68results about How to "Good stone chip resistance" patented technology

The invention relates to a preparation method of high-reaction-activity hydroxyl acrylic resin. According to the invention, a solvent in a reactor is heated to a preset temperature under the protection of an inert gas; a mixture of a monomer component A with hard monomer as a main component (and comprising a small amount of soft monomer, hydroxyl monomer and carboxyl monomer) and an initiation agent is slowly added; a reaction is carried out for a certain period of time with maintained temperature; a mixture of a monomer component B with soft monomer as a main component (and comprising a small amount of hard monomer, hydroxyl monomer and carboxyl monomer) and an initiation agent is slowly added; and reaction is carried out for a certain period of time with maintained temperature, such that acrylic resin comprising hydroxyl is obtained. The invention has the characteristic that common monomers are adopted, and only the synthesis process is changed wherein monomer dropping sequence is changed, such that resin molecular structure is substantially changed, and the synthesized hydroxyl acrylic resin shows high reaction activity during a curing reaction. The method provided by the invention also has the advantages of low cost, simple process, and suitability for industrialized productions.

The invention discloses a making method of scraping-proof, stone-impacting resistant aqueous nanometer automobile paint in the chemical paint making technical domain, which comprises the following parts: 60-70% paint filming base, 5-15% nanometer powder, 20-25% solvent water and 0.5-1.0% adjuvant, wherein the adjuvant contains thickener, dispersant, defoamer and filming agent; the weight rate of crosslinking agent and nanometer emulsion is 0.9:1-1:1; the crosslinking agent is chemical material of melamine type; the scraping-proof index of paint layer can be 96-99% (displayed by glass keeping rate).

The invention discloses paint for a train body surface of a high speed train, which is prepared by preparing a matrix resin by mixing elastic polyester with high hydroxyl value and hydroxylated acrylic resin, using rutile type titanium dioxide as a pigment, using silicon-aluminum base ceramic cenosphere as a filler and using a nanometer ATO and a nanometer SiO2 as modified materials; preparing a component A by the processes of grinding, stirring, mixing, packaging and the like in the presence of an auxiliary and a solvent; and using HDI tripolymer N-3390 as a component B; and mixing the component A and the component B. The paint has the advantages of high adhesive force, high hardness, sand rock impact resistance, heat insulation, energy-saving, corrosion resistance, temperature change resistance, high weather resistance, easy cleaning, decorativeness, strong security and long service life, and is suitable for protective paint of the train body surface of the high speed train.

The invention relates to a preparation method of waterborne non-isocyanate polyurethane modified polyester and provides a preparation method of the waterborne non-isocyanate polyurethane modified polyester. The preparation method comprises the following steps: (1) preparation of unsaturated prepolymer containing a urethane bond; (2) preparation of polyester containing an unsaturated double bond; (3) graft polymerization of the prepared polyester containing the unsaturated double bond, and the prepolymer; and (4) dispersion of a graft polymer. The invention also provides an application of the prepared waterborne non-isocyanate polyurethane modified polyester in vehicle coatings.

A waterborne automobile coating composition is provided. The composition is prepared from, by weight, 20-60 parts of a waterborne polyurethane dispersoid, 1.0-3.5 parts of a dispersing agent, 5-15 parts of titanium dioxide, 5-15 parts of precipitated barium sulfate, 0.1-0.5 part of carbon black, 0.5-1.5 parts of a defoamer, 3-8 parts of a waterborne hydroxy acrylic acid dispersoid, 0.1-0.5 part of an organic amine, 6-12 parts of amino resin, 0.1-1 part of a substrate wetting agent, 1-3 parts of an explosion-proof auxiliary agent, 1-5 parts of a cosolvent, 20-40 parts of deionized water and 0.1-1 part of a thickening agent. The waterborne polyurethane dispersoid is a compound of a polycarbonate-type waterborne polyurethane dispersoid having hydroxy groups and a polyester-type waterborne polyurethane dispersoid preferably. The coating composition has excellent resistance to rock crash, and can meet requirements on an automobile coating process including three times of coating and one time of baking, namely a 3C1B process, in the field of environment protection.

The invention discloses a stone-hitting resisting automobile middle coating which is composed A and B components, A:B is equal to 1:(1.5-8), A component is formed by dissolving polyisocyanate soft resin and high crosslinking polyisocyanate hard resin in solvent, B component is formed by dissolving acrylic resin, titanium pigment, furnace black, talcum powder, dispersing auxiliary, functional resin, anti-sedimentation assistant, leveling agent and drying accelerator in solvent; in the stone-hitting resisting automobile middle coating, by matching more than two different soft and hard polyisocyanate resins which are self-prepared, the automobile middle coating which has good stone-hitting resisting performance and good construction rubbing property is obtained; the two components in the stone-hitting resisting automobile middle coating have good mild water resistance, acid resistance and alkali resistance, the film is flexible and hard and has adhesive force with a bottom layer and good bonding force with a surface layer; the thickness of dry film of the film formed by one step can reach 40-60mum, the leveling property is good, the surface roughness of the middle coating can reach Ra:0.13, DOI (Dorigon) average value of spraying finishing paint rear automobile body is 83-86 and reaches high level.

The invention discloses a coating for blades of a wind generation set, which is formed by polyurethane NEUKAPOL 1007, polyester ether NEUKADUR 1036, curing agents, auxiliaries, auxiliaries and titanium dioxide powder R930. Double-component polyurethane NEUKAPOL 1007 and double-component polyester ether NEUKADUR 1036 are chosen, the chosen polyurethane and polyester ether are low-viscosity resin with high hydroxyl values (respectively being 550-590 and 160-170), the resin is very small in molecular weight and can form coating films with high cross-linking density, the coating films have extra high surface hardness and excellent elasticity, bending resistance, elasticity and physical and mechanical performance and can avoid stress concentration, and therefore the coating films formed by the coating have good tensile strength, tearing strength and stone striking resistance, and service life of the wind generation set is ensured.

The invention provides the preparation method of a water intermediate coating suitable for automobile factories and repair. The coating prepared by the method is universally suitable for automobile factories and repair. The preparation method comprises the following steps and process conditions: (1) synthesizing water-dispersible resin; (2) modifying hydrophilic polyisocyanate; (3) preparing the intermediate coating for automobile factories and repair; and (4) mixing the intermediate coating prepared in step (3) with the hydrophilic end-terminated polyisocyanate synthesized in step (2) to obtain the final product. The prepared intermediate coating has high applicability and is suitable for factory manufacturing and for repair. The intermediate coating is very friendly to the environment and greatly reduces the use of and the dependence on organic solvent, thus effectively conserving the energy resources. Additionally, the coating has the advantages of excellent flexibility, particularly high chip resistance and water resistance, smooth and fine coating surface and excellent interlayer adhesive force with the prime coat and the top coat.

The present invention relates to a kind of metal surface lacquer with flip-flop effect and its preparation process. The metal surface lacquer with flip-flop effect is prepared with dispersive nanometer particle slurry with flip-flop effect together with polyester resin, amino resin, closed isocyanate modified resin, metal aluminum powder, pigment and stuffing, solvent and assistant, and through certain technological process. The present invention has nanometer particle dispersed homogeneously in paint, and the prepared metal surface lacquer has high brightness, low haze value, obvious flip-flop effect, excellent decoration effect, high scrape resistance, high stone attack resistance, high wear resistance and good ageing resistance. The lacquer is used for car surface, outer metal decoration, etc.

The invention provides modified polyester, which is prepared by the following steps of: a) under the action of an antioxidant and a catalyst, reacting polyhydric alcohol and alkene diacid with polybasic acid to obtain polyester; b) adding an aqueous cosolvent into the polyester to obtain a polyester mixture; c) adding a first monomer, a second monomer, a third monomer and a radical initiator into the polyester mixture, and continuously reacting to obtain a first intermediate product, wherein the first monomer is one or two of crylic acid and methacrylic acid, the second monomer is one or more of acrylic ester and styrene, and the third monomer is crylic acid hydroxy ester; and d) adding a neutralizer into the first intermediate product, and stirring for neutralization to obtain the modified polyester. The invention also provides a water-borne middle coating composition. Experiments show that the water-borne middle coating composition has the stone-chip resistance of less than or equal to 3 grade, the impact strength of more than or equal to 50kg.cm and the lustre of 70 to 80 percent at 60 DEG C.

The present invention relates to water dispersed resin and paint for the intermediate coat of vehicle. The resin is water dispersed matter produced through condensation polymerizing hydrophilic polyester resin with acid value of 20-60 and hybrophobic polyester resin with acid value below 5 and obtained via ring-opening polymerization of epsilon-caprolactone in the weight ratio of 1-3 and has acid value of 10-25, hydroxyl value of 50-100 and number average molecular weight of 3000-5000. The paint with the water dispersed resin as filming agent contains water dispersed amino resin and water enclosed polyisocyanate mixed crosslinking agent. The paint has organic volatile matter less than 8 % and can form smooth coat with high adhesive force, good water resistance and flexibility and excellent high shock resistance.

The invention discloses plastisol for an automobile chassis and a preparation method of the plastisol. PVC (polyvinyl chloride) paste resin and DOP (dioctyl phthalate) are taken as main materials, and the plastisol comprises components in parts by weight as follows: PVC paste resin, DOP, KCM-12, heavy calcium carbonate, a lead sulfate tribasic stabilizer, ZnO, low-molecule polyamide, nano activated calcium carbonate, CaO and a viscosity reducer.

The invention relates to polyester resin used for a transparent powdery paint and a preparation method thereof, and provides the polyester resin having good stone chip-resistant performance used for the transparent powdery paint and the preparation method thereof. The polyester resin comprises the following main components by mass percentage through fusion polymerization: a polyols component A, a polyacids component B, a hydrogenated dimeric acid component C, an esterification catalyst component D, an alcoholysis agent component E, an anti-oxidant component F and a curing accelerator component G; the preparation method comprises the following steps: adding the component A, then adding the component B, the component C and the component D, stirring the components and gradually heating the components; performing a melt esterification condensation reaction; performing a primary pressure reduction reaction; adding the component E and performing an alcoholysis reaction; performing a secondary pressure reduction reaction; adding the component F and the component G, stirring the components for a reaction; cooling the materials and discharging the product, and cooling the product and crushing the product. A polyurethane transparent powdery paint film prepared by the polyester resin has excellent levelability, high glossiness and transparency, and good stone chip-resistant performance.

The invention discloses a primer surfacer for automobiles. The primer surfacer comprises a component A and a component B. The component A comprises the following raw materials by weight: 10-20 parts of a waterborne polyurethane dispersion, 12-23 parts of polyester resin, 5-15 parts of acrylic modified polyurethane, 2-8 parts of an acrylic emulsion, 5-8 parts of acrylic resin, etc.; and the component B is a curing agent, and the weight ratio of the component A to the component B is (6-10):1. The invention also provides a preparation method and application of the primer surfacer. The primer surfacer disclosed by the invention has the characteristics that the primer surface can meet wet-to-wet construction process and the coating film can be baked and cured at a low temperature (60-100DEG C),and also has excellent adhesive force, stone impact resistance, wear resistance, chemical resistance and other physical and chemical properties while having good construction performance and coatingfilm appearance.

The invention provides a high-crack-resistance damping coating. The high-crack-resistance damping coating comprises the following raw materials in parts by weight: 290 to 310 parts of an acrylic acid waterproof emulsion, 95 t 105 parts of an anti-rust emulsion, 45 to 55 parts of a plasticized acrylic acid emulsion, 13 to 17 parts of a film-forming aid, 90 to 110 parts of functional fillers and 45 to 55 parts of corrosion-resistant fillers. The damping coating has high flexibility, impact resistance and high stone crash resistance, and solves the problem that the profile 90-degree transitional coating is susceptible to cracking.

The invention belongs to the technical field of automobile coating and specially relates to water-based high temperature plain colored paint capable of being used for a wet-on-wet middle-coating-freesystem and a preparation method thereof. The water-based high temperature plain colored paint capable of being used for the wet-on-wet middle-coating-free system includes an A component and a B component, wherein the A component includes aqueous acrylic acid polyol dispersion, aqueous polyurethane dispersion, ultrafine talc powder, ultrafine barium sulfate, aluminum triphosphate, titanium dioxide,carbon black, an aqueous dispersant, methylated amino resin and pure water; and the B component includes the aqueous acrylic acid polyol dispersion, the aqueous polyurethane dispersion, an amine neutralizer, ethylene glycol butyl ether, titanium dioxide, a dispersant, methylated amino resin, a thickening agent and pure water. The water-based high temperature plain colored paint capable of being used for the wet-on-wet middle-coating-free system has excellent properties, strong paint film adhesion, high paint film hardness, and good water resistance, acid resistance, alkali resistance, weatherresistance and stone-chipping resistance, and environmental protection.

The invention discloses a high strength and energy saving flexible bridge frame, which includes a bridge frame shell. The bridge frame shell is externally provided with a protective coating formed by paint, and the paint is composed of polyurethane, epoxy resin, acrylic resin, polytetrafluoroethylene, polyethylene glycol, butanediol, linseed oil, alumina, ceramic powder, silicon powder, cerium oxide, a solvent, a curing agent, aluminum potassium sulfate and sodium fluosilicate. Due to adoption of polyurethane, epoxy resin, acrylic resin and polytetrafluoroethylene by the invention, the high crosslinking density paint can be formed through mutual synergistic effects of the resins. The paint has extremely high surface hardness, excellent flexibility, bending resistance and flexibility, and excellent physical and mechanical properties, thus being able to avoid stress concentration. Therefore, the film formed by the paint has very good tensile strength, tear strength and stone impact resistance, thereby ensuring the service life of the bridge frame.

The invention provides an automobile water-based primer surfacer with excellent chip resistance and a preparation method thereof. The automobile water-based primer surfacer is characterized by consisting of the following components in parts by weight: 18-26 parts of water-based epoxy resin, 36-45 parts of water-based polyester resin, 0.1-0.4 part of gas-phase silicon dioxide anti-settling agent, 7-12 parts of methylated melamine resin, 6-10 parts of talc powder, 10-15 parts of calcium carbonate, 4-7 parts of barium sulfate, 8-13 parts of butyl cellosolve, 0.2-0.5 part of water-based dispersing agent, 0.1-0.4 part of water-based leveling agent and 0.2-0.6 part of water-based wetting agent. The water-based automobile primer surfacer provided by the invention has excellent chip resistance and impact strength, wherein the chip resistance can reach the level 3, and the impact strength is 294N.cm; the performances such as gloss, adhesion, heat and humidity resistance, salt mist resistance and the like reach the standard for a solvent type automobile primer surfacer.

The invention relates to the technical field of coating, in particular to a dual-component waterborne polyurethane intermediate coating composition with anti-sagging characteristics and a preparationmethod thereof. The composition is mainly prepared from an A component and a B component. The A component is prepared from, by mass, 28-45% of hydroxyl functionalized waterborne acrylic resin, 2-9% ofa cosolvent A, 0.2-1.2% of a dispersant, 0.2-0.35% of a leveling agent, 0.1-0.3% of a defoamer, 0.1-0.45% of a pH regulator, 6-17% of pigment, 14-40% of a filler, 4.5-12.5% of a waterborne anti-sagging polymer containing a polyurea group and 6.55-12% of deionized water. The composition has excellent sagging resistance, adhesive force, waterproofness and resistance to stone crash.

The invention discloses water-based middle coating high in stone-chip resistance. The water-based middle coating is prepared from, by weight, 2-10 parts of oil-free saturated polyester, 15-35 parts ofmodified alkyd resin, 15-35 parts of water-based polyester resin, 2-10 parts of mixed etherified melamine resin, 2-10 parts of methylated amino resin, 1-5 parts of blocked isocyanate, 2-10 parts of polyurethane resin, 10.4-78 parts of pigment and filler, 0.6-21.5 parts of pH regulating agent, 2.61-9.3 parts of additive and 11.2-37 parts of solvent. The coating film gloss of the water-based middlecoating high in stone-chip resistance is effectively controlled to be about 75, and the gloss of the original formula is up to 85; the stone-chip resistant effect of original middle coating is judgedas Class 5 according to the Great Wall standards, and the original middle has the phenomenon that a steel plate is exposed; the stone-chip resistant effect of the water-based middle coating high in stone-chip resistance can reach Class 7, and the phenomenon that the steel plate is exposed does not occur.

The invention discloses automobile bi-component intermediate paint resistant to rock impact, which consists of a first component and a second component. The first component: the second component=1:(1.5 to 8), polyisocyante barras and high-crosslinking polyisocyante animi resin are dissolved in solution to form the first component, and acrylic resin, titanium white, furnace black, talcum powder, dispersion auxiliaries, functional resin, sediment-preventive auxiliaries, leveling auxiliaries and drying accelerator are dissolved in solution to form the second component. The bi-component intermediate paint which is excellent in rock impact resistance and has excellent construction rubbing property can be prepared by compounding of at least two kinds of self-made polyisocyante resin different in hardness, and is excellent in warm water resistance, acid and alkali resistance, and a paint film is flexible and hard, has excellent attaching force to a bottom layer and has excellent binding force to a surface layer. The thickness of a dry film formed at one step can reach 40 mu m to 60 mu m, the leveling performance of the dry film is fine, the surface roughness Ra of an intermediate paint layer can reach 0.13 approximately, and the average value of DOI (Dorigon) of a painted surface of a painted automobile body ranges from 83 to 86 and is higher in level.

The invention provides modified epoxy resin, a preparation method and an application thereof, a cathodic electrophoretic coating and a preparation method and an application thereof, which belong to the technical field of the coating. The modified epoxy resin is mainly prepared from the following raw materials by weight: 20-32 parts of epoxy resin, 6-12 parts of bisphenol A, 2.5-5 parts of polyether polyol, 0.02-0.15 parts of a catalyst, 4-10 parts of ketimine-containing alcohol, 10-16 parts of carbamate-containing isocyanate, 8-15 parts of polyetheramine, and 22-40 parts of a solvent. The modified epoxy resin has flexible functional groups and more crosslinking sites, so that the modified epoxy resin of the invention and the cathodic electrophoretic coating using the modified epoxy resin can maintain excellent physical and chemical properties, and have excellent anti-stone chip performance, so that the cathodic electrophoretic coating can better meet the coating performance requirements of automobiles and related parts.

The invention relates to a low-temperature stone chip-resistant automobile refinishing paint varnish and a preparation method thereof. The low-temperature stone chip-resistant automobile refinishing paint varnish comprises the following components in parts by weight: 60-70 parts of hydroxy acrylic resin, 10-30 parts of a solvent, 0.5-1.5 parts of a levelling agent, 0.1-0.5 parts of a catalyst, and0.5-1.5 parts of an ultraviolet ray absorber; while in preparation, the hydroxy acrylic resin and the solvent are weighed according to a formula, the materials are mixed and uniformly dispersed, under low-speed stirring condition, the levelling agent, the ultraviolet ray absorber, and the catalyst are added in order, the materials are stirred and mixed at a high speed, and the target product canbe obtained. Compared with the prior art, after the varnish is subjected to solidification at low temperature and film forming, the refinishing paint varnish has excellent stone chip-resistant performance, can achieve stone chip-resistant performance of an automobile original paint, has low VOC, and is environmentally friendly.

The invention discloses a dedicated coating for high speed trains and a preparation method thereof. Polyesters and acrylic polyurethane which have high hydroxyl value and low viscosity are used as main raw materials, rutile titanium dioxide is used as a pigment, then with cooperation of additives and solvents, an A component is prepared by mixing and dispersing the polyesters, acrylic polyurethane and rutile titanium dioxide; a B component is prepared by mixing curing agents and a diluent agent; the dedicated coating for the high speed trains is obtained by mixing and curing the A component and the B component. The coating has extremely high surface hardness, has excellent elasticity, bending resistance, flexibility and weather resistance, has good tensile strength, tear strength and stone chip resistance, and thereby protecting the high speed trains and prolonging service life of the high speed trains.

The invention discloses super fast-drying high-solid polyurethane paint and a preparation method thereof. The polyurethane paint comprises base stock and a curing agent, wherein the base stock comprises hydroxy acrylic resins, coloring pigments, a filler, an enhancer, an additive and a solvent. The preparation method comprises the following steps: uniformly dispersing the hydroxy acrylic resins with an antifoaming agent, a dispersing agent and a solvent, adding the coloring pigments and the filler, and shearing and dispersing at a high speed; deeply dispersing by a sanding and sealing process;and finally, adding the enhancer and a surface additive to prepare the paint. The application method comprises the following steps: mixing the base stock and the curing agent according to a ratio, uniformly stirring, blending to applicable viscosity, and applying and coating. According to the super fast-drying high-solid polyurethane paint disclosed by the invention, the problem that the conventional coating is high in emission of VOCs (Volatile Organic Compounds), slow in surface drying and long in turnover construction period is solved, the decoration requirement and corrosion prevention requirement of equipment manufacturing devices can be met, the environmental requirement can also be met, and the construction is rapid.

The invention provides high-strength damping paint. The high-strength damping paint comprises raw materials in parts by weight as follows: 145-155 parts of vinyl acetate-ethylene copolymer emulsion, 145-155 parts of waterproof acrylic acid emulsion, 145-155 parts of pure acrylic emulsion, 195-205 parts of a flame retardant, 4-6 parts of a defoamer and 195-205 parts of functional filler. The high-strength damping paint is good in impact resistance, adhesion and flexibility.

The invention relates to an aqueous stone-chip-resistant polyurethane dispersion body and a preparation method thereof, wherein the technical parameters of the polyurethane dispersion body are that the pH value is 7.5-9.5, the viscosity is 50-200 CPS, the solid content is 35+ / -3 wt%, the acid value is 17-42 mgKOH / g, and the weight average molecular weight Mw is controlled at 25000-70000. The invention further provides a preparation method of the aqueous stone-chip-resistant polyurethane dispersion body. According to the present invention, the aqueous stone-chip-resistant polyurethane dispersion body has low VOC content so as to meet the environmental protection requirement, and further has excellent stone-chip resistance; and the resin synthesis route is simple, and the method is suitablefor industrialized large-scale production.

The invention relates to stone-crash-resistant automobile corrosion-resistant wax and a preparation method thereof, and belongs to the technical field of metal corrosion prevention. The characteristicthat environment-friendly phytic acid compounds inositol hexaphosphoric acid and tannic acid are liable to be self-assembled on the surface of metal to form a film is utilized; when the environment-friendly phytic acid compounds inositol hexaphosphoric acid and tannic acid are contacted with the surface of the metal, the two anti-rust groups are chelated with the surface of the metal to generateone layer of compact passivation film, and composite paraffin is met and guided to gradually form a protective wax film on the surface of plate material; on the other hand, the two anti-rust groups have optimal compatibility with metal polymers with excellent corrosion resistance such as titanium and aluminum in the metal, the two anti-rust group and a film-forming substance jointly form a corrosion-resistant layer with high compactness on the surface of the metal, and the corrosion-resistant layer has extremely high barrier property on erosion and corrosion mediums such as water, oxygen and ions. The corrosion-resistant wax prepared by the method has extremely high barrier property and high stone crash resistance, is applied to the surface and the hole gap of the material by a spray-coating mode, and has high long-time corrosion resistance.

The invention provides damping paint for automotive chassis armoring. The damping paint comprises the following raw materials: 145-155 parts of waterproof acrylic acid emulsion, 45-55 parts of anti-rust emulsion, 95-105 parts of plasticizing acrylic emulsion, 145-155 parts of pure acrylic emulsion, 13-17 parts of a coalescing agent, 478-522 parts of functional filler, 23-27 parts of a flame retardant and 1.5-2.5 parts of an adhesive. The damping paint is free of environmental pollution, resistant to stone chips, acid, base and salt spray and the like.