Chromium slag soaking and reducing detoxication method

A reducing agent, hexavalent chromium technology, applied in the restoration of polluted soil, the removal of solid waste and other directions, can solve the problems of endangering the natural environment, difficult to widely use, expensive treatment costs, etc., to achieve simple and applicable process, scientific detoxification method. , The effect of low processing cost

Inactive Publication Date: 2004-12-22
董宏杰 +1
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Problems solved by technology

If the hexavalent chromium in the chromium slag cannot be effectively removed, it will endanger the natural environment on which human beings depend.
At present, the methods adopted for the treatment of chromium slag mainly include: slag stacking method, roasting reduction method, chrome slag ironmaking and coal blending power generation, etc. Among the above methods, the slag field stacking method can not fundamentally solve the toxicity problem of chromium slag, It also brings a lot of inconvenience to later storage, anti-leakage, etc.
Although the roasting reduction method can fundamentally solve the toxicity problem of chrome slag, its expensive treatment cost makes it difficult for enterprises to accept, and there is still the problem of slag toxicity scattering in the transportation process of chrome slag ironmaking and coal blending power generation. In a word, the above method Unsatisfactory and difficult to achieve widespread adoption

Method used

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Embodiment Construction

[0026] 1. Requirements for disposal of chromium slag

[0027] Design 15-20m 3 Volume, the bottom of the immersion iron tank with a leaky plate filter layer, the maximum particle diameter of chromium ballast is ≤5mm, and the chromium ballast is placed in the iron tank in batches, and the height is 15cm from the edge of the upper tank. Treat 20 tons of chromium dregs at a time (the capacity or quantity of the iron tank can be expanded according to the scale), then comprehensively sample and test the hexavalent chromium content, calculate the total amount of hexavalent chromium salt according to the content, and calculate the actual amount of sodium sulfide.

[0028] 2. Calculation of reducing agent sodium sulfide dosage

[0029] The amount of sodium sulfide is calculated according to the amount of chromium slag processed in each batch. Because in the actual treatment process, a small part of sodium sulfide will be lost naturally, and a small amount of sodium sulfide will be tak...

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Abstract

The chromium slag soaking and reducing detoxicating process is to soak chromium slag in reductant solution so that the six-valent chronium as the toxic matter in chromium slag is separated from chronium slag and reduced into three valent chronium in the solution for detoxication. The process is scientific, simple, practical, fast in detoxication speed and low in cost. The present invention makes it possible to process chronium slag in large scale or oil environmental pollution.

Description

Technical field [0001] The invention relates to the technical field of detoxification of chromium slag, and mainly relates to a chromium slag soaking reduction detoxification method. Background technique [0002] Chromium salt products are indispensable and important chemical products in the national economy. Because the waste dregs produced in the production process are leaching and toxic, their storage in the environment will seriously pollute the environment, which is also an important factor restricting the production and development of enterprises. If the hexavalent chromium in the chromium slag cannot be effectively removed, the natural environment on which human beings depend will be endangered. At present, the methods adopted for the treatment of chromium slag mainly include: slag stacking method, roasting reduction method, chrome slag ironmaking and coal blending power generation, etc. Among the above methods, the slag field stacking method can not fundamentally sol...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09B3/00B09C1/08
Inventor 范玉瓒董宏杰
Owner 董宏杰
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