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Single-layer type electrophotosensitive material and image forming apparatus using the same

a technology of electrophotosensitive materials and image forming apparatuses, applied in the direction of electrographic process apparatus, instruments, optics, etc., can solve the problems of reduced potential, difficult on-off timing of transfer voltage, insufficient neutralization of negative space electric charges, etc., to reduce memory, improve sensitivity to positive or negative polarities, and high hole transferability

Inactive Publication Date: 2011-03-01
KYOCERA DOCUMENT SOLUTIONS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The solution effectively reduces exposure and transfer memories, preventing the generation of memory images even in systems without a charge neutralizing step, by ensuring balanced hole and electron transfer, thus improving image quality.

Problems solved by technology

However, the following problems such as generation of a memory image occur when using a conventional electrophotosensitive material in a reversal development type digital image forming apparatus.
However, on-off timing of the transfer voltage is very difficult and portion to be applied directly to the photosensitive material is often generated with respect to front / rear portions of the transfer medium.
However, in case where the sensitivity of the positively charging single-layer type photosensitive material to the negative polarity is drastically inferior (mobility of the electron transferring material is very small) or the photosensitive material is used in the image forming apparatus including no charge neutralizing step, negative space electric charges are not sufficiently neutralized and a reduction in potential is caused by an influence of space electric charges even if the photosensitive material is positively charged in the following charge step.
Furthermore, a difference in sensitivity appears in the development step, thus causing such problems that said portion turns into black in the image (memory image).

Method used

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  • Single-layer type electrophotosensitive material and image forming apparatus using the same
  • Single-layer type electrophotosensitive material and image forming apparatus using the same
  • Single-layer type electrophotosensitive material and image forming apparatus using the same

Examples

Experimental program
Comparison scheme
Effect test

examples 1 to 8

[0076]2.0 Parts by weight of a X type metal-free phthalocyanine (CGM-1) as the electric charge generating material, 70 parts by weight of a hole transferring material (HTM-1) represented by the general formula (1), 40 parts by weight of electron transferring materials (ETM-1 to ETM-8) represented by the general formulas (2), (3), (4) and (5), 100 parts by weight a bis-Z type polycarbonate resin having a weight-average molecular weight of 30,000 as the binder resin and 800 parts by weight of tetrahydrofuran were dispersed or dissolved in a ball mill for 24 hours to prepare a coating solution for single-layer type photosensitive layer. Then, an alumina tube as the substrate was coated with the coating solution according to a dip coating method, followed by hot-air drying at 125° C. for 30 minutes to form a single-layer type photosensitive material having a photosensitive layer of 20 μm in a film thickness.

examples 9 to 16

[0078]In the same manner as in Examples 1 to 8, except that titanyl phthalocyanine (CGM-2) was used as the electric charge generating material, single-layer type photosensitive materials were produced.

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Abstract

The present invention provides a single-layer type electrophotosensitive material comprising a conductive substrate and a photosensitive layer formed on the conductive substrate, wherein the photosensitive layer contains a phthalocyanine compound as an electric charge generating material, a hole transferring material and an electron transferring material in a binder resin, and that a difference in absolute value between a plus polarity sensitivity and a minus polarity sensitivity measured under the conditions of an exposure wavelength of 780 nm and an exposure energy of 1.0 μJ / cm2 is not more than 500312 V, and a reversal development type digital image forming apparatus using the electrophotosensitive material, which does not include a charge neutralizing step.

Description

[0001]This application claims priority to Japanese Patent Application No. 1999-302914, filed on Oct. 25, 1999, the disclosure of which is incorporated by reference in its entirety.BACKGROUND OF THE INVENTION[0002]The present invention relates to a single-layer type electrophotosensitive material which is used in digital image forming apparatuses such as electrophotosensitive copying machine, facsimile and laser beam printer, and a digital image forming method using the same.[0003]More particularly, the present invention relates to a single-layer type electrophotosensitive material, which does not generate a memory image even when using in a reversal development type digital image forming apparatus including no charge neutralizing step, and a reversal development type digital image forming method using the same, which does not include a charge neutralizing step.[0004]Recently, an organic photosensitive material has widely been used because of its easy production, low cost, wide range...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): G03G5/09G03G13/22G03G5/04G03G5/06
CPCG03G5/04G03G5/0609G03G5/0638G03G5/0672G03G5/0696G03G13/16G03G13/22
Inventor IMANAKA, YUKIKATSUIWASAKI, HIROAKITANAKA, YUJIHAYASHI, MASAKATSU
Owner KYOCERA DOCUMENT SOLUTIONS INC