting in an unpleasant smell and excessive VOC in the entire composite material.
[0003] In view of the above problems, the existing method is to compound PU and PP layers to obtain foam composite materials. Specifically, by setting PP medium glue between the base cloth layer of PU and the PP layer, it is possible to avoid the need for flame compounding to burn This leads to the problem of VOC exceeding the standard. Due to the base cloth and medium glue, on the one hand, the glue also has the problem of odor and VOC release; on the other hand, it increases the weight of the composite material, which does not meet the current trend of lightweight materials; but If the combination of base cloth and medium glue is not used, although the traditional solvent-free adhesive layer also has a certain adhesive ability, due to the particularity of the PP layer material, the adhesive performance between the two cannot meet the use requirements.

Method used

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  • Preparation method and application of polyurethane/polypropylene foam composite material

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preparation example Construction

[0025] First aspect of the present invention provides a kind of preparation method of polyurethane / polypropylene foam composite material, comprises the following steps:

[0026] form a polyurethane finish

[0027] According to the embodiments of the present invention, the formation of the polyurethane surface layer is not particularly limited, and the conventional polyurethane surface layer preparation process in the art can be used. In one or more embodiments of the present invention, the specific process is: the surface layer polyurethane The slurry is coated on the surface of the release paper with a cutter head gap of 15-25 wires, and then placed at 100-140°C for 1-2 minutes; wherein, the polyurethane slurry for the surface layer is composed of 100-50 parts of polyurethane resin, N,N- 10-50 parts of dimethylformamide, 1-4 parts of anti-wear additive and 5-10 parts of color paste are composed according to parts by weight. It can be understood that the polyurethane resin, w...

Embodiment 1

[0050] Apply the surface layer polyurethane slurry on the surface of the release paper with a gap of 15 wires between the blades, and bake at 100°C for 2 minutes to form the polyurethane surface layer, that is, the texture layer of the automobile interior; wherein, the surface layer polyurethane slurry is made of LY-90NPC 50 parts, 50 parts of LT-50, 50 parts of N,N-dimethylformamide, 1 part of 3238 and 5 parts of color paste;

[0051] Coat the solvent-free polyether polyol combination material A and Haptex CC 6945 / 100 C-B at a mass ratio of 100:55 with a blade gap of 25 wires on the surface of the surface layer, and then bake at 75°C for 2 minutes to prepare Obtain a viscous solvent-free polyurethane bonding layer; wherein, the polyether polyol combination A material consists of 100 parts of Haptex CC 6945 / 100 C-A, 60 parts of antimony trioxide, 0.2 part of Haptex CC 6945 / 90 C-CC and Additive CX 93600 0.05 part composition;

[0052] The polypropylene foam is laminated with 7...

Embodiment 2

[0055] Apply the surface layer polyurethane slurry on the surface of the release paper with the blade gap of 20 wires, and bake at 110°C for 1.5 minutes to form the polyurethane surface layer, that is, the texture layer of the car interior; the surface layer polyurethane slurry is made of LY-90NPC 65 65 parts of LT-50, 30 parts of N,N-dimethylformamide, 2.5 parts of 3238 and 7.5 parts of color paste;

[0056] Coat the solvent-free polyether polyol combination material A and Haptex CC 6945 / 100 C-B at a mass ratio of 100:60 with a blade gap of 30 wires on the surface of the surface layer, then bake at 85°C for 1.5min, Obtain a viscous solvent-free polyurethane bonding layer; Wherein, the polyether polyol composition A material is made up of 125 parts of Haptex CC 6945 / 100 C-A, 40 parts of antimony trioxide, 0.3 part of Haptex CC 6945 / 90 C-CC and Additive CX 93600 0.1 composition;

[0057] The polypropylene foam is laminated with 95 filaments on the solvent-free polyurethane adh...

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Abstract

The invention discloses a preparation method and application of a polyurethane / polypropylene foam composite material. The preparation method comprises the following steps: forming a polyurethane surface layer; the polyether polyol combined material A is prepared from the following components in parts by weight: 100 to 150 parts of polyether polyol, 20 to 60 parts of filler, 0.2 to 0.4 part of a rear-section curing catalyst and 0.05 to 0.15 part of an equilibrium catalyst; a polypropylene foam body is attached to the surface of the solvent-free polyurethane bonding layer, and a semi-finished product is obtained; and forming a surface treatment layer on the surface of the semi-finished product to prepare the polyurethane / polypropylene foam composite material. Through a special solvent-free cross-linked structure, the solvent-free polyurethane bonding layer and the PP foam body are firmly bonded, so that on the basis that the odor is reduced and the light weight is realized, excellent bonding performance is achieved, and the requirements of automobile interior foam type composite materials are met.

Description

technical field [0001] The invention belongs to the technical field of polyurethane composite materials, in particular to a method for preparing a polyurethane / polypropylene foam composite material, and also relates to the application of the polyurethane / polypropylene foam composite material prepared by the preparation method in automotive interior decoration. Background technique [0002] Automotive interiors generally require a foam-type composite material to meet the needs of daily use. In the current industry, PVC or PU polyurethane skin and polyurethane sponge are mostly prepared by flame compounding process, but when flame compounding, because the surface of the sponge needs to be melted, the combustion will be incomplete, and the initial decomposition will generate isocyanate and polyol, and then further decompose It is water, carbon dioxide and other volatile organic compounds (VOC). Although most of the VOC will volatilize in the subsequent process, it is still poss...

Claims

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Application Information

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IPC IPC(8): B29C65/48B29C65/52B29K23/00B29K75/00B29L31/58
Inventor 杨旭陈茂祥吴文胡俊笪丽红胡兆阳刘志球苏星
Owner ANHUI ANLI MATERIAL TECH