Transparent gel self-adhesive agent, transparent gel self-adhesive sheet, optical filter for display

An adhesive and filter technology, applied in the direction of adhesives, film/sheet adhesives, chemical instruments and methods, etc., to achieve excellent buffering properties, migration prevention, and durability improvement effects

Inactive Publication Date: 2006-09-13
MITSUBISHI PLASTICS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, in both cases of the former composite material glass and the latter laminated display panel and protective plate, it is mostly necessary to bond while applying heat or pressure or both by the autoclave method, and in this case In this case, bending and peeling, cracks and other phenomena will appear after bonding, which is due to the different linear expansion coefficients of various materials

Method used

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  • Transparent gel self-adhesive agent, transparent gel self-adhesive sheet, optical filter for display
  • Transparent gel self-adhesive agent, transparent gel self-adhesive sheet, optical filter for display
  • Transparent gel self-adhesive agent, transparent gel self-adhesive sheet, optical filter for display

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0196] In the acrylate copolymer of 100 weight parts, add the trade name that 0.3 weight part Ciba SpecialtyChemicals produces is called Irgacure 500 as photoinitiator and the trade name that 0.3 weight part Osaka Organic Chemical Industry produces is called Viscoat V260 (1,9-nonyl diacrylate) glycol ester) as a crosslinking monomer to obtain a UV crosslinking composition. The composition of the acrylate copolymer used is 78.4% by weight of n-butyl acrylate, 19.6% by weight of 2-ethylhexyl acrylate and 2.0% by weight of acrylic acid that have been copolymerized. The viscosity is 250,000 (mPa.s).

[0197] In the above-mentioned ultraviolet light crosslinking composition, the plasticizer diisodecyl phthalate (DIDP) and 2% by weight of Nippon Aerosil are mixed with 20% by weight of the superfine silica particles produced by Nippon Aerosil, and the primary average The particle diameter was 7 nm, which was melt-stirred to obtain a sol composition.

[0198] The sol composition is sa...

Embodiment 2

[0204] To 100 parts by weight of the acrylate copolymer used in Example 1, 2.0 parts by weight of a photoinitiator "Irgacure 500" and 2.0 parts by weight of a crosslinking monomer "Viscoat V260" were added to obtain an ultraviolet light crosslinking composition.

[0205] In this ultraviolet light crosslinking composition, the plasticizer diisodecyl phthalate (DIDP) of 60% by weight and 10% by weight of “Aerosil50” silica ultrafine particles with a primary average particle diameter of 30nm are mixed. Melt stirring is performed to obtain a sol composition.

[0206] Sandwich the above-mentioned sol composition between peelable PET with a thickness of 75 μm and 100 μm, heat-melt and form it into a sheet with a thickness of 0.5 mm, and use a high-pressure mercury lamp to radiate 4000 mJ / cm on each side from the front and rear sides through the peelable PET 2 The cumulative amount of light, a transparent gel adhesive sheet was obtained. Using the transparent gel adhesive sheet obta...

Embodiment 3

[0208] 20% by weight of plasticizer diisodecyl phthalate (DIDP) and 2% by weight of Aerosil 50 were mixed into the UV crosslinking composition obtained in Example 1, and melted and stirred to obtain a sol combination , and a transparent gel adhesive sheet and a laminate were obtained by a method similar to Example 1.

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Abstract

A novel transparent adhesive agent is provided which allows a substrate and a surface material to be pasted together at room temperature, without requiring high temperature/high pressure treatment, and, furthermore, may confer an excellent damping property. A transparent gel adhesive is provided, wherein the transparent gel consists of a three-dimensionally cross-linked polymer swollen by a liquid containing a plasticizer and an inorganic fine particle, whose plasticizer is a fluid body with a solidifying point of -20 DEG C or below and a content of 20 to 70 weight percent, whose inorganic fine particles have a primary average particle diameter of 200 nm or less and contained in an amount of 1 to 15 weight percent, whose resin that constitutes the three-dimensionally cross-linked polymer has a glass transition temperature (Tg) of -20 DEG C or below, melt viscosity at 130 DEG C of 50,000 mPa.s or above, whose transparent gel has a holding strength of 5 mm or less at a load of 490 mN (50 gf)x2 hours and 40 DEG C, in a test conforming to JIS Z0237.

Description

technical field [0001] The present invention relates to a transparent gel adhesive and a transparent gel adhesive sheet, which are used for gluing transparent materials such as glass, transparent plastic materials, etc. constituting various window materials, various display panels, etc., and light filters for displays using the above materials piece. Background technique [0002] Glass materials are widely used in various window materials, various display panels, etc., and have advantages such as wear resistance, weather resistance, and transparency. However, since glass materials have problems of being weak against shock and vibration, they are reinforced by various methods, such as a method of thermally or chemically strengthening glass, a method of laminating glass, and a method of lining a protective sheet, depending on the application. [0003] In recent years, as the requirements for window materials and various panels have increased in terms of crime prevention, safe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J201/00C09J7/02B32B27/00B32B27/30B32B5/18B32B15/08C09J7/00C09J11/00
Inventor 山冈哲也稻永诚
Owner MITSUBISHI PLASTICS INC
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