Imidazoline containing fiberglass binder

Abstract

Provided is a fiberglass binder composition which comprises a polycarboxy polymer, polyol and an imidazoline. The binder also preferably includes a catalyst which is an alkali metal salt of a phosphorus-containing organic acid. The resultant binder provides minimal processing difficulties and a product which exhibits minimal water absorption.

Description

[0001] 1. Field of the Invention[0002] The subject invention pertains to polycarboxy polymer binding resins having improved water absorption properties. More particularly, the subject invention pertains to thermosetting, acrylic acid-based binder resins which cure by crosslinking with a poly-functional, carboxyl group-reactive curing agent, which binders containing such resins exhibit minimal water absorption. Such binders are useful as replacements for formaldehyde-based binders in non-woven fiberglass goods.[0003] 2. Description of the Related Art[0004] Fiberglass binders have a variety of uses ranging from stiffening applications where the binder is applied to woven or non-woven fiberglass sheet goods and cured, producing a stiffer product; thermo-forming applications wherein the binder resin is applied to sheet or lofty fibrous product following which it is dried and optionally B-staged to form an intermediate but yet curable product; and to fully cured systems such as building ...

AI Technical Summary

Benefits of technology

[0016] Yet another object of the present invention is to provide such a binder which allows one to prepare fiberglass insulation products which are less prone to absorb liquid water.

[0017] Still another object of the present invention is to provide a fiberglass insulation product which exhibits good recovery and rigidity, and is formaldehyde-free, and is more water-proof.

Problems solved by technology

Fiberglass binders also cannot be equated with paper or wood product "binders" where the adhesive properties are tailored to the chemical nature of the cellulosic substrates.

Many such resins, e.g. urea / formaldehyde and resorcinol / formaldehyde resins, are not suitable for use as fiberglass binders.

Also, viscous binders tend to be tacky or sticky and hence they lead to accumulation of fiber on the forming chamber walls.

This accumulated fiber may later fall onto the mat causing dense areas and product problems.

However, binder-coated fiberglass products are often of the commodity type, and thus cost becomes a driving factor, generally ruling out such resins as thermosetting polyurethanes, epoxies, and others.

This hydrophilicity results in fiberglass insulation that is more prone to absorb liquid water, thereby possibly compromising the integrity of the product.

Also, the thermosetting acrylic resins now being used as binding agents for fiberglass have been found to not react as effectively with silane coupling agents of the type traditionally used by the industry.