Conductive polymer gel and process for producing the same, actuator, patch label for ion introduction, bioelectrode, toner, conductive functional member, antistatic sheet, printed-circuit member, cond
A conductive polymer, conjugated polymer technology, applied in conductive coatings, circuits, fuel cells, etc., can solve the problem of reducing the thickness of electrodes 3103 and fuel cells, and achieve excellent compatibility, good conductivity, and low cost. Effect
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[0138] Figure 11 is a schematic sectional view showing an example of the toner 1001 according to the embodiment of the present invention.
[0139] The toner 1001 includes a generally spherical core portion 1011 made of a conductive polymer gel 1002 and a resin portion 1012 provided on the surface of the core portion 1011 .
[0140] The particle size of the toner 1001 is preferably 15 μm or less, more preferably 8 μm or less. Therefore, when the toner 1001 is transferred and fixed to the base material, excellent resolution can be achieved and pattern wiring with a fine line width can be formed.
[0141] As shown in FIG. 13B , conductive polymer gel 1002 contains water 1021 , conductive conjugated polymer 1022 , and surfactant 1023 and / or alcohol as main components.
[0142] The conductive polymer gel 1002 is formed by gelling the conductive conjugated polymer 1022 using a surfactant 1023 and / or alcohol, and those conductive polymers proposed in Japanese Patent Application No...
Embodiment 1
[0364] In this example, 100 parts by weight of a colloidal dispersion of conductive conjugated polymer colloidal dispersion PEDOT / PSS (B about 1.3 weight percent of a colloidal aqueous dispersion of conductive polymer (PEDOT / PSS), prepared by Bayer Co., Trade name: Baytron P) and 0.7 parts by weight of dodecylbenzenesulfonic acid (C 12 h 25 C 6 h 4 SO 3 H) (hereinafter also referred to as DBS) was mixed and stirred for about 10 minutes, and the mixture was left in a closed state at 10°C, 25°C, and 50°C for 1 day to obtain gelatinized samples at different standing temperatures.
[0365] As for the samples obtained at each standing temperature, the degree of gelation was examined. The degree of gelation was evaluated by the following three grade standards (indicated by symbols ○, Δ, ×).
[0366] ○: Cured to obtain a self-supporting gel
[0367] △: Not cured, but high viscosity
[0368] ×: Does not meet the above two criteria (○, △)
[0369] In the case where a gel corres...
Embodiment 2
[0371]In this example, except that the amount of DBS mixed as an additive was changed to 1.0 parts by weight, it was operated in the same manner as in Example 1, and then left in a closed state at a standing temperature of 10°C, 25°C, and 50°C The mixture was kept for 1 day to obtain gelled samples at different storage temperatures.
[0372] As for the corresponding samples obtained in this example, the degree of gelation was evaluated and the conductivity was measured in the same manner as in Example 1. Table 1 shows the results of the evaluation of the degree of gelation and the results of the conductivity measurement.
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