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Special master batch for hot press molding transparent polypropylene as well as preparation method and application of master batch

A technology of transparent polypropylene and hot-pressing molding, applied in the field of special polypropylene masterbatch, can solve the problems of large fluctuation in transparency of disposable water cups, difficult dispersion of transparent nucleating agents, rising production costs, etc., and achieve uniform product quality. Stable, improved interface effect, low production cost effect

Pending Publication Date: 2022-07-15
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the transparent nucleating agent is relatively difficult to disperse, it is easy to reunite locally, which will cause large fluctuations in the transparency of the disposable water cup and unstable quality; in order to ensure the transparency of the disposable water cup, the manufacturer will further increase the addition of the nucleating agent volume, which will lead to an increase in production costs

Method used

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  • Special master batch for hot press molding transparent polypropylene as well as preparation method and application of master batch
  • Special master batch for hot press molding transparent polypropylene as well as preparation method and application of master batch
  • Special master batch for hot press molding transparent polypropylene as well as preparation method and application of master batch

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-89

[0075] The following table 2 is the masterbatch composition table (unit: weight percent) of the hot-pressed transparent polypropylene special-purpose masterbatches of Examples 1 to 89 of the present invention:

[0076] The specific embodiment of the special master batch of table 2 thermoforming transparent polypropylene

[0077]

[0078]

[0079]

[0080]

[0081]

[0082]

[0083]

[0084]

[0085]

[0086]

[0087]

[0088]

[0089]

[0090]

Embodiment 90

[0092] The preparation method of the special masterbatch for thermoforming transparent polypropylene of the present embodiment comprises the following steps:

[0093] Step (1) Blending polypropylene and auxiliary agents: According to the special masterbatch formula for hot-pressing transparent polypropylene in Examples 1-89, polypropylene resin and composite transparent nucleating agent, compatibilizer, lubricant, antioxidant masterbatch are mixed together. The materials are mixed in a high-speed mixer;

[0094] Step (2) twin-screw extruder melt granulation: add the blended material into the extruder hopper, melt and extrude the strands through the twin-screw extruder, and then cool in a water tank and air-dry and cut into pellets. Special masterbatch.

[0095] Preferably, in the step (1), the polypropylene resin, the composite transparent nucleating agent, the compatibilizer, the lubricant, and the antioxidant masterbatch are mixed in a high-speed mixer for 10-20 minutes, an...

Embodiment 91

[0097]The special masterbatch products of hot-pressed transparent polypropylene of Example 1 to Example 89 are detected, and their technical indicators are respectively shown in Table 3:

[0098] The technical index of the special masterbatch for thermoforming transparent polypropylene of table 3 embodiment 1~89

[0099]

[0100]

[0101]

[0102]

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Abstract

The invention provides a master batch special for hot press molding transparent polypropylene as well as a preparation method and application of the master batch. The master batch special for the hot press molding transparent polypropylene comprises the following components in percentage by weight: 76.5-94.7% of polypropylene resin; 5-20% of a composite transparent nucleating agent (comprising four composite transparent nucleating agents of sorbitol, phosphate, rosin and carboxylate, which are compounded according to the weight percentage of 55-85: 5-15: 5-15: 5-15)); 0.1-5% of a compatibilizer; 0.1-5% of a lubricant; 0.1-3% of an antioxidant master batch; wherein the compatibilizer is a compatilizer, a coupling agent or a dispersing agent. The master batch special for hot-press molding transparent polypropylene is uniformly mixed with polypropylene matrix resin in the production of hot-press molding polypropylene products such as disposable cola cups, can effectively and directly reduce the agglomeration phenomenon generated by a nucleating agent, can be secondarily crystallized and dispersed in the hot-press molding process, and effectively improves the transparency and mechanical properties of polypropylene; and the preparation method has the advantages of low cost and easiness in processing.

Description

technical field [0001] The invention relates to a special masterbatch for polypropylene, in particular to a special masterbatch for hot-pressing transparent polypropylene and a preparation method and application thereof. Background technique [0002] With the rapid development of the national economy, the amount of thin-walled transparent containers such as disposable cola cups, milk cups and ice cream cups has increased year by year. Because polypropylene has the characteristics of high heat resistance and good hygiene, it is widely used in the production of this field. [0003] At present, most of the transparent disposable water cup manufacturers use hot pressing technology to produce this product, that is, firstly, the polypropylene base resin is extruded into a sheet of a certain thickness, and then a cup of a certain volume is prepared by hot pressing with an automatic hydraulic cup making machine. Hot press molding is a simple and common processing method in the plas...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08L93/04C08K5/053C08K5/098C08K5/52C08K5/00C08J3/22
CPCC08J3/226C08J2323/12C08J2423/12C08J2451/06C08J2493/04C08K5/053C08K5/098C08K5/52C08K2201/014C08K5/0091
Inventor 安彦杰姜艳峰吴双李瑞王熺张明强杨国兴葛腾杰闫义彬任鹤
Owner PETROCHINA CO LTD
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