Positive pole in use for lithium cell, and preparation method
A lithium battery and battery technology, applied in the direction of electrode manufacturing, active material electrodes, etc., can solve the problems of terminating battery life, severe electrochemical polarization, and battery voltage drop, and achieve the effect of expanding the application field and reducing electrochemical polarization
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Embodiment 1
[0011] A positive electrode for a lithium battery (lithium thionyl chloride battery), mainly composed of two positive electrode films located on both sides of a nickel material, the positive electrode film is mainly composed of acetylene black, polytetrafluoroethylene and CuCl 2 Prepared from raw materials, the mass percentage of each raw material is: 86.5% acetylene black, 8.5% polytetrafluoroethylene, CuCl 2 5.0%.
[0012] The preparation method of the positive pole of above-mentioned a kind of lithium battery, it comprises the steps:
[0013] 1), ingredients: dissolve 5.0 g of CuCl with 500 ml of ethanol with a mass concentration of 95% 2 , mixed well into a mixed with CuCl 2 The ethanol solution of 8.5g polytetrafluoroethylene is made the polytetrafluoroethylene aqueous emulsion that mass concentration is 60%;
[0014] Measure 86.5g of acetylene black and polytetrafluoroethylene aqueous emulsion and mix uniformly to obtain active substance mixture A; measure and mix CuC...
Embodiment 2
[0025] A positive electrode for a lithium battery (lithium thionyl chloride battery), mainly composed of two positive electrode films located on both sides of a nickel material, the positive electrode film is mainly composed of acetylene black, polytetrafluoroethylene and CuBr 2 Prepared from raw materials, the mass percentage of each raw material is: acetylene black 86.5, polytetrafluoroethylene 8.5, CuBr 2 5.0.
[0026] The preparation method of the positive pole of above-mentioned a kind of lithium battery, it comprises the steps:
[0027] 1), ingredients: dissolving 5.0 g of CuBr with 500 ml of ethanol with a mass concentration of 96% 2 , mix well into a mixture with CuBr 2 The ethanol solution of 8.5g polytetrafluoroethylene is made into the polytetrafluoroethylene aqueous emulsion that mass concentration is 60%, and is standby;
[0028] Measure 86.5g of acetylene black and polytetrafluoroethylene aqueous emulsion and mix uniformly to obtain active substance mixture A;...
Embodiment 3
[0039] A positive electrode for a lithium battery (lithium thionyl chloride battery), mainly composed of two positive electrode films located on both sides of a nickel material, the positive electrode film is mainly composed of acetylene black, polytetrafluoroethylene and CuCl 2 Prepared from raw materials, the mass percentage of each raw material is: acetylene black 84.1, polytetrafluoroethylene 7.8, CuCl 2 8.1.
[0040] The preparation method of the positive electrode of the above lithium battery is the same as in Example 1, and the properties are shown in Table 3.
[0041] table 3
[0042] battery model
After improvement
(discharge system 1)
before improvement
(discharge system 1)
After improvement
(discharge system 2)
before improvement
(discharge system 2)
ER14505
1278mAh
997mAh
2435mAh
2101mAh
[0043] Discharge system 1: 400mA constant current discharge to 2V at 23±2℃.
[0044] Dischar...
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