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Soot control for diesel engine lubricants

Inactive Publication Date: 2007-10-04
HAIGH HEATHER M +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of a diesel engine, the fuel is a diesel fuel and the combustion thereof generally results in emissions from the exhausts of such vehicles which comprise three main components.
However, this retarded combustion has the disadvantage that it causes more soot to accumulate in the engine lubricant partly due to incomplete combustion of the fuel because of the lower combustion temperature, and partly due to increased soot deposition on the cylinder wall which is drawn down into the lubricant with the downward stroke of the piston.
The presence of soot in the lubricant has the adverse affects of causing viscosity increase and accelerated wear.
However, the higher temperatures whilst mitigating the formation of soot also result in the formation of increased amounts of NOx.
If, however, the engine temperature is lowered, incomplete combustion ensues and whilst this reduces the amount of NOx formed in the emissions, it also substantially increases the amount of soot generated.
As the soot builds up in the lubricant, the latter becomes more and more viscous and upon reaching a critical value can cause gelation of the lubricant and may eventually cause seizure of the engine.
Consequently, such wax isomerate base oils would be expected to have low solvency and poor additive solubility performance.

Method used

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  • Soot control for diesel engine lubricants
  • Soot control for diesel engine lubricants
  • Soot control for diesel engine lubricants

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0148]Blends were prepared comprising only GTL 6 of nominal KV 6.0 mm2 / s at 100° C., a mixture of only 150N and 600N Group I base oil the KV of the mixture being nominally 6.0 mm2 / s @ 100° C., and combinations of the GTL 6 and the 150N / 600N base oils. All contained 2.0 wt % (as received) dispersant Infineum C9268. The blends were tested in a soot handling screener test which adds 3 wt % carbon black to the blend replicating 3 wt % soot in the oil.

[0149]The screener test is summarized below:[0150]1. Prepared blend by adding designated amount of carbon black paste (20% carbon black) and test oil to a blender. Blend for 5 minutes at high speed.[0151]2. Transfer mixture to beaker with magnetic stir bar. Stir at 200 rpm for 1 hour at 65° C.[0152]3. Immediately after stirring, charge the mixture to the viscometer in the 100° C. KV bath. Allow sample to equilibrate for exactly 15 minutes, then measure the Kinematic viscosity.[0153]4. For each oil, measure the viscosity increase at each inc...

example 2

[0155]In this Example the relationship between GTL content and the desired thickening ability of two different viscosity modifiers at two different concentrations in blends is investigated. A 6.0 mm2 / s GTL 6 and a 6.0 mm2 / s Group I blend were used. No carbon black was added. The GTL / Group I base stock combinations used in Example 2 are the same as those used in Example 1 above.

TABLE 3% GTL / % Group I Blend0 / 10020 / 8040 / 6060 / 4080 / 20100 / 0Viscosity: Blend with 15 wt16.015.515.214.814.514.2% (as received) Paratone 8011(mm2 / s)Thickening parameter: %1.501.571.641.701.771.82Paratone 8011 / change inKV100Viscosity: Blend with 25 wt15.414.814.213.713.312.9% (as received) InfineumSVs 151 (mm2 / s)Thickening parameter: %2.652.853.053.253.443.64Shellvis 151 / change in KV100

[0156]Larger ratios of % viscosity modifier to change in viscosity represent less thickening ability or solubilizing power of the base stock of the deliberately added viscosity modifier. Smaller values, i.e., lower ratio values are ...

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PUM

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Abstract

The present invention is directed to a method for controlling soot induced viscosity increase in diesel engines, by using as the diesel engine lubricant an oil formulation comprising a base oil containing about 10 to 80 wt % GTL base stock and / or base oil and / or hydrodewaxed or hydroisomerized / catalytic (or solvent) dewaxed base stock and / or base oil in combination with 20 to 90 wt % conventional Group I petroleum derived base oil, said base oil being further combined with a polymeric viscosity modifier, and to the lubricating oil which effects such control over soot induced viscosity increase.

Description

CROSS REFERENCE TO RELATED APPLICATIONS[0001]This application claims the benefit of U.S. Provisional Application No. 60 / 788,213 filed Mar. 31, 2006.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The present invention relates to diesel engine lubricating oils and to the control of soot induced viscosity increase of the lubricating used in such engines.[0004]2. Description of the Related Art[0005]Internal combustion engines function by the combustion of fuels which in turn generate the power needed to propel vehicles. In the case of a diesel engine, the fuel is a diesel fuel and the combustion thereof generally results in emissions from the exhausts of such vehicles which comprise three main components. These are: soot and particulate matter, carbon monoxide and nitrogen oxides (the latter will hereafter be abbreviated as NOx for convenience). To alleviate environmental concerns, research is ongoing to reduce the levels of these emissions. NOx emission can be reduced ...

Claims

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Application Information

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IPC IPC(8): C10L1/22
CPCC10M111/02C10M111/04C10M169/04C10M169/041C10N2230/041C10M2203/1006C10M2205/173C10N2230/02C10N2230/04C10M2201/041C10N2030/02C10N2030/04C10N2030/041
Inventor HAIGH, HEATHER M.WELDON, BRANDON T.GAO, JASON Z.
Owner HAIGH HEATHER M
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