Universal reagent for nucleic acid detection
A reagent and molecular detection technology, applied in the field of DNA hybridization reaction, can solve problems such as difficult to use in field environment without detection conditions, complex equipment and detection system, etc.
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Embodiment 1
[0054] Example 1. Oligonucleotide strands required for CHA to catalyze the hairpin assembly reaction.
[0055] The oligonucleotide chain of CHA reaction includes C, H, F chain, and its complementary structure is such as figure 2 shown (SEQ ID NOs: 1-4). The C chain firstly hybridizes with the neck loop of the H chain through the TMSD reaction, and opens the hairpin structure of H, and then the H chain is complementary to the neck loop of the F chain through the TMSD reaction, and opens the hairpin structure of F to form the H-F-C complex. Finally, the free end of the F chain replaces C through the TMSD reaction, so that C is separated from the hybrid complex to form an H-F complex, and C acts as a catalyst to participate in another assembly process. In order to facilitate the TMSD reaction of the H and F chains immobilized on different microspheres, the 5'-end (or all 3'-ends) of the H and F chains are biotin (Biotin) or amino (-NH) 2 ) group is combined with the correspond...
Embodiment 2
[0056] Example 2. Conjugation of oligonucleotide probe strands to microspheres
[0057] The H and F chains can be tightly linked to avidin microspheres by labeling biotin at the 5' or 3'-end, or labeling with amino groups (-NH 2 ) and the carboxyl functional group (-COOH) on the surface of the carboxyl microspheres through chemical cross-linking reaction to form chemical bonds. The cross-linking between the amino group and the carboxyl group adopts the classical method, using carbodiimide (EDC) and N-hydroxysuccinimide (NHS) as the cross-linking agent. The principle is as follows: EDC first reacts with a carboxyl group to form an O-acylisourea intermediate that can react with amino groups, and NHS is used to stabilize the intermediate. After the addition of amino-modified terminal nucleotides, this intermediate can rapidly react with an amino group to form an amide bond, covalently labeling the oligonucleotide chain to polystyrene microspheres.
[0058] The end of the F chai...
Embodiment 3
[0061] Example 3. Comparison of agglutination reactions of different microspheres
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