Bionic poisonless anti-pollution paint for ship and its preducing method

A technology for antifouling coatings and ships, applied in antifouling/underwater coatings, coatings, paints containing biocides, etc., can solve serious environmental pollution problems, achieve high cross-linking density, prevent marine organisms from adhering, Good antifouling effect

Inactive Publication Date: 2003-01-22
辽宁神逸特种涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the prolongation of the use time of organotin coatings, this potential environ

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0053] Example 1 Preparation of anti-fouling coating for ship's bottom

[0054] (1) Preparation of modified fluorine-containing resin, raw materials and dosage (Kg):

[0055] 4-tert-butylphenyl tetrafluorothiophene hydroxide 14

[0056] Polyvinylidene fluoride 14

[0057] Polyvinyl fluoride 12

[0058] Polychlorotrifluoroethylene 1

[0059] PTFE 10

[0060] Vinyl fluoride 18

[0061] N-butanol 20

[0062] Acetone 11

[0063] The preparation method is as follows: dissolve vinyl fluoride in 10Kg of butanol and add it to the reactor. Then add the heated liquid polychlorotrifluoroethylene and 3g of benzoyl peroxide, stir and heat to 240 ℃, then slowly add the raw materials other than tetrafluoroethylene, and finally add polytetrafluoroethylene and the remaining butyl Alcohol, react at 220-240°C for 1h. Cool down to below 200°C and add butanone, react at 180-230°C until the acid value reaches 13mgKOH / g, cool down, add ionized water to dilute it until the visco...

example 2

[0075] Example 2 Preparation of antifouling coating for ship bottom (1) Preparation of modified fluororesin. Raw materials and dosage (hg) are:

[0076] 4-tert-butylphenyl tetrafluorothiophene hydroxide 18

[0077] Polyvinylidene trifluoride 12

[0078] Polyvinyl fluoride 8

[0079] Polychlorotrifluoroethylene 0.8

[0080] PTFE 8.2

[0081] Vinyl fluoride monomer 20

[0082] Butanol 23

[0083] The preparation method of methyl ethyl ketone 10 is the same as the preparation of the coating of Example 1 (2). The amount of raw material (kg) is:

[0084] Fluorine resin PC grade 25

[0085] Modified fluororesin 23

[0086] Alkaloid 14

[0087] Peptide compound 4

[0088] Butanol 15

[0089] Ionized water 7

[0090] Leveling agent 4

[0091] Filler (natural mineral powder, calcium carbonate) 8 preparation method as in Example 1. Example 3 Manufacturing of coatings for offshore drilling platforms and underwater pipelines and equipment. (1) M...

example 4

[0101] Example 4 Production of underwater antifouling paint

[0102] Preparation of modified fluororesin. Raw materials and dosage (kg) are:

[0103] 4-tert-butylphenyl tetrafluorothiophene hydroxide 12

[0104] Polychlorotrifluoroethylene 27

[0105] PTFE 7

[0106] Chlorotrifluoroethylene monomer 23

[0107]Solvent butanol 21

[0108] Butanone 10

[0109] The preparation process is as in Example 1, and a pressure-resistant reactor is used for closed reaction. The coating is manufactured as in Example 1.

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PUM

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Abstract

The bionic poisonless antifouling paint for ship is prepared with fluororesin, modified fluororesin alkaloid, peptide compound, solvent, ionic water, leveling agent, stuffing, pigment and assistant. The modified fluororesin is preparew with fluoric thiofuran, polyfluoroethylene, fluoric ethylene monomer and solvent and through reaction in the action of initiator. The alkaloid is extracted from marine life seaweed, and the peptide compound is extracted from sponge. The antifouling paint forms paint film on the bottom of ship and under the action of sea water the paint film surface with high crosslinking density and low adhering performance will exude alkaloid and peptide to prevent marine life from attaching. The paint may be also used in the surface treatment of marine drilling platform, underwater pipe, valve and other facilities.

Description

Technical field: [0001] The invention relates to a fluorine-containing paint, which is an anti-fouling paint composed of a fluorine-containing olefin copolymer, a marine organism extract, a solvent and an auxiliary agent. Background technique: [0002] Due to the parasitism and reproduction of marine organisms, especially shellfish, on the bottom of ships in the ocean, the burden of navigation on ships increases, which affects their navigation speed and load efficiency. How to prevent the parasitism of these organisms has become an important topic. After a lot of research, a paint made of tin organic compounds was found, which can effectively inhibit and prevent the growth of these organisms. After years of use, due to the high toxicity of this kind of organotin paints, serious pollution to the marine ecological environment, to a certain extent, affect the natural ecological balance, destroy the living environment of some aquatic organisms, especially for the important ecological...

Claims

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Application Information

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IPC IPC(8): C09D5/16C09D127/12
Inventor 王钧宇
Owner 辽宁神逸特种涂料有限公司
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