Arc-extinguishing composition and articles manufactured therefrom
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second embodiment
[0067] In accordance with the arc-extinguishing compositions, articles and methods described herein, it has been found that when the arc-extinguishing compound is provided in finely divided form (see Table 2 and FIG. 4), the molded arc-extinguishing composition has unexpectedly increased toughness, and especially elongation, thereby preventing breakage of the molded articles.
[0068] In accordance with the second embodiment, wherein the arc-extinguishing compound is provided in finely divided form, it has been found that the compound should have a particle size distribution such that at least 90% by weight, up to 100%, of the particles have a size less than about 200 microns (μm). Preferably, at least 90% by weight of the particles have a particle size less than about 100 μm and, more preferably, at least 99% by weight of the arc-extinguishing compound particles have a particle size less than 100 μm. To achieve the full advantage of this second embodiment of the compositions, articles...
third embodiment
[0069] In accordance with the compositions, articles and methods described herein, it has been found that by including a plasticizer for the binder polymer into the compositions, the structural properties of the molded articles are increased without sacrificing arc-extinguishing properties.
[0070] To determine which plasticizer(s) is suitable for a particular polymer binder, compatible plasticizers should have a solubility parameter (δ) suitable for the particular polymeric binder, as well known in the art. One method of determining solubility parameters (δ) is in accordance with ASTM Designation D-3132-84 (Re-approved 1990). The plasticizer for the polymeric binders should have a solubility parameter (δ) as close as possible to the solubility parameter of the polymeric binder. For example, some of the preferred polyamide (nylon) polymeric binders have solubility parameters (δ) as follows:
Preferred δ forδ for ε-δ for binderplasticizercaprolactamNylon 6: δ = 12.8311.5-14.012.7Nylon ...
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