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Light-emitting material for organo-electroluminescence device and for organic electroluminescence device which the material is applied

a technology of light-emitting materials and organoelectroluminescence devices, applied in the direction of diaryl/triaryl methane dyes, natural mineral layered products, anthracene dyes, etc., can solve the problems of low light emission brightness and light emission efficiency of conventional organic el devices, and no organic el device has been put to practical us

Inactive Publication Date: 2001-10-25
TOYO INK SC HOLD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As compared with inorganic EL devices, conventional organic EL devices require high voltage, and their light emission brightness and light emission efficiency are low.
Further, conventional organic EL devices deteriorate in properties to a great extent, and no organic EL device has been put to practical use.
However, conventional organic EL devices including the above organic EL device are not yet satisfactory in brightness although these organic EL devices are improved in brightness to some extent.
Further, they have a serious problem that their stability is insufficient in their continuous operation for a long period of time.
That is because, for example, a metal chelate complex such as a tris(8-hydroxyquinolinate)-alu-minum complex, or the like, is chemically unstable when an electric field is applied for light emission, is poor in adhesion to a cathode and extremely deteriorates in a short period of emission.
When the layer thickness is too large, inefficiently, a high voltage is required to achieve predetermined emission of light.
When the layer thickness is too small, the layer is liable to have a pinhole, etc., so that sufficient light emission brightness is hard to obtain when an electric field is applied.

Method used

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  • Light-emitting material for organo-electroluminescence device and for organic electroluminescence device which the material is applied
  • Light-emitting material for organo-electroluminescence device and for organic electroluminescence device which the material is applied
  • Light-emitting material for organo-electroluminescence device and for organic electroluminescence device which the material is applied

Examples

Experimental program
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Effect test

example 1

[0047] Compound (1) in Table 3 as a light-emitting material, 2,5-bis(1-naphthyl)-1,3,4-oxadiazole and a polycarbonate resin (Panlite K-1300, supplied by Teijin Kasei) in a weight ratio of 5:3:2 were dissolved in tetrahydrofuran, and the solution was spin-coated on a cleaned glass substrate with an ITO electrode to form a light-emitting layer having a thickness of 100 nm. An electrode having a thickness of 150 nm was formed thereon from a magnesium / indium alloy having a magnesium / indium mixing ratio of 10 / 1, to obtain an organic EL device. The device had the following light emission characteristics. The device showed blue light emission having a brightness of 90 (cd / m.sup.2) at a direct current voltage of 5 V, a maximum brightness of 1,500 (cd / m.sup.2) and a light emission efficiency of 0.50 lm / W.

example 2

[0048] Compound (2) in Table 3 was vacuum-deposited on a cleaned glass substrate with an ITO electrode to form a light-emitting layer having a thickness of 100 nm. An electrode having a thickness of 100 nm was formed thereon from a magnesium / silver alloy having a magnesium / silver mixing ratio of 10 / 1, to obtain an organic EL device. The light-emitting layer was formed by deposition under a vacuum of 10.sup.-6 Torr at a substrate temperature of room temperature. The device showed green light emission having a brightness of 260 (cd / M.sup.2) at a direct current voltage of 5 V, a maximum brightness of 800 (cd / r.sup.2) and a light emission efficiency of 0.60 lm / W.

example 3

[0049] Compound (3) in Table 3 was dissolved in methylene chloride tetrahydrofuran, and the solution was spin-coated on a cleaned glass substrate with an ITO electrode to form a light-emitting layer having a thickness of 50 nm. Then, aluminum bis(2-methyl-8-quinolinate)(2-naphtola-te) was vacuum-deposited to form an electron-injecting layer having a thickness of 10 nm, and an electrode having a thickness of 100 nm was formed thereon from a magnesium / aluminum alloy having a magnesium / aluminum mixing ratio of 10 / 1, to obtain an organic EL device. The light-emitting layer and the electron-injecting layer were formed by deposition under a vacuum of 10.sup.-6 Torr at a substrate temperature of room temperature. The device showed bluish green light emission having a brightness of 200 (cd / m.sup.2) at a direct current voltage of 5 V, a maximum brightness of 12,000 (cd / m.sup.2) and a light emission efficiency of 1.2 lm / W.

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Abstract

A light-emitting material which serves to emit light having a high brightness and is almost free of deterioration in light emission, and an organic EL device for which the light-emitting material is adapted, the material having the formula (1) disclosed in claim 1, 2 or 3.

Description

[0001] The present invention relates to a light-emitting material for an organo-electroluminescence ("EL" hereinafter) device for use as a flat light source or display, and to a light-emitting device having a high brightness.PRIOR ART[0002] An EL device using an organic substance is expected to have a great promise as a solid light-emitting inexpensive large-screen, full-color display device, and developments thereof are being made in many ways. Generally, an EL device is composed of a light-emitting layer and a pair of facing electrodes sandwiching the light-emitting layer. The light emission of an EL device is the following phenomenon. When an electric field is applied between the two electrodes, the cathode injects electrons into the light-emitting layer, and the anode injects holes into the light-emitting layer. When the electrons recombine with the holes in the light-emitting layer, their energy level shifts back to a valence bond band to release energy as light.[0003] As compa...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C07C211/54C07C217/92C07C225/22C07C225/32C07C255/42C07C317/36C07C323/37C07D207/34C07D209/40C07D209/86C07D217/22C07D219/08C07D241/12C07D241/24C07D241/26C07D241/38C07D241/42C07D249/08C07D249/20C07D263/32C07D271/10C07D271/107C07D271/113C07D277/64C07D277/68C07D277/82C07D309/34C07D309/38C07D311/16C07D311/30C07D333/36C07D333/64C07D333/76C07D417/04C07D417/14C07D471/04C07D471/06C07D493/04C07D513/04C09K11/06H01L51/00H01L51/30H01L51/50H05B33/14
CPCC07C211/54C07C217/92C07C225/22C07C225/32C07C255/42C07C317/36C07C323/37C07C2101/14C07C2102/30C07C2103/18C07C2103/24C07C2103/50C07C2103/54C07D207/34C07D209/40C07D209/86C07D217/22C07D219/08C07D241/12C07D241/24C07D241/26C07D241/38C07D241/42C07D249/08C07D249/20C07D263/32C07D271/107C07D271/113C07D277/64C07D277/68C07D277/82C07D309/34C07D309/38C07D311/16C07D311/30C07D333/36C07D333/64C07D333/76C07D417/04C07D417/14C07D471/04C07D471/06C07D493/04C07D513/04C09K11/06H01L51/0051H01L51/0052H01L51/0053H01L51/0054H01L51/0055H01L51/0057H01L51/0058H01L51/006H01L51/0061H01L51/0065H01L51/0067H01L51/0068H01L51/0069H01L51/007H01L51/0072H01L51/0073H01L51/0074H01L51/0077H01L51/0081H01L51/5012H05B33/14Y10S428/917Y02E10/549C09B23/0075C09B23/148C09B48/00C09B49/04C09B57/001C09B57/008C09B57/02C09B1/00C09B3/14C09B3/78C07C2601/14C07C2602/30C07C2603/18C07C2603/24C07C2603/50C07C2603/54H10K85/611H10K85/623H10K85/625H10K85/621H10K85/615H10K85/622H10K85/653H10K85/636H10K85/626H10K85/656H10K85/633H10K85/6565H10K85/654H10K85/655H10K85/6576H10K85/6572H10K85/6574H10K85/30H10K85/324H10K50/11
Inventor ONIKUBO, TOSHIKAZUTAMANO, MICHIKOOKUTSU, SATOSHIENOKIDA, TOSHIO
Owner TOYO INK SC HOLD CO LTD
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