Liquid crystal display orientation layer material and preparing method thereof
A technology selected from polymers, applied in the field of polymers, can solve the problems that cannot be fully met, cannot meet the needs, and the active alignment film technology is not mature enough.
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Embodiment 1
[0043]Embodiment one: the synthesis of prepolymer BP-AN
[0044] Add 29 grams (0.074 moles) of bisphenol A epoxy resin and 6.74 milliliters (0.074 moles) of aniline in a single-necked flask equipped with a stirrer, and use an oil bath to control the temperature at 60-130 ° C to react to obtain a slightly Yellow blocky solid. This solid was dissolved in 100 mL CHCl 3 After dissolving, the polymer was precipitated with 500 milliliters of acetone, and the precipitate was dried in a vacuum oven. The final product was the prepolymer BP-AN of layered solid.
Embodiment 2
[0045] Embodiment two: the synthesis of prepolymer PP-MAN
[0046] Add 0.69 g (0.0065 mole) of o-methylaniline to 1.6 g (0.0072 mole) of hydroquinone epoxy resin, and use an oil bath to control the temperature at 60-130° C. for the reaction. Then the product was dissolved in THF and gradually added to CCl 4 In the middle, a white precipitate is produced, and finally the prepolymer BP-MAN is obtained by drying in a vacuum oven.
Embodiment 3
[0047] Embodiment three: the synthesis of prepolymer DP-EAN
[0048] Add 0.69 gram (0.0058 mol) m-ethylaniline in 2.15 gram (0.0072 mol) biphenol epoxy resin, react at 60-130 ℃ with oil bath control temperature, obtain white solid product, then use solid After the DMF was dissolved, it was gradually added to water, and precipitated immediately, and finally dried in a vacuum oven to obtain the prepolymer DP-EAN.
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