Flame-retardant resin composition, process for producing the same, and method of molding the same
A technology of resin composition and flame retardancy, which is applied in the field of resin composition, can solve the problem of low usefulness, and achieve the effect of industrial value, usefulness and great industrial value
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Embodiment 1
[0049] 70 wt% of polylactic acid (PLA) synthesized from corn and 30 wt% of polybutylene succinate (PBS) were kneaded using a twin-screw mixer to produce pellets. Here, the purpose of mixing PBS is to improve heat resistance.
[0050] In this example, iron acetylacetonate (Fe(acac) 3 ) by SiO 2 supported by porous bodies. Fe(acac) 3 The loading ratio of the porous body was 60 parts by weight with respect to 100 parts by weight of the porous body. Using a twin-shaft mixer, at 185 ° C, for 90 wt% of the particles obtained in step 1, and loaded with Fe(acac) 3 SiO 2 10wt% of the porous body is kneaded (step 2), and molded into a test piece of 125mm × 13mm × 3.2mm (the forming temperature is 180°C, and the pressure is 120kg / cm 2 ) (step 3). SiO used in this example 2 The porous body has a porosity of about 45 to 50 vol%, and a particle diameter of about 100 nm to 1000 nm. The SiO 2 When the porous body is kneaded with the resin, it is crushed by shearing force, and finall...
Embodiment 2
[0053] In the particles obtained in step 1 of Example 1, kneading was not affected by SiO 2 Iron acetylacetonate (Fe(acac) 3 ) powder, the Fe(acac) required to obtain a flame-retardant resin composition suitable for UL standard V0 was obtained 3 the mixing ratio.
[0054] The matching sequence of the composition in this embodiment is the same as that of Example 1, and can be used figure 1 flow chart representation. In this example, the granules obtained in step 1 and Fe(acac) 3 Carry out kneading (step 2), press molding is the test piece of 125mm * 13mm * 3.2mm (forming temperature is 180 ℃, and pressure is 120kg / cm 2 ) (step 3). In this example, changing the particle and Fe(acac) 3 A number of test pieces were produced and evaluated for their flame retardancy. Fe(acac) 3 is not covered by SiO 2 The porous body is supported and used in the form of a powder having a particle diameter of about 2 to 80 μm. At this time, the powder is not pulverized by kneading, but is d...
Embodiment 3
[0056] In the same procedure as in Example 1, polylactic acid (PLA) and polybutylene succinate (PBS) were kneaded to produce pellets (step 1).
[0057] The matching sequence of the composition in this embodiment is the same as that of Example 1, and can be used figure 1 flow chart representation. In this example, SiO 2 The flame retardant component carried by the porous body is zinc borate. Zinc borate was supported at a ratio of 42 parts by weight with respect to 100 parts by weight of the porous body. Using a twin-shaft mixer, at 185°C, 90 wt% of the particles obtained in step 1, zinc borate-loaded SiO 2 10wt% of the porous body is kneaded (step 2), and molded into a test piece of 125mm × 13mm × 3.2mm (the forming temperature is 180°C, and the pressure is 120kg / cm 2 ) (step 3). SiO used in this example 2 Porous body and SiO used in Example 1 2 The porous body is the same, and through kneading, it finally becomes nano-sized particles dispersed in the resin. In additio...
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