Electrode, electrochemical device, and method of making electrode
A manufacturing method and electrode technology, applied in electrode manufacturing, electrochemical generator, electrode rolling/calendering, etc., can solve the obstacles of high output or high energy density of electrochemical devices, high internal resistance of electrochemical devices, contact The problem of high resistance can reduce the contact resistance, reduce the number of processes, and reduce the cost.
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Embodiment A1
[0139] Here, first, an electrode for an electric double layer capacitor is prepared.
[0140] (1) Preparation of composite particles
[0141] First, the composite particles 250 used in the production of the active material-containing layer of each electrode for an electric double layer capacitor were produced in the following procedure. Here, the composite particles 250 are composed of a cathode or anode active material (90% by mass), conductive additive particles (5% by mass), and a binder (5% by mass).
[0142] Activated carbon (average particle diameter: 15 μm) was used as the active material (particles containing the active material) for the cathode and anode. In addition, carbon black (acetylene black) was used as a conductive aid. Furthermore, polyvinylidene fluoride (PVDF) is used as an adhesive.
[0143] First, a "raw material solution" in which carbon black was dispersed in a solution of polyvinylidene fluoride dissolved in N,N-dimethylformamide as a solvent (3% by...
Embodiment A2、A3
[0152] Except making roll line pressure be 200 * 10 in embodiment A2, A3 2 N / m, 2000×10 2 Except for N / m, others are the same as in Example A1.
Embodiment A4
[0154] In Example A4, a lithium ion secondary battery was prepared. As the anode, the same electrode as in Example A1 was used. On the other hand, the cathode was produced by performing the same hot roll processing as in Example A1 using the following composite particles and the following current collector.
[0155] Use of LiCoO as particles containing active material 2 Composite particles were produced in the same manner as in Example A1 for particles (average particle diameter: 0.5 mm), acetylene black (electrochemical black) as a conductive additive, and polyvinylidene fluoride (PVDF) as a binder. The particle size of the composite particles was 200 μm. In addition, the constituent ratio of the composite particle was the particle containing an active material (90 mass %), the conductive additive particle (7 mass %), and the binder (3 mass %).
[0156] The current collector was an aluminum foil (thickness: 20 μm), and an aluminum foil on which a conductive resin layer (th...
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