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Metal surface lacquer with flip-flop effect and its preparing method

A technology of changing color with angle and metal surface, which is applied in the field of metal topcoat with effect of changing color with angle and its preparation, and achieves the effect of enhancing anti-ultraviolet ability, improving weather resistance and good stability

Inactive Publication Date: 2009-11-04
FUDAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is no metal flash automotive topcoat technology and related patent reports modified by inorganic nanoparticles

Method used

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  • Metal surface lacquer with flip-flop effect and its preparing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Formula 1 for metallic finishes with flop effects

[0047] Ingredient parts by weight wt(%)

[0048] Nano particle dispersion 4.8

[0049] Setal173 (polyester resin) 21

[0050] Setamine138 (amino resin) 5.5

[0051] BI7982 (modified resin) 3.7

[0052] Metallux2154 aluminum powder) 3.5

[0053] CAB381-0.5 (aluminum powder directional agent) 4.7

[0054] Solvent 56

[0055] Auxiliary 0.8

[0056] The above formula is prepared according to the preparation method proposed by the invention, and a metal topcoat with a color-dependent effect can be obtained. The color-dependent effect of the coating (visual inspection): good, stone chip resistance: ≤2 grades, gloss (Gloss 20°) 97, Haze Hlog 95, artificial accelerated aging resistance time ≥ 1500 hours, other coating properties passed GB / T13492-92.

Embodiment 2

[0058] Metallic topcoat formulation with floppy effect 2

[0059] Ingredient parts by weight wt(%)

[0060] Nanoparticle dispersion paste 7.4

[0061] Desmophen 650 (polyester resin) 37

[0062] Setamine133 (amino resin) 21.3

[0063] Metallux2154 (aluminum powder) 1.3

[0064] CAB381-0.5 (aluminum powder directional agent) 3.3

[0065] Solvent 30.6

[0066] Auxiliary 1.1

[0067] The above formula is prepared according to the preparation method proposed by the invention, and a metal topcoat with a color-dependent effect can be obtained. The color-dependent effect of the coating (visual inspection): good, stone chip resistance: ≤2 grades, gloss (Gloss 20°) 95, haze (Haze Hlog) 127, artificial accelerated aging resistance time ≥ 1500 hours, good wear resistance of the coating, other coating properties passed GB / T13492-92.

Embodiment 3

[0069] Metallic topcoat formulation with floppy effect 3

[0070] Ingredient parts by weight wt(%)

[0071] Nano particle dispersion slurry 0.9

[0072] Desmophen 650 (polyester resin) 14

[0073] Setal173 (polyester resin) 12

[0074] Setamine133 (amino resin) 7.1

[0075] C1158 (amino resin) 2.6

[0076] Vestanat BI358A (modified resin) 6.9

[0077] SSP504-AR (aluminum powder) 7.7

[0078] CAB381-0.5 (aluminum powder directional agent) 2.5

[0079] CAB551-0.2 (aluminum powder directional agent) 4

[0080] Pearlescent Pigment 3

[0081] Solvent 36.9

[0082] Auxiliary 2.4

[0083] The above formula is prepared according to the preparation method proposed by the invention, and a metal topcoat with a color-dependent effect can be obtained. The color-dependent effect of the coating (visual inspection): good, stone chip resistance: ≤2 grades, gloss (Gloss 20°) 96, haze (Haze Hlog) 189, artificial accelerated aging resistance time ≥ 1500 hours, other coating properties ...

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Abstract

The invention relates to a metal topcoat with an angle-dependent color effect and a preparation method thereof. The present invention adopts stable and transparent nano-particle dispersion slurry with color-dependent effect, and polyester resin, amino resin, blocked isocyanate modified resin, metal aluminum powder, other pigments and fillers, solvents, and additives In combination, a certain preparation process is used to prepare a metal topcoat with a color-dependent effect. By adopting the method provided by the invention, the nanoparticles are evenly dispersed in the paint, and the prepared metal topcoat has high gloss and low haze value, and has obvious color flop effect and good decoration, scratch resistance and stone chip resistance Resistance, abrasion resistance and aging resistance. Used in car topcoat, metal exterior decoration paint, etc.

Description

technical field [0001] The invention belongs to the field of chemical industry, and relates to a metal topcoat with an angle-dependent color effect and a preparation method thereof. Background of the invention [0002] The high-grade and high-performance requirements of automobiles force the development of automobile coatings to continuously improve their protection and decoration performance. The main focus is to improve the decoration of the car surface, improve the scratch resistance and anti-corrosion ability, and better protect the environment, especially the surface protection and decoration layer of the car body, which directly affects the appearance and appreciation of the whole car. [0003] The research and development and industrialization of nano-materials for modified automotive coatings started earlier in the United States and Germany, and the research and development of nano-modified automotive coatings started relatively late in China. CN1189522A, a patent fo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D167/00B05D7/14
Inventor 武利民刘娅莉于占锋游波周树学
Owner FUDAN UNIV
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