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Negative plate and battery

A negative electrode sheet and negative electrode technology, which is applied in the field of batteries, can solve problems such as electrolyte consumption, side reactions, and abnormal pitting in the middle area, and achieve the effects of improving cycle performance, slow lithium decomposition, and good cycle performance

Pending Publication Date: 2022-06-07
ZHUHAI COSMX BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, as the compaction density of the negative electrode sheet increases, the porosity of the negative electrode sheet will decrease, and the electrolyte mainly infiltrates the negative electrode sheet through the path channels on the upper and lower sides of the cell, and the lower porosity It will hinder the infiltration channel of the electrolyte, resulting in insufficient infiltration of the electrolyte in the middle area of ​​the negative electrode sheet. As the number of cycles increases, the electrolyte solution is gradually consumed, which is not enough to support the normal charge and discharge needs, resulting in the appearance of the negative electrode sheet in the middle area. Lithium is precipitated in a spot shape, and the precipitated lithium ions have a large safety hazard. At the same time, the precipitated lithium ions will have a side reaction with the electrolyte, resulting in abnormal pitting in the middle area, which affects the cycle performance of the battery.

Method used

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Examples

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Effect test

Embodiment 1

[0046]The negative electrode sheet provided in the present embodiment comprises a negative collector copper foil and a negative active layer disposed on the surface of the negative collector copper foil, the negative active layer comprises a first negative active layer located in the middle and a second negative active layer located on both sides of the first negative active layer, the width ratio of the first negative active layer and the second negative active layer is 1:4, the first negative active layer comprises 97 mass parts of graphite B, 1.2 mass parts of styrene - acrylate, 0.5 mass of conductive carbon black and 1.3 mass of sodium carboxymethyl cellulose; the second anode active layer comprises 97 parts of mass graphite A, 1.2 parts of mass styrene latex, 0.5 parts of mass of conductive carbon black and 1.3 parts of mass of sodium carboxymethyl cellulose.

[0047] The preparation method of the negative electrode sheet provided in the present embodiment comprises the foll...

Embodiment 2

[0051] The negative electrode sheet provided in the present embodiment may refer to Example 1, the difference is that the first negative active layer comprises 48.5 mass parts of graphite A, 48.5 mass parts of graphite B, 1.2 mass parts of styrene - acrylate, 0.5 parts of mass conductive carbon black and 1.3 mass parts of sodium carboxymethyl cellulose.

Embodiment 3

[0053] The negative electrode sheet provided in the present embodiment may refer to Example 1, the difference is that the first negative electrode active layer comprises 97 mass parts of graphite C, 1.2 mass parts of styrene - acrylate, 0.5 parts of mass conductive carbon black and 1.3 mass parts of sodium carboxymethyl cellulose.

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Abstract

The invention provides a negative plate and a battery. The invention provides a negative electrode plate, the negative electrode plate comprises a negative electrode current collector and a negative electrode active layer arranged on at least one surface of the negative electrode current collector, and in the width direction of the negative electrode active layer, the negative electrode active layer comprises a first negative electrode active layer located in the middle and second negative electrode active layers located on the two sides of the first negative electrode active layer; the symmetry axis of the first negative active layer is overlapped with the symmetry axis of the negative plate; the liquid absorption capacity of the first negative electrode active layer is greater than that of the second negative electrode active layer, and / or the electrolyte consumption of the first negative electrode active layer is less than that of the second negative electrode active layer. According to the negative plate provided by the invention, the problem of insufficient electrolyte infiltration in the middle area of the negative plate is effectively relieved, the problem of lithium precipitation of the negative plate is relieved, and the cycle performance of the battery is improved.

Description

Technical field [0001] The present invention relates to a negative electrode sheet and a battery, relates to the field of battery technology. Background [0002] Because of its high cycle life, light and thin, the battery is widely used in mobile phones, notebook computers, power tools, wearable and other fields. With the development of technology, the energy density of the battery has put forward higher and higher demand, and the energy density of the battery can be improved by increasing the compaction density of the negative electrode sheet, for example, the compaction density of the negative electrode sheet is from 1.7g / cm 3 Increased to 1.78g / cm 3 The energy density of the battery can be increased by 2%-4%. [0003] However, with the improvement of the compaction density of the negative electrode sheet, the porosity of the negative electrode sheet will be reduced, and the electrolyte is mainly through the path channel on the upper and lower sides of the cell to achieve infil...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/13H01M10/0525H01M10/0587
CPCH01M4/13H01M10/0525H01M10/0587H01M2004/027Y02P70/50
Inventor 张文轩邸会芳方双柱郭富荣
Owner ZHUHAI COSMX BATTERY CO LTD