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High Purity Heavy Normal Paraffins Utilizing Integrated Systems

a technology of integrated systems and heavy normal paraffin, applied in the direction of hydrocarbon oil treatment products, hydrocarbon distillation, aromatic hydrocarbon hydrogenation, etc., can solve the problems of inconvenient adsorption separation, expensive equipment, and equipment is not readily replaced, so as to improve the purity of a normal paraffin stream, reduce contaminants, and reduce the concentration of heavy aromatics

Inactive Publication Date: 2012-06-28
UOP LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention improves the purity of a normal paraffin stream by selectively removing aromatic compounds from the extract stream. This process involves separating out a selected range of hydrocarbons, hydrogenating and removing contaminants, and selectively removing aromatic compounds from the extract stream. The technical effect is a purified heavy normal paraffin with reduced contaminants and aromatic compounds.

Problems solved by technology

While the multiport rotary disc valve of Carson (U.S. Pat. No. 3,040,777) provided a satisfactory valve design for the simultaneous interconnection of two independent groups of conduits such that each conduit of the first group could be brought into individual communication with every conduit of the second group, it is not suitable when three groups of conduits must be simultaneously interconnected in the same manner.
Adsorption separation uses expensive equipment, and the equipment is not readily replaced to increase the production of a product stream.

Method used

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  • High Purity Heavy Normal Paraffins Utilizing Integrated Systems

Examples

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Embodiment Construction

[0010]A high purity heavy normal paraffin is required for some applications. The high purity, also includes having a low aromatic content. Conventional methods for producing a heavy normal paraffin result in a product that contains an aromatic content greater than 0.5% by weight. The high purity heavy normal paraffins require a purity of greater than 99.5 wt. % with an aromatic content less than 100 ppm by weight. Conventional methods use a high pressure hydrogenation process to saturate the aromatics, but this does not increase the overall purity of the heavy normal paraffin.

[0011]Linear alkylbenzenes (LABs) and secondary alkane sulfonates (SASs) are types of surfactant components used for the production of detergents. The production of LABs requires a feedstream of linear olefins, which in turn can be produced from linear paraffins. The linear olefins useful for producing SASs for detergent production have linear carbons chains in the 10 to 20 range, and preferably in the 14 to 17...

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Abstract

A process is presented for producing a purified normal paraffin product stream. The process includes passing a hydrocarbon stream having the desired normal paraffins to an adsorption separation system. A process stream generated from the separation system and having the normal paraffins is passed to an adsorption unit for the selective adsorption of aromatic compounds from the process stream, thereby producing a purified product.

Description

FIELD OF THE INVENTION[0001]The invention relates to adsorption separation processes. The invention is specifically directed at a process to improve the capacity and purity of normal paraffins.BACKGROUND OF THE INVENTION[0002]The separation of various substances through selective adsorption is an important process for producing pure substances. However, this generally is a batch process, but with the development of simulated moving bed (SMB) technology, the adsorption separation process can be operated on a continuous basis. For simulated moving bed technology, the process uses a multiport rotary valve to redirect flow lines in the process. The simulation of a moving adsorbent bed is described in U.S. Pat. No. 2,985,589 (Broughton et al.). In accomplishing this simulation, it is necessary to connect a feed stream to a series of beds in sequence, first to bed no. 1, then to bed no. 2, and so forth for numerous beds, the number of beds often being between 12 and 24. These beds may be ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10G45/00
CPCC10G7/00C10G25/08C10G25/12C10G45/02C10G2400/30C10G67/06C10G67/14C10G2300/201C10G45/44
Inventor SOHN, STEPHEN W.BOZZANO, ANDREA G.PIEPER, JEFFREY L.
Owner UOP LLC
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