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Wooden modifying composition, production and use thereof

A technology of wood modification and composition, applied in botany equipment and methods, wood treatment, impregnated wood, etc., can solve problems such as pollution and hazards, and achieve the effects of enhanced densification, good weather resistance and service life

Inactive Publication Date: 2009-09-16
陈万利 +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, long-term and large-scale use of heavy metal ions will cause irreversible pollution and harm to the human body and the surrounding environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Synthesis of protective glue:

[0038] Add 500kg of 37% formaldehyde and 40kg of borax to the reaction kettle, adjust the pH to 8 with ammonia water, then add 190kg of urea and 80kg of melamine, raise the temperature to 92°C, keep it warm for about 1hr, cool down to 65°C, add 14kg of boric acid, keep it warm for 15min, add Dicyandiamide phosphate 100kg and then keep warm for 20 minutes, adjust the pH of the material to 5.8 with ammonia water, cool down to about 50°C and discharge.

[0039] Preparation of mixed emulsifier: mix 15kg of didecyldimethylammonium chloride, 4kg of sodium lauryl sulfate, 13kg of sodium salt of alkylphenol ether sulfosuccinate and 13kg of decylphenol polyoxyethylene ether. have to.

[0040] Synthesis of pre-emulsified monomers: Add 500kg of water, 30kg of mixed emulsifier, and 6kg of N-methylolacrylamide into the reactor and stir evenly, then add 110kg of mixed monomers butyl acrylate, 320kg of styrene, and isooctyl acrylate 150kg, 5kg of acry...

Embodiment 2

[0044] Synthesis of protective glue:

[0045] Add 400kg of 37% formaldehyde and 35kg of borax to the reaction kettle, adjust the pH to 8.5 with ammonia water, then add 160kg of urea and 60kg of melamine, raise the temperature to 92°C, keep it warm for about 1hr, cool down to 70.5°C, add 12kg of boric acid, keep it warm for 30min, add 90kg of dicyandiamide phosphate was kept warm for another 30 minutes, and the pH of the material was adjusted to 6.2 with boric acid, and the temperature was lowered to about 50°C for discharge.

[0046] Preparation of mixed emulsifier: 18 kg of dodecyl dimethyl benzyl ammonium chloride, 6 kg of sodium lauryl sulfate, 13 kg of sodium alkylphenol ether sulfosuccinate and 13 kg of decylphenol polyoxyethylene ether Mix well and serve.

[0047] Synthesis of pre-emulsified monomers: Add 500kg of water, 33.5kg of mixed emulsifier, and 5kg of N-methylolacrylamide into the reactor and stir evenly, then add 110kg of mixed monomers butyl acrylate, 300kg of s...

Embodiment 3

[0051] Synthesis of protective glue:

[0052] Add 450kg of 37% formaldehyde and 35kg of borax to the reaction kettle, adjust the pH to 8.3 with ammonia water, then add 175kg of urea and 65kg of melamine, heat up to 95°C, keep it warm for about 1hr, cool down to 70°C, add 12kg of boric acid, keep it warm for 20min, add Dicyandiamide phosphate 90kg and then keep warm for 20 minutes, adjust the pH of the material to 6.0 with ammonia water, cool down to about 50°C and discharge.

[0053] Preparation of mixed emulsifier: 8 kg of dodecyl dimethyl benzyl ammonium chloride, 7 kg of didecyl dimethyl ammonium chloride, 6 kg of sodium lauryl sulfate, sodium alkylphenol ether sulfosuccinate Mix 17kg of salt and 17kg of decylphenol ethoxylate evenly.

[0054] Synthesis of pre-emulsified monomers: Add 500kg of water, pre-dispersed wood dye, 37kg of mixed emulsifier, and 5kg of N-methylolacrylamide into the reactor and stir evenly, then add 110kg of mixed monomer butyl acrylate, benzene 31...

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Abstract

The invention discloses a new wood modification composition and its preparation method and application. The composition is mainly made of the following raw materials: 37% formaldehyde, borax, ammonia water, urea, melamine, boric acid, dicyandiamide phosphate, High carbon alkyl quaternary ammonium salt, sodium lauryl sulfate, sodium alkylphenol ether sulfosuccinate, decylphenol polyoxyethylene ether, N-methylol acrylamide, butyl acrylate, styrene, Isooctyl acrylate, acrylic acid, tertiary dodecyl mercaptan, ammonium persulfate, sodium bicarbonate, sodium metasulfite, chlorinated paraffin with a chlorine content of 50-60%, silica microemulsion with a solid content of 45% and / or 40 % solid content of hydrated aluminum oxide microemulsion. The artificial forest and low-grade wood modified by the composition of the present invention not only have significantly improved physical and mechanical properties, but also have excellent fire-retardant, moth-proof, mildew-proof and anti-corrosion properties, and also overcome the existing wood preservatives. Generally contain defects such as heavy metal ions and other toxic components.

Description

technical field [0001] The invention relates to a composition for wood modification and a preparation method thereof, in particular to a composition for modification of artificial forest materials and other low-grade wood, and belongs to the field of forestry chemical industry. Background technique [0002] Densifying and modifying wood to increase its density, and then increase its physical and mechanical properties such as hardness and strength, is a feasible way to improve the quality of wood. For example, unsaturated olefin monomer or prepolymer is injected into wood tissue, and then under the initiation of thermal initiator or thermal radiation source, it is polymerized and solidified in wood to form a wood-plastic composite (Zhu Wei, Guo Fengping. Plastic New developments in wood research [J]. Journal of Northwest Forestry University, 1998, 13(4): 82-91; edited by Lu Wenda. Wood Modification Technology [M]. Harbin: Northeast Forestry University Press, 1993; Feist W C,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B27K3/52B27K5/02C09K3/00B27K3/50
CPCB27K2240/30B27K3/52A01N35/02B27K3/50
Inventor 吴子良陈万利
Owner 陈万利
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